Combinatorial Methods,Automated Synthesis and High‐Throughput Screening in Polymer Research: Past and Present

Combinatorial techniques, parallel experimentation and high‐throughput methods represent a very promising approach in order to speed up the preparation and investigation of new polymeric materials: a large variety of parameters can be screened simultaneously resulting in new structure/property relationships. The field of polymer research seems to be perfectly suited for parallel and combinatorial methods due to the fact that many parameters can be varied during synthesis, processing, blending as well as compounding. In addition, numerous important parameters have to be investigated, such as molecular weight, polydispersity, viscosity, hardness, stiffness and other application‐specific properties. A number of corresponding high‐throughput techniques have been developed in the last few years and their introduction into the commercial market further boosted the development. These combinatorial approaches can reduce the time‐to‐market for new polymeric materials drastically compared to traditional approaches and allow a much more detailed understanding of polymers from the macroscopic to the nanoscopic scale. Here we provide an overview of the present status of combinatorial and parallel polymer synthesis and high‐throughput screening.

     

高光谱分辨率横向剪切静态干涉光谱仪

提出一种基于新型的分光方法的横向剪切分束器,分析了该分束器结构的分光原理,并对其用于干涉光谱仪中的效果进行了分析计算.该分束器同体积条件下较目前的分束器可以产生十倍以上的剪切量,应用到干涉仪中可以在获得高光谱分辨率的同时不增大仪器的体积和重量.同时,该分束器分光时,无光能返回光源,较Sagnac型分束器对光能的利用率提高了近一倍;相对变形Mach-Zehnder型结构易实现实体化.     

Vibration of an infinite inhomogeneous transversely isotropic viscoelastic medium with cylindrical hole

This paper investigates the influences of higher order viscoelasticity and the inhomogeneities of the transversely isotropic elastic parameters on the disturbances in an infinite medium, caused by the presence of a transient radial force or twist on the surface of a cylindrical hole with circular cross section. Following Voigt＇s model for higher order viscoelasticity, the nonvanishing stress components valid for a transversely isotropic and higher order viscoelastic solid medium have been deduced in terms of radial displacement component. Considering the power law variation of elastic and viscoelastic parameters, the stress equation of motion has been developed. Solving this equation under suitable boundary conditions, due to transient forces and twists, radial displacement and relevant stress components have been determined in terms of modified Bessel functions. The problem for the presence of transient radial force has been numerically analysed. Modulations of displacement and stresses due to different order of viscoelasticity and inhomogeneity have been graphically depicted. The numerical study of the disturbance caused by the presence of twist on the surface may be similarly done but is not pursued in this paper.     

Ni改性Cu/Mn/ZrO2催化剂合成低碳混和醇的研究

Ni改性的Cu/Mn/ZrO2是CO加氢合成低碳混合醇的有效催化剂,在较为温和的条件(T=573K,p=8.0MPa,GHSV=5000h-1)下,醇的时空产率为0.36g/(ml.h),其中C2+OH的选择性约30%.产物由直链C2+OH和以异丁醇为主的支链醇构成.温度和压力的提高明显促进了异丁醇的生成.可以认为,Ni的添加对直链醇的生成有决定性作用,而异丁醇的生成取决于Zr的作用.反应过程中甲烷等副产物的生成及水煤气变换反应可控制在合理的范围内.另外,K助剂的加入可进一步促进C2+OH的生成.     

一种光纤局域网介质访问协议的设计

本文针对光纤网络提出一种新的无碰撞介质访问协议,该协议允许的用户数比一般协议多,吞吐量不会因输入负载的增多而下下降。文中给出网络流量、分组延迟的性能。     

Study of a X-ray laser-plasma source for radiobiological experiments: microdosimetry analysis and plasma characterisation

A soft X-ray laser-plasma source, used in radiobiology experiments with yeast cells, was characterised with flat crystal spectrometers and P-I-N diodes, obtaining an absolute measurement of the emission spectrum. A comparison with the results of simulations performed with the code RATION allowed the characterisation of the emitting plasma. A model for the energy deposition in yeast cells was developed to take into account the different cell structures (wall-membrane complex, cytoplasm and nucleus). Dose calculations performed considering the source emission spectrum were compared with direct measurements of transmission through plastic foils and allowed to verify the hypothesis of preferential dose deposition in the outer cellular regions. Received 16 September 1999 and Received in final form 1st February 2000     

求解界面裂纹应力强度因子的高次权函数法

从界面裂纹完备的特征展开式出发,利用伪正交特性,提出了计算界面裂纹特征展开式系数和应力强度因子的高次权函数法。文中计算的均匀材料应力强度因子,与已有结果吻合得非常好,并给出了同裂纹的应力强度因子Ｋ１／Ｋ０和Ｋ２／Ｋ０随机材料弹性模量比及裂纹长度的变化。     

实轴上几种高阶奇异积分的换序公式

给出实轴上几种类型高阶奇异积分的换序公式,由于∞点的特异性,对公式（４）,（９）尤加特别注意。     

一种高性能硅片曝光场分布优化算法

以提高光刻机应用性能为目的,提出了一种高性能硅片曝光场分布优化算法。由芯片尺寸计算得到最佳曝光场尺寸,使其最接近于光刻机提供的曝光场最大尺寸,提高了曝光系统的利用率;引入曝光场交错分布,减少了硅片边缘曝光场的交叠,提高了光刻产率;建立产率优先和良率优先两种优化方案,实现了产率和良率的共优。以实际芯片产品的参量为例,将本算法用于曝光过程,采用产率优先标准,曝光场数量减少了10%,而内场数量基本不变,提高了光刻的产率也确保了良率;采用良率优先标准,内场数量增长了10%,总的场数也有所减少,提高了光刻良率的可靠性也确保了产率。     

货物吞吐量预测的改进ARIMAX方法——以天津港为例

为提高港口货物吞吐量预测精度,建立了基于ARIMAX-SVR的组合预测模型。以天津港为例,选取1999～2018年货物吞吐量数据进行分析,首先运用BP神经网络补插缺失数据,然后通过Pearson相关分析筛选出影响货物吞吐量的主要因素;再在ARIMA模型的基础上建立了ARIMAX模型,为进一步提高模型精度,最后建立了SVR模型修正的ARIMAX模型。实证分析结果表明组合模型拟合精度更高,预测效果更好,适用于港口吞吐量预测并且模型具有一定的先进性。