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111.
S. Loridant G. LucazeauT. Le Bihan 《Journal of Physics and Chemistry of Solids》2002,63(11):1983-1992
A high-pressure structural study of SrCeO3 has been performed at room temperature by Raman spectroscopy and X-ray diffraction up to 32 and 45 GPa, respectively. A first-order reversible phase transition is observed at about 12 GPa in both techniques. A second weak structural change, taking place between 18 and 25 GPa, can be suspected from Raman data. The increase in the number of Raman bands and diffraction lines is an indication that the symmetry is lowered and the compound does not evolve towards the ideal cubic perovskite structure. A Rietveld analysis of X-ray data was performed for the low-pressure phase and the atomic positions and the cell lattice parameters variations are reported in this paper. The volume compressibility derived from Raman modes (5.6×10−12 Pa−1), involving mainly bond-stretching for each type of polyhedron, is found to be close to the one obtained from volume cell variations measured by X-ray diffraction (7.9×10−12 Pa−1). 相似文献
112.
本文用多组态HXR自洽场方法和优化以Slater径向积分法相结计算了类锂离子(Z=13~17,19)1s~2nl~2LJ(2≤n≤5,0≤l≤4)能级之间的跃迁波长和振子强度,并和实验进行了比较。就软X射线激光跃迁4f—3d而言,本文计算的波长值比其它文献的计算值更接近于观测值。 相似文献
113.
矩孔金属光栅矢量模式理论的数值计算 总被引:1,自引:0,他引:1
根据矩孔金属光栅的矢量模式理论,计算了不同入射方向,波长及偏振态情况下衍射场的分布,研究了不同光栅结构对衍射效率,偏振态变化的影响;同时,根据实际需要,加工制作了一批不同深度的矩孔光栅样品,进行了实验测量,并将计算值与实验值进行了比较,两者基本相符。 相似文献
114.
Nicolae Tomozeiu 《Applied Surface Science》2006,253(1):376-380
Thin films of a-SiOx (0 < x < 2) were prepared by reactive r.f. magnetron sputtering from a polycrystalline-silicon target in an Ar/O2 gas mixture. The oxygen partial pressure in the deposition chamber was varied so as to obtain films with different values of x. The plasma was monitored, during depositions, by optical emission spectroscopy (OES) system. Energy dispersive X-ray (EDX) measurements and infra-red (IR) spectroscopy were used to study the compositional and structural properties of the deposited layers.Structural modifications of SiOx thin films have been induced by UV photons’ bombardment (wavelength of 248 nm) using a pulsed laser. IR spectroscopy and X-ray photoemission spectroscopy (XPS) were used to investigate the structural changes as a function of x value and incident energy. SiOx phase separation by spinodal decomposition was revealed. The IR peak position shifted towards high wavenumber values when the laser energy is increased. Values corresponding to the SiO2 material (only Si4+) have been found for laser irradiated samples, independently on the original x value. The phase separation process has a threshold energy that is in agreement with theoretical values calculated for the dissociation energy of the investigated material.For high values of the laser energy, crystalline silicon embedded in oxygen-rich silicon oxide was revealed by Raman spectroscopy. 相似文献
115.
B. Sahoo W. Keune E. Schuster W. Sturhahn T. S. Toellner E. E. Alp 《Hyperfine Interactions》2006,168(1-3):1185-1190
Amorphous (a-) Fe x Mg1?x alloys are interesting materials for the investigation of non-Debye-like low-energy vibrational excitations. We have prepared a-Fe x Mg1?x alloy thin films (0.3 ≤ × ≤0.7) by vapour quenching. The amorphous state was confirmed by conversion electron Mössbauer spectroscopy between 4.2–300 K, and the x- and temperature-dependence of the isomer shift and hyperfine magnetic field was measured. For x= 0.6 and 0.7, magnetic ordering occurs below ~150 K. The atomic vibrational density of states, g(E), was determined by nuclear resonant inelastic scattering, providing clear evidence for the non-Debye-like low-energy vibrational excitations. 相似文献
116.
Alignment of photon-induced L3 vacancies is studied in rare earth and highZ elements at energies of experimental interest, near thresholds to 60 keV, under nonrelativistic dipole approximation. Numerical
calculations of the matrix element are undertaken to produce theoretical data for comparison with the experimental findings.
The A2 values being s>0.1 at photoelectron energies <20 keV are certainly higher than 5–8% uncertainties quoted in experimental
results. Present findings are from a very basic model, hydrogen-like and can further be treated as reference to observe the
impact of screening, relativistic, multipole and retardation corrections to the model 相似文献
117.
L. T. Eremenko L. B. Romanova M. E. Ivanova I. L. Eremenko S. E. Nefedov Yu. T. Struchkov 《Russian Chemical Bulletin》1994,43(4):619-623
An effective method of esterification of 1,4-cubanedicarboxylic acid with alkylsulfuric acids is proposed. The derivatives of alkanols with substantially different pKa Valus are obtained in high yields. Molecular structures of the esters obtained are confirmed by various methods. The X-ray study showed a remarkable effect of the nature of an alkyl radical on the geometry of the cubane core.Translated fromIzyestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp.668–672, April, 1994.The authors thank Dr. G. V. Lagodzinskaya for analyzing the NMR spectra and for useful discussions. 相似文献
118.
The TG and DTA curves and diffractograms of powdered CeO2 samples irradiated with a CO2 laser beam with powers of 0.41–1.39 kW/cm2 are presented. The laser treatment induced structural changes and probably generation of a metastable phase. X-ray diffraction coupled with thermal analysis was used to establish the structural modifications in the irradiated samples after heating. 相似文献
119.
A. Waksberg 《International Journal of Infrared and Millimeter Waves》2002,23(9):1327-1335
Coupling losses have been calculated for laser resonators with unequal apertures and extended Fresnel Numbers. This was done using both, diffraction theory and a simple linear model.A close form expression was derived to calculate coupling losses with reasonable accuracies for a limited range of paramters. This should help in the preliminary design of hole coupling laser resonators. 相似文献
120.
Yang Lingxia Ge Debiao Wei Bing 《International Journal of Infrared and Millimeter Waves》2003,24(11):1893-1897
A modified formulation for fringe component of diffraction coefficient is implemented to TD-EEC method. An example of diffraction by perfectly conducting plate is used to illustrate our scheme. Comparing with the FDTD results we observe that the improved expression for fringe component is more accurate than that of Michaeli's formulation. This high frequency time domain technique is available for treating the bistatic scattering problems for millimeter waves. 相似文献