流动注射分析在环境水质重金属检测中的应用进展

重金属具有毒性大、不易被代谢、易被生物富集并有生物放大效应等特点,不但污染水环境,也严重威胁人类和水生生物的存在。近年来各类水环境中重金属污染日趋加剧,重金属的检测及处理方法有多种,而流动注射分析技术以其自动化程度高、分析速度快、精密度高、分析成本低等优点在水环境监测方面占有重要地位。介绍了流动注射在重金属检测方面的应用。     

Modulation of photoswitching profiles by 10,11-dialkoxymethyl substituents in c(2)-symmetric dibenzosuberane-based helicenes

A series of C₂‐symmetric, 10,11‐disubstituted dibenzosuberane (DBS)‐based helicenes 6 a – c with a common 7‐bromo‐α‐tetralin‐based bottom fragment were synthesized. Their absolute stereochemistry was determined to be 10R,11R,P after reductive desulfurization of the corresponding (10R,11R,1′S)‐episulfides with complete stereospecificity. Photoisomerization of the diastereomerically pure (P)‐ 6 c in hexane led to virtually exclusive formation of the opposite M‐form diastereomer (P/M′, <1:>99) at 290 nm. The preferential return of (M′)‐ 6 c to (P)‐ 6 c was also achieved with high selectivity (P/M′, 90:10) at 330 nm. Molecular simulations of (P)‐ 6 c and (M′)‐ 6 c with both DBS conformations suggest that the selectivities of photoswitching are controlled by the conformation of the top DBS template as evidenced by their ¹H NMR spectra. Doping 6 c into a nematic liquid crystal (E7) led to a cholesteric mesophase with modulated pitches, reversible helical senses, and with a switch memory of ternary logic.     

Isospin splittings of doubly heavy baryons

The SELEX Collaboration has reported a very large isospin splitting of doubly charmed baryons. We show that this effect would imply that the doubly charmed baryons are very compact. One intriguing possibility is that such baryons have a linear geometry Q–q–Q$Q\text{–}q\text{–}Q$ where the light quark q oscillates between the two heavy quarks Q  , analogous to a linear molecule such as carbon dioxide. However, using conventional arguments, the size of a heavy-light hadron is expected to be around 0.5 fm, much larger than the size needed to explain the observed large isospin splitting. Assuming the distance between two heavy quarks is much smaller than that between the light quark and a heavy one, the doubly heavy baryons are related to the heavy mesons via heavy quark–diquark symmetry. Based on this symmetry, we predict the isospin splittings for doubly heavy baryons including Ξ_cc${\Xi }_{cc}$, Ξ_bb${\Xi }_{bb}$ and Ξ_bc${\Xi }_{bc}$. The prediction for the Ξ_cc${\Xi }_{cc}$ is much smaller than the SELEX value. On the other hand, the Ξ_bb${\Xi }_{bb}$ baryons are predicted to have an isospin splitting as large as (6.3±1.7) MeV$(6.3\pm 1.7)\text{MeV}$. An experimental study of doubly bottomed baryons is therefore very important to better understand the structure of baryons with heavy quarks.     

Heavy quarks at RHIC and LHC within a partonic transport model

Production and space-time evolution of heavy quarks in central and non-central heavy-ion collisions at RHIC and LHC are studied with the partonic transport model Boltzmann Approach of MultiParton Scatterings (BAMPS). In addition to the initially created heavy quarks in hard parton scatterings during nucleon-nucleon collisions, secondary heavy quark production in the quark-gluon plasma is investigated and the sensitivity on various parameters is estimated. In BAMPS heavy quarks scatter with particles of the medium via elastic collisions, whose cross section is calculated with the running coupling and a more precise implementation of Debye screening. In this framework, we compute the elliptic flow and nuclear modification factor of heavy quarks and compare it to the experimental data.     

Direct photon and photon-jet measurement capability of the ATLAS experiment at the LHC

Direct photon and photon-jet correlations are perfect tools for tomographic studies of the dense medium produced in heavy ion collisions at LHC energies. Due to their weak interactions with the medium, direct photons serve as standard candles for hard-scattering processes, providing a clean calibration of the momentum of the associated jets. The ATLAS detector has powerful opportunities to carry out these measurements. The combination of fine granularity, longitudinal segmentation and large acceptance is unique for the LHC detectors. We show how it will provide optimal capability to distinguish direct photon clusters from neutral meson clusters based on their shower profile over a wide acceptance in η−?$\eta -?$ up to 200 GeV in pT$p_T$. We show that combined with a photon isolation cut ATLAS would be able to measure a relatively background-free direct photon yield from 50–200 GeV along with the corresponding gamma-jet correlations in one nominal LHC Pb+Pb year. These high pT$p_T$ photons provide clean and statistically significant measurements of gamma-jet correlations and the fragmentation function for photon-tagged jets.     

用激光诱导击穿光谱快速分析油漆中的重金属含量

 将电光调Q Nd：YAG激光脉冲聚焦于油漆样品表面以产生激光诱导等离子体。等离子体的光辐射经过一组透镜收集进入单色仪并由光电倍增管探测。通过对等离子体辐射光谱的研究,能够实现对油漆样品中重金属元素含量的快速定性分析。实验分析了多种市售油漆中重金属元素Pb, Cu, Cr, Mn的含量。实验表明：对于同一种类的油漆样品,在相同检测条件下,重金属元素的特征光谱线强度与元素质量分数成正比,因此利用激光诱导击穿光谱来快速分析油漆中重金属元素含量是完全可行的。     

Strain modification of AlGaN layers using swift heavy ions

Epitaxial AlGaN/GaN layers grown by molecular beam epitaxy (MBE) on SiC substrates were irradiated with 150 MeV Ag ions at a fluence of 5×10¹² ions/cm². The samples used in this study are 50 nm Al_0.2Ga_0.8N/1 nm AlN/1 μ m GaN/0.1 μ m AlN grown on SI 4H-SiC. Rutherford backscattering spectrometry/channeling strain measurements were carried out on off-normal axis of irradiated and unirradiated samples. In an as-grown sample, AlGaN layer is partially relaxed with a small tensile strain. After irradiation, this strain increases by 0.22% in AlGaN layer. Incident ion energy dependence of dechanneling parameter shows E ^1/2 dependence, which corresponds to the dislocations. Defect densities were calculated from the E ^1/2 graph. As a result of irradiation, the defect density increased on both GaN and AlGaN layers. The effect of irradiation induced-damages are analyzed as a function of material properties. Observed results from different characterization techniques such as RBS/channeling, high-resolution XRD and AFM are compared and complemented with each other to deduce the information. Possible mechanisms responsible for the observations have been discussed in detail.     

纳米零价铁去除水中重金属离子的研究进展

重金属离子危害严重.本文综述了近几年纳米零价铁去除水中重金属离子的研究,总结了纳米零价铁去除水中重金属离子的机理,主要包括:纳米零价铁的表面吸附-配合、还原、吸附-还原,并对纳米零价铁在这一领域的应用进行了展望.     

Are accurate computations of the 13C′ shielding feasible at the DFT level of theory?

The goal of this study is twofold. First, to investigate the relative influence of the main structural factors affecting the computation of the ¹³C′ shielding, namely, the conformation of the residue itself and the next nearest‐neighbor effects. Second, to determine whether calculation of the ¹³C′ shielding at the density functional level of theory (DFT), with an accuracy similar to that of the ¹³C^α shielding, is feasible with the existing computational resources. The DFT calculations, carried out for a large number of possible conformations of the tripeptide Ac‐G XY ‐NMe, with different combinations of X and Y residues, enable us to conclude that the accurate computation of the ¹³C′ shielding for a given residue X depends on the: (i) (?,ψ) backbone torsional angles of X ; (ii) side‐chain conformation of X ; (iii) (?,ψ) torsional angles of Y ; and (iv) identity of residue Y . Consequently, DFT‐based quantum mechanical calculations of the ¹³C′ shielding, with all these factors taken into account, are two orders of magnitude more CPU demanding than the computation, with similar accuracy, of the ¹³C^α shielding. Despite not considering the effect of the possible hydrogen bond interaction of the carbonyl oxygen, this work contributes to our general understanding of the main structural factors affecting the accurate computation of the ¹³C′ shielding in proteins and may spur significant progress in effort to develop new validation methods for protein structures. © 2013 Wiley Periodicals, Inc.     

用于中能重离子反应测量的塑料闪烁探测器阵列

描述了用于中能(10-100MeV/u)重离子核反应前角度(5°≤θ≤20°)测量的36单元phoswich闪烁探测器阵列.每个phoswich探测器单元由1mm厚的快塑料闪烁体NE102A和100mm厚的慢塑料闪烁体NE115组成,用传统的快、慢门控制的QDC积分方法,对Z=1-20范围的碎片得到了好的粒子鉴别,其粒子分辨能力Z/△Z～45.