电感耦合等离子体质谱（ICP-MS）法测定碳质板岩样品中铂族元素

碳质板岩属黑色岩系,与多种金属(包括贵金属)成矿有密切的联系。按照常规的分析方法,硫镍试金溶剂配方都不能对贵金属元素有较好的富集,影响贵金属元素的测定。根据石墨岩中样品的成份特征,对测定铂族元素的常规硫镍试金配方进行了改进,增加了硝酸钾和氧化镁,且无需加入锇稀释剂。通过实验选择了合适比例配料,熔融后粉碎镍扣,加入盐酸分解,碲共沉淀剂富集。过滤沉淀用王水溶解。用电感耦合等离子体质谱(ICP-MS)法测定,Lu作内标,对碳质板样品中的铂族元素进行了测定。结果表明,加标回收率为85%～105%,能够满足碳质板岩中铂族元素的分析测定要求。     

A posteriori error analysis of an augmented fully mixed formulation for the nonisothermal Oldroyd–Stokes problem

In this article, we consider an augmented fully mixed variational formulation that has been recently proposed for the nonisothermal Oldroyd–Stokes problem, and develop an a posteriori error analysis for the 2‐D and 3‐D versions of the associated mixed finite element scheme. More precisely, we derive two reliable and efficient residual‐based a posteriori error estimators for this problem on arbitrary (convex or nonconvex) polygonal and polyhedral regions. The reliability of the proposed estimators draws mainly upon the uniform ellipticity of the bilinear forms of the continuous formulation, suitable assumptions on the domain and the data, stable Helmholtz decompositions, and the local approximation properties of the Clément and Raviart–Thomas operators. On the other hand, inverse inequalities, the localization technique based on bubble functions, and known results from previous works are the main tools yielding the efficiency estimate. Finally, several numerical results confirming the properties of the a posteriori error estimators and illustrating the performance of the associated adaptive algorithms are reported.     

化学蒸汽发生/电感耦合等离子体质谱法测定近岸及河口海水中的超痕量砷、锑、铋、锗、锡、汞

建立了化学蒸汽发生(CVG)电感耦合等离子体质谱(ICP MS)同时测定近岸及河口海水中超痕量As、Sb、Bi、Ge、Sn和Hg元素的方法.研究了CVG过程中KBH4、盐酸和硫脲的浓度以及样品流速、载气流速、海水样品盐度等对方法分析性能的影响.结果表明,在0.70％6盐酸、0.10 g/L硫脲、11.0 g/L硼氧化钾...     

Calibration of Stress-triaxiality Dependent Crack Formation Criteria: A New Hybrid Experimental–Numerical Method

A new experimental technique has been developed to investigate the onset of fracture in metals at low and intermediate stress triaxialities. The gage section of a flat specimen has been designed such that cracks are most likely to initiate within the specimen center, remote from the specimen boundaries. Along with the specimen, a biaxial testing device has been built to apply a well-defined displacement field to the specimen shoulders. The stress state within the specimen is adjusted by changing the biaxial loading angle. Using this new experimental technique, the crack initiation in metals can be studied experimentally for stress triaxialities ranging from 0.0 to 0.6. The stress and strain fields within the specimen gage section are determined from finite element analysis. The reliability of the computational model of the test set-up has been verified by comparing the simulation results with laser speckle-interferometric displacement measurements during testing. Sample experiments have been performed on the Al-7Si-Mg gravity die casting alloy. A three-step hybrid experimental–numerical calibration procedure has been proposed and applied to determine a phenomenological crack formation criterion for the Al-7Si-Mg alloy.

The role of surface terminations on the band structure and optical properties of silicon nanonets

The ab initio calculations are carried out to investigate the effect of hydrogen, oxygen and nitrogen terminations on the properties of the band edge and the values of the band-gap, as well as the oscillator strength of the silicon nanonets (SiNNs). The oxygen functional groups are found to effectively preserve the direct band-gap nature of the SiNNs, and even change the luminescence properties of the silicon nanowires (SiNWs) to the direct band-gap transition. The appreciable oscillator strength of the first direct transition is obtained for the oxygen terminated nanostructure. The study on the electronic states indicates that the variation of the band edge caused by the surface terminations is attributed to the change of the state compositions. These surface modifications are thought to be useful for silicon band-gap engineering in the area of optoelectronics.     

Microscopic conditions favoring itinerant ferromagnetism: Hund's rule coupling and orbital degeneracy

The importance of Hund's rule coupling for the stabilization of itinerant ferromagnetism is investigated within a two-band Hubbard model. The magnetic phase diagram is calculated by finite-temperature quantum Monte-Carlo simulations within the dynamical mean-field theory. Ferromagnetism is found in a broad range of electron fillings whereas antiferromagnetism exists only near half filling. The possibility of orbital ordering at quarter filling is also analyzed. Received: 26 February 1998 / Accepted: 17 April 1998     

Analysis of the movement behaviour of soil between subsoilers based on the discrete element method

The identification of the movement behaviour of soil in the area under the combined effect of two subsoilers (i.e., the area between two subsoilers) is one of the key issues in determining a reasonable inter-subsoiling shovel distance. The present study established a working model of subsoiling using the discrete element method (DEM). Based on this model and an indoor soil-bin experiment, the present study focused on investigating the micro-movement and macro-disturbed behaviour of soil in the area under the combined effect of two subsoilers. The results show the following. (1) The range of transverse and longitudinal disturbance of soil decreased with increasing distance between the soil and subsoiler. The range of disturbance of the soil in the shallow layer was the widest, followed by the range of disturbance of the soil in the middle layer and the range of disturbance of the soil in the deep layer. The simulated and experimental values of the mean displacement of the soil in the shallow layer (tracer blocks with a side length of 10 mm) were 34.81 mm and 34.55 mm, respectively (error: 0.75%). (2) The force on the soil particles in the deep layer was the greatest, followed by the force on the soil particles in the middle layer and the force on the soil particles in the shallow layer. The force on and the velocity of movement of the soil particles at different locations decreased with increasing distance between the soil and subsoiler. (3) The discrete element simulation could accurately simulate the disturbance process of the soil subjected to subsoiling. The sectional profiles of the disturbed soil obtained from the simulation and experiment were consistent with each other. The relative error between the simulated and experimental values of the soil looseness and the soil disturbance coefficient was 14.45% and 12.06%, respectively. Based on the DEM combined with an indoor soil-bin experiment, the present study determined the movement behaviour of the soil in the area under the combined effect of two subsoilers. The results of the present study can facilitate in-depth investigations of the subsoiling shovel–soil interaction and provide a basis for making decisions to optimise subsoiler arrangements.     

Hybrid-Trefftz有限元法的研究进展

系统概述了Ｈｙｂｒｉｄ Ｔｒｅｆｆｔｚ有限元法及其在弹性力学中的应用．该单元模型由于在插值函数上的灵活选择性使其比普通有限元能更有效地处理局部效应问题,如孔洞,集中荷载等．通过适当选择单元插值函数可构造出高精度的ｐ－扩展元和一系列满足特殊条件的新单元,以在同等条件下提高计算精度      

Improved experimental tracking techniques for validating discrete element method simulations of tumbling mills

We report on further developments in the three-dimensional tracking of a particle deep within the tumbling ball charge of an experimental mill. The experimental X-ray program employing the use of bi-planar X-ray angiography now includes the tracking of a typical 6 mm bulk charge particle in three dimensions with a spatial resolution that is accurate to within 0.15 mm. The improved experimental tracking techniques presented were developed for the purpose of generating accurate three-dimensional particle trajectory data against which to validate a numerical method for the simulation of discrete media, namely the discrete element method (DEM). These improvements are complimented with techniques for comparing charge profiles between numerical DEM simulations and three-dimensional experimental trajectory data.     

点式压电智能结构的模型修正与振动主动控制

提出了在点式压电智能结构中应用摄动有限元方法对结构的有限元模型进行修正 ,从而达到提高建模精度 ,改善实际结构振动主动控制效果的目的。通过对一悬臂梁在模型修正前后进行振动主动控制的不同的控制效果验证了该方法的有效性