全文获取类型
收费全文 | 573篇 |
免费 | 76篇 |
国内免费 | 75篇 |
专业分类
化学 | 206篇 |
晶体学 | 3篇 |
力学 | 67篇 |
综合类 | 8篇 |
数学 | 86篇 |
物理学 | 354篇 |
出版年
2023年 | 4篇 |
2022年 | 8篇 |
2021年 | 12篇 |
2020年 | 15篇 |
2019年 | 13篇 |
2018年 | 22篇 |
2017年 | 18篇 |
2016年 | 25篇 |
2015年 | 16篇 |
2014年 | 22篇 |
2013年 | 41篇 |
2012年 | 25篇 |
2011年 | 30篇 |
2010年 | 20篇 |
2009年 | 28篇 |
2008年 | 28篇 |
2007年 | 25篇 |
2006年 | 35篇 |
2005年 | 21篇 |
2004年 | 26篇 |
2003年 | 20篇 |
2002年 | 30篇 |
2001年 | 16篇 |
2000年 | 26篇 |
1999年 | 21篇 |
1998年 | 13篇 |
1997年 | 15篇 |
1996年 | 14篇 |
1995年 | 10篇 |
1994年 | 19篇 |
1993年 | 11篇 |
1992年 | 5篇 |
1991年 | 4篇 |
1990年 | 7篇 |
1989年 | 7篇 |
1988年 | 9篇 |
1987年 | 8篇 |
1986年 | 5篇 |
1985年 | 6篇 |
1984年 | 7篇 |
1983年 | 4篇 |
1982年 | 8篇 |
1981年 | 4篇 |
1979年 | 4篇 |
1978年 | 4篇 |
1977年 | 2篇 |
1976年 | 3篇 |
1973年 | 2篇 |
1969年 | 2篇 |
1967年 | 1篇 |
排序方式: 共有724条查询结果,搜索用时 31 毫秒
41.
The partition of the canonical entropy (invariant of motion) into a thermodynamic part 5th and a nonthermodynamic oneS
nonth, respectively increasing and decreasing functions of time for a system approaching equilibrium, was proposed by Prigogine and co-workers. This viewpoint is critically examined in the special case of an initially uncorrelated gas of hard disks. BothSth and the leading term ofS
nonth are evaluated for finite assemblies of 400,1600, and 6400 disks, by the method of molecular dynamics. There is good evidence that, in the limit of an infinite system, the Prigogine scheme is verified.On leave of absence from the University of Brussels, Belgium. 相似文献
42.
43.
Muhammad Ejaz Bhanukiran Sunkara Lakhinder Kamboj Jibao He Vijay T. John Noshir S. Pesika Scott M. Grayson 《Journal of polymer science. Part A, Polymer chemistry》2013,51(15):3314-3322
An efficient and novel one‐pot process is developed to immobilize the atom transfer radical polymerization (ATRP) initiators onto the surface of fully pyrolyzed carbon hard spheres (CHSs) via a radical trapping process from the in situ thermal decomposition of bis(bromomethylbenzoyl)peroxide. The CHSs do not require any additional preparative treatment prior to the initiator immobilization. Styrene and methyl methacrylate are polymerized onto initiator‐immobilized CHSs by surface‐initiated atomic transfer radical polymerization (SI‐ATRP). Samples are characterized using Fourier transform infrared, thermogravimetric analysis, scanning electron microscopy, and transmission electron microscopy. These methods of characterization confirmed that all the CHSs are coated with a uniform layer of grafted polymer. This efficient, one‐pot immobilization of ATRP‐initiators represents an exceptionally simple route for the rapid preparation of various polymer‐coated carbon‐based nanomaterials using SI‐ATRP. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 3314–3322 相似文献
44.
The time displacement operator is described for a system of hard-sphere particles. We show how to avoid needing a representation for this operator in unphysical regions of phase space, and how to construct a useful representation in terms of binary collision operators in the physical region. The various binary collision operators used for hard-sphere systems are derived for the case of a system of two spheres, and the results are generalized toN-particle systems.Dedicated to Prof. E. G. D. Cohen on the occasion of his 65th birthday. 相似文献
45.
46.
A pulsed hard X-ray source with shot to shot reproducible spectrum, based on a 4.7 kJ small-chamber Mather-type plasma focus device, is presented. The hard X-ray output spectrum was measured in a single shot basis by differential absorption on metallic plates. The measured spectra have a single dominant peak around 75 keV and a spectral bandwidth covering the 40-150 keV range. A hard X-ray dose of (53±3) μGy per shot was measured on axis at 53 cm from the source, and found to be uniform within a half aperture angle of 6°. 相似文献
47.
Hau‐Chun Chiang Chia‐Hong Liu Raymond Chien‐Chao Tsiang 《Journal of polymer science. Part A, Polymer chemistry》2008,46(24):8149-8158
An acrylic–silica hybrid polymeric nanocomposite, comprising well‐distributed silica nanoparticles in acrylic matrix, has been synthesized at a markedly rapid rate from a dendritic acrylic oligomer (DAO) and an acrylic‐functionalized silica (A‐silica) via UV‐curing. A‐silica was made by functioning colloidal silica nanoparticles with 3‐methacryloxypropyltrimethoxysilane (MATMS) and DAO was formed by reacting 1,5‐diamino‐2‐methylpentane (MPMDA) with trimethylopropane triacrylate (TMPTA). The MATMS has been found either doubly or singly bonded to silica nanoparticles but not triply bonded, and the inclusion of MATMS into the siloxane network structure increases the size of silica nanoparticles. The well distribution of A‐silica and its good compatibility with DAO cause an increase in Td of the acrylic–silica hybrid material. Silica nanoparticles are too small to cause any significant light scattering, and do not have deleterious effects on transparency. The “hybrid‐on‐polyethylene terephathalate” films exhibited satisfactory hardness and surface roughness because of silica nanoparticles. The preparation as well as the characterization of the constituting species and the final hybrid material are described in detail. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 8149–8158, 2008 相似文献
48.
I. M. de Schepper J. J. van Loef A. F. E. M. Haffmans 《Journal of statistical physics》1989,57(3-4):631-645
We argue that the density dependence of the shear viscosities of dense argon at 174, 223, and 301 K and of dense methane at 298 K can be understood on the basis of the mode coupling theory for hard spheres, in particular near the fluid-solid phase transition. 相似文献
49.
Yanfeng Wang Li ZhengxianDu Jihong Hua YunfengWang Baoyun 《Applied Surface Science》2011,258(1):456-460
Materials’ surface service property could be enhanced by transition metal nitride hard coatings due to their high hardness, wear and high temperature oxidation resistance, but the higher friction coefficient (0.4-0.9) of which aroused terrible abrasion. In this work, quinternary (Ti,Al,Si,C)N hard coating 3-4 μm was synthesized at 300 °C using plasma enhanced magnetron sputtering system. It was found that the coating's columnar crystals structure was restrained obviously with the increase of C content and a non-columnar crystals growth mode was indicated at the C content of 33.5 at.%. Both the XRD and TEM showed that the (Ti,Al,Si,C)N hard coatings had unique nanocomposite structures composed of nanocrystalline and amorphous nc-(Ti,Al)(C,N)/nc-AlN/a-Si3N4/a-Si/a-C. However, the coatings were still super hard with the highest hardness of 41 GPa in spite of the carbon incorporation. That a-C could facilitate the graphitization process during the friction process which could improve the coating's tribological performance. Therefore, that nanocomposite (Ti,Al,Si,C)N coatings with higher hardness (>36 GPa) and a lower friction coefficient (<0.2) could be synthesized and enhance the tribological performance and surface properties profoundly. 相似文献
50.
In the present paper, we deal with the complex Szasz-Durrmeyer operators and study Voronovskaja type results with quantitative estimates for these operators attached to analytic functions of exponential growth on compact disks. Also, the exact order of approximation is found. 相似文献