基于不稳定核基本性质测量的原子核结构研究

精密激光谱学是通过测量核素原子光谱的超精细结构和同位素移位来研究原子核的基本性质,为原子核自旋、磁矩、电四极矩及电荷均方根半径的确定提供了一种模型独立的测量方式。这些原子核基本性质的测量,能够比较精确地描述原子核微观结构的演化。近年来,随着放射性束流装置的发展,产生远离β-稳定线的丰中子/丰质子核素成为可能,也进一步促进了高分辨和高灵敏度的激光谱技术更加广泛的应用。简单介绍了基于放射性核素超精细结构的激光谱学测量原理,并通过几个经典实例来回顾近年来激光谱学在原子核奇特结构研究领域的独特贡献。主要通过分析几个重要核区原子核的基本性质,结合大尺度壳模型、ab initio理论、密度泛函理论等,来探索丰中子核中展现出来的一些新的奇特现象,如晕结构、幻数演化、形状共存等。High-precision laser spectroscopy technique is used to determine the ground state properties of exotic nuclei by probing its electronic hyperfine structure and isotope shift. It provides a model-independent measurement of nuclear spin, magnetic moment, electric quadrupole moment and charge radii. These nuclear parameters can be used to investigate the nuclear structure evolution and the nuclear shapes. With the development of accelerators and isotope separators, exotic isotopes far from β stability became accessible experimentally, which enhanced the capability of the laser spectroscopy technique being applied in the field of nuclear physics. A brief introduction to experimental principle is given, followed by a review of several typical examples for the experimental investigations in the different regions of nuclear chart. This aims to demonstrate the contributions of ground state properties measurement by using laser spectroscopy technique to the nuclear structure study of exotic isotopes. This discussion involves several different nuclear theory models in order to interpret the exotic phenomena observed in the neutron-rich isotopes, such as halo structure, shell evolution, shape coexistence and so on.     

Relativistic symmetries of Deng Fan and Eckart potentials with Coulomb-like and Yukawa-like tensor interactions

Relativistic symmetries of the Dirac equation under spin and pseudo-spin symmetries are investigated and a combina- tion of Deng-Fan and Eckart potentials with Coulomb-like and Yukawa-like tensor interaction terms are considered. The energy equation is obtained by using the Nikiforov-Uvarov method and the corresponding wave functions are expressed in terms of the hypergeometric functions. The effects of the Coulomb and Yukawa tensor interactions are numerically discussed as well.     

卤素离子触发亚铁四面体笼的自旋状态转换

合理构筑了3个具有固态自旋交叉特性的亚铁四面体笼状化合物1~3。单晶X射线衍射分析证实了化合物是由6个咪唑席夫碱配体和4个亚铁离子组装形成的边导向封顶胶囊结构。金属中心占据四面体的顶点,而配体组成了四面体的边。这些笼状化合物的内部空腔被咪唑基团环绕,而外部则被取代苯环包围。一个阴离子客体被限域在笼状化合物空腔内,并与笼状化合物主体产生较强的相互作用。当在笼状化合物的乙腈溶液中加入卤素离子（Cl^-和Br^-）时,溶液的颜色和MLCT峰强度会发生明显变化,表明亚铁四面体笼状化合物的自旋状态由低自旋向髙自旋发生了转换。     

Coherent control of spin tunneling in a driven spin–orbit coupled bosonic triple well

We investigate the coherent control of spin tunneling for a spin–orbit (SO) coupled boson trapped in a driven triple well. In the high-frequency limit, the quasienergies of the system are obtained analytically and the fine energy band structures are shown. By regulating the driving parameters, we reveal that the directed spin-flipping or spin-conserving tunneling of an SO-coupled boson occurs along different pathways and in different directions. The analytical results are demonstrated by numerical simulations and good agreements are found. Further, an interesting scheme of quantum spin tunneling switch with or without spin-flipping is presented. The results may have potential applications in the design of spintronic devices.     

稀磁半导体的研究进展

本文主要介绍了III-V族稀磁半导体(Ga,Mn)As的研究进展,包括(Ga,Mn)As的生长制备、基本磁性质、磁输运特征、磁光性质、磁性起源、相关的异质结构和自旋注入等,同时还简单介绍了其它稀磁半导体如IV族、III-VI族和IV-VI族等稀磁半导体的研究进展,在文章的最后描述了理想的稀磁半导体应该具备的特征以及对未来的展望。     

磁性纳米结构中由激光引起的超快自旋动力学研究

以单个磁性中心的NiO以及由Co和Ni等元素构成的双磁性中心的纳米结构为例,总结了近年所做的主要工作.为了在理论上实现磁性纳米结构中的超快自旋翻转和转移,提出了一种称为Λ进程(Λ process)的超快自旋转换机理.在实际计算中,首先采用量子化学第一性原理计算得到磁性纳米结构中精确的隙间d电子态,然后考虑外加磁场和自旋轨道耦合分析磁性原子中的自旋局域化程度,最后引入激光脉冲项,研究在其作用下材料的自旋态经由Λ进程实现转换的时间历程.研究结果表明自旋翻转和转移可以在线偏振光的作用下在亚皮秒的时间尺度内完成. 关键词： 超快自旋动力学 第一性原理计算 Λ进程 磁性纳米结构     

内含式化合物X@Al12P12的结构与稳定性研究

采用B3LYP/6-31G*方法, 对内含式化合物X@Al₁₂P₁₂ (X＝Li^0/＋, Na^0/＋, K^0/＋, Be^0/2＋, Mg^0/2＋, Ca^0/2＋, H和He)的不同对称性构型进行计算, 讨论其最稳定构型的几何参数、布居分析、偶极矩、电离势、包含能、频率、HOMO-LUMO能隙和自旋密度．发现X@Al₁₂P₁₂化合物中, 客体X＝Na^0/＋, K^0/＋, Mg和He几乎处在笼的中心, Be和Ca^0/2＋处在中心附近0.033 nm的半径内, Li^0/＋, Be^2＋, Mg^2＋和H很大程度上偏离笼的中心位置. 大部分金属内含式化合物的C₃对称性构型稳定．Li^0/＋, Be^0/2＋, Mg^2＋, Ca^2＋和H与其它离子相比更易嵌入笼内形成稳定的内含式化合物.