全文获取类型
收费全文 | 9710篇 |
免费 | 684篇 |
国内免费 | 1226篇 |
专业分类
化学 | 3422篇 |
晶体学 | 45篇 |
力学 | 188篇 |
综合类 | 146篇 |
数学 | 6298篇 |
物理学 | 1521篇 |
出版年
2024年 | 11篇 |
2023年 | 104篇 |
2022年 | 186篇 |
2021年 | 247篇 |
2020年 | 237篇 |
2019年 | 296篇 |
2018年 | 272篇 |
2017年 | 304篇 |
2016年 | 225篇 |
2015年 | 209篇 |
2014年 | 348篇 |
2013年 | 1053篇 |
2012年 | 326篇 |
2011年 | 444篇 |
2010年 | 386篇 |
2009年 | 528篇 |
2008年 | 592篇 |
2007年 | 753篇 |
2006年 | 573篇 |
2005年 | 525篇 |
2004年 | 459篇 |
2003年 | 493篇 |
2002年 | 433篇 |
2001年 | 355篇 |
2000年 | 341篇 |
1999年 | 324篇 |
1998年 | 304篇 |
1997年 | 267篇 |
1996年 | 193篇 |
1995年 | 112篇 |
1994年 | 131篇 |
1993年 | 81篇 |
1992年 | 79篇 |
1991年 | 58篇 |
1990年 | 43篇 |
1989年 | 43篇 |
1988年 | 41篇 |
1987年 | 42篇 |
1986年 | 24篇 |
1985年 | 42篇 |
1984年 | 22篇 |
1983年 | 15篇 |
1982年 | 21篇 |
1981年 | 20篇 |
1980年 | 10篇 |
1979年 | 7篇 |
1978年 | 11篇 |
1977年 | 12篇 |
1976年 | 4篇 |
1936年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
81.
含二氧杂环异黄酮的合成 总被引:8,自引:0,他引:8
本文报道含有3', 4'-亚甲二氧基, 3', 4'-亚乙二氧基, 3, 4'-三亚甲二氧基的异黄酮类化合物的合成, 所得25个新化合物的结构经元素分析、^1H NMR谱确证; 紫外光谱表明有异黄酮特征吸收。文中并对反应机理进行了探讨。 相似文献
82.
83.
袁香环 《新疆大学学报(理工版)》1987,(4)
作者在文献[1]中证明了一个结果:有限群G如果满足|P(G),p|=1,则G为P~-可解群。本文将指出,这个论断的逆命题不成立。并且还指出,满足条件(|P(G)|,p)=1的有限群也不一定是p~-超可解群。 相似文献
84.
85.
WONG Henry N. C. 《中国化学》2005,23(8):1106-1108
Trimethylsilyl groups have been used in our research as a director as well as a bulky and lipophilic group in our quest for natural and non-natural molecules. 相似文献
86.
Mao-fengZhang Qiao-hongYao Chun-huiHuang Wei-xiaoCao 《高分子科学》2005,(1):27-27
A kind of azo-containing resin (Azo-R) was synthesized by a simple way through the coupling reaction of 2-nitro-N-methyldiphenylamine-4-diazoresin (NDR) with phenol, and a new covalentely attached multilayer film from Azo-R as H-donor and photosensitive diazoresin, diphenylamine-4-diazoresin (DR) as H-acceptor via H-bonding attraction by selfassembly technique has been fabricated. Following the decomposition of diazonium group of DR under exposure to UV light, the H-bonds between the layers of the film convert to covalent bonds and the film becomes very stable toward polar solvents or electrolyte aqueous solutions. Thus the UV-irradiated azo-containing films can be used to measure photocurrent in a conventional three-electrode photoelectrochemical cell using KCl as supporting electrolyte. It was confirmed that the azo-containing multilayer film is responsible for the photocurrent generation. 相似文献
87.
O. M. Radul M. Z. Krimer O. N. Rebrova V. N. Biyushkin I. V. Feofanova A. A. Panasenko 《Russian Chemical Bulletin》1993,42(3):522-527
The rearrangement of enol acylates of aryl 1H-1, 2, 4-triazol-1-ylmethyl ketones at 140–150°C in acetic anhydride is studied. The migration of the acyl group to the C(5) atom of the heterocycle is found to be intramolecular. The characteristics of the original and final products are presented. X-ray structural studies of the enol acetates of 2, 4-dichlorophenyl 1H-1, 2, 4-triazol-1-ylmethyl ketone and 2, 4-dichlorophenyl 5-acetyl-1H-1, 2, 4-triazol-1-ylmethyl ketone are carried out.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 560–564, March, 1993. 相似文献
88.
H. Binder B. Kohlstrunk U. Brenn W. Schwieger G. Klose 《Colloid and polymer science》1998,276(12):1098-1109
Microcrystals of the metal silicate hydrate ilerite orient macroscopically on the surface of a ATR-crystals and thus, are
accessible for infrared linear dichroism measurements. We present first results which indicate that the alkyl chain packing
and the orientation of the polar group of dodecyltrimethylammoniumbromide (DTAB) intercalated between silicate layers can
be determined in terms of infrared order parameters. The properties of DTAB can be modulated by the relative humidity of the
surrounding atmosphere and by temperature. Upon heating DTAB undergoes a phase transition from a paraffin-like solid to a
fluid phase. The former is characterized by the orthorhombic perpendicular packing of the frozen alkyl chains with tilted
long axes. The interactions between the ionic groups of the surfactant and that of the host matrix stabilize the lamellar
arrangement of DTAB in the crystalline and in the fluid phases.
Received: 14 January 1998 Accepted: 27 July 1998 相似文献
89.
Olivier Busnel 《Tetrahedron letters》2007,48(33):5767-5770
The preparation of new Nβ-Fmoc-protected aza-β3-amino acids (aza-β3-aa) with proteinogenic side chains as well as their Nβ-Fmoc, Nβ-Cbz or Nβ-Boc aza-β3-amino esters (from Pro, Asn, Asp, Glu, Gln) by successive nucleophilic substitutions will be described. 相似文献
90.
Kosuke Katagiri Yukina Yamamoto Yuui Takahata Ryoga Kishibe Naoki Fujimoto 《Tetrahedron letters》2019,60(30):2026-2029
Anthracenyl(diphenyl)phosphine oxide and dianthracenylphenylphosphine oxide as photoactive compounds have been synthesized. Anthracenyl group of these compounds indicate the multi-functional roles such as an emission component, a photodimerization component, and a leaving group. When the light irradiation was performed under an oxygen atmosphere, photo-oxidative PC bond cleavage to leave the antharacenyl group was observed. Moreover, phosphonyl radical was produced and then PP bond formation to form diphosphane was observed. 相似文献