膦系阻垢剂阻碳酸钙垢机理的研究

在模拟循环水中, 通过静态阻垢实验研究了HEDP, PBTCA, ATMP和EDTMP对碳酸钙的阻垢性能, 在相同的加药浓度下(按物质的量浓度计)阻垢性能的强弱顺序为HEDP＞PBTCA＞ATMP＞EDTMP; 同时采用分子动力学方法, 模拟计算了阻垢剂负二价离子与方解石(104), (102), (202)和(113)面的相互作用. 结果表明: 阻垢剂分子中的膦酸基团和羧酸基团与碳酸钙中的Ca^2＋形成的离子键对吸附起到了主要作用, 同时阻垢剂与晶面间存在较弱的范德华力相互作用. 阻垢剂与各晶面的结合能强弱顺序为(113)≥(102)≥(202)＞(104); 分子中的羟基易与垢晶面形成氢键而加强阻垢效果; 羧基的位置不同对阻垢作用的影响不同. 将静态阻垢的实验结果与分子动力学模拟结果进行了相关性分析, 发现阻垢剂在(104)面和(102)面上的吸附对阻垢作用的贡献较大.     

Static SIMS–VAMAS interlaboratory study for intensity repeatability,mass scale accuracy and relative quantification

An interlaboratory study involving 19 time‐of‐flight static secondary ion mass spectrometer (TOF‐SSIMS) instruments from 12 countries has been conducted. Analysts were supplied, by the National Physical Laboratory, with a protocol for analysis together with three reference materials: poly(tetrafluoroethylene), a thin layer of polycarbonate on a silicon wafer and a patterned sample with different amounts of Irganox 1010 in each of four quadrants on a silicon wafer. The objectives of the study are (i) to determine the repeatability and constancy of the relative intensity scale achievable using the draft ISO standard (DIS 23830), (ii) to evaluate the effectiveness of mass scale calibration and optimisation procedure and (iii) to evaluate the current capability of relative quantification using SSIMS. The results of this study show that the constancy of the relative intensity scale has an approximate scatter standard deviation of only 5%. This is excellent and demonstrates that SSIMS measurements are significantly more stable than often thought by analysts. The draft ISO standard (DIS) CD 13084 for calibration of the mass scale in TOF‐SIMS was evaluated and found to be consistent with our previous study. Four laboratories optimised the instrument mass calibration accuracy using this procedure leading to improvements in mass scale calibration by factors of 1.8, 2.2, 2.3 and 8.6. Using a novel patterned Irganox sample it is shown that the precision of relative quantification may be as good as a standard deviation of only 5% for 16 instruments—this is a remarkable result. Further work is required to develop more robust reference materials. © Crown copyright 2010. Reproduced with the permission of Her Majesty's Stationery Office. Published by John Wiley & Sons, Ltd.     

神龙一号直线感应加速器X光转换靶破坏诊断

 利用能量约450 keV、焦斑直径1~4 mm的低能X光对神龙一号直线感应加速器束靶作用后钽靶的破坏进行诊断,利用增强型电荷耦合器件（ICCD）对诊断过程记录,得到束靶作用后数μs时间内钽靶材料密度的变化。结果表明：在束靶作用后约1 μs内靶材料密度基本没有变化,且该时间段内ICCD相机没有观察到有靶前钽靶材料的微粒喷射。     

基于无衍射光的表面粗糙度三角测量及其灰色评定方法

 激光三角法是表面形貌非接触测量中的一种常用方法,在几何测量领域应用广泛。传统的激光三角法采用高斯光束作为指示光源,在机械扫描机构的配合下,通过对被测表面逐点扫描完成表面形貌的测量。采用新型的无衍射光替代传统激光光源,解决了普通高斯光束存在的“焦深”问题,简化了机械结构。并采用基于灰色系统理论的灰色滤波进行表面形貌的分离与评定,克服了原有方法对测量数据样本量和统计特性的依赖,并通过实验表明该系统能够准确地完成表面形貌的三维测量,所提出的灰色评定方法能够比较有效地进行表面形貌的分离与评定。     

加偏压中心对称双光子光折变晶体中多变量空间灰孤子

 为了得到有偏压的中心对称双光子光折变晶体中存在多变量空间灰孤子的结果,基于中心对称双光子光折变晶体中空间灰孤子的基本理论,采用数值方法推导出了中心对称双光子多变量空间灰孤子归一化包络解的积分形式,并对其特性进行研究。结果表明：这种多变量空间灰孤子是由多束偏振方向和波长都相同的互不相干光束耦合形成的。当多变量空间灰孤子只包含有1个或2个光束分量成分时,它自动退化到中心对称双光子空间灰孤子或中心对称双光子非相干耦合灰 灰空间孤子对的情况。当这一多变量空间灰孤子在有偏压的中心对称双光子光折变晶体中传播时,各分量成分光束都能稳定传播。     

Electromechanical cracking in ferroelectrics driven by large scale domain switching

Experimental results indicate three regimes for cracking in a ferroelectric double cantilever beam (DCB) under combined electromechanical loading. In the loading, the maximum amplitude of the applied electric field reaches almost twice the coercive field of ferroelectrics. Thus, the model of small scale domain switching is not applicable any more, which is dictated only by the singular term of the crack tip field. In the DCB test, a large or global scale domain switching takes place instead, which is driven...     

基于M2因子测量的大气湍流参数的确定方法

基于广义惠更斯-菲涅尔原理以及大气湍流理论,推导出部分相干光束在大气湍流中传输的光束传输M ^{2因子的解析表达式.定量分析了表征大气湍流参数的折射率结构常数 C2_n}和涡旋内尺度 l _{0对 M ^{2因子的影响,并由此提出了一种通过实验测量大气湍流中光束的 M 2因子,进而确定出大气湍流参数的新方法.研究结果表明,由于大气湍流对相干性好的光束影响更为明显,在测量中可采用具有高相干性的基模高斯光束作为测量光源,而测量装 关键词： 2因子')" href="#">光束传输 M 2因子 大气湍流参数 湍流折射率结构常数 湍流涡旋内尺度}}     

Crystalline misfit-angle implications for solid sliding

For the contact of two finite portions of interacting rigid crystalline surfaces, we compute the pinning energy barrier dependency on the misfit angle and contact area. This simple model allows us to investigate a broad contact-size and angular range, thus obtaining the statistical properties of the energy barriers opposing sliding for a single asperity. These data are used to generate the distribution of static frictional thresholds for the contact of polycrystals, as in dry or even lubricated friction. This distribution is used as the input of a master equation to predict the sliding properties of macroscopic contacts.     

Cross-correlations in volume space: Differences between buy and sell volumes

We study the cross-correlations of buy and sell volumes on the Korean stock market in high frequency. We observe that the pulling effects of volumes are as small as that of returns. The properties of the correlations of buy and sell volumes differ. They are explained by the degree of synchronization of stock volumes. Further, the pulling effects on the minimal spanning tree are studied. In minimal spanning trees with directed links, the large pulling effects are clustered at the center, not uniformly distributed. The Epps effect of buy and sell volumes are observed. The reversal of the cross-correlations of buy and sell volumes is also detected.     

Derivation of Korteweg–de Vries flow equations from the short‐wave model equation

We perform a multiple‐time scales analysis and compatibility condition to the short‐wave model equation. We derive Korteweg–de Vries flow equation in the bi‐Hamiltonian form as an amplitude equation. Copyright © 2013 John Wiley & Sons, Ltd.