Diffusiophoresis in suspensions of highly charged soft particles

Diffusiophoresis phenomenon of aoft particles suspended in binary electrolyte solutions is explored theoretically in this study based on the spherical cell model, focusing on the chemiphoresis component in absence of diffusion potential. Both the electrostatic and hydrodynamic aspects of the boundary confinement, or steric effect, due to the presence of neighboring particles are examined extensively under various electrokinetic conditions. Significant local extrema are found in mobility profiles expressed as functions of the Debye length in general, synchronized with the strength of the motion-inducing double layer polarization. Moreover, a seemingly peculiar phenomenon is observed that the soft particles may move faster in more concentrated suspensions. The competition between the simultaneous enhancement of the motion-inducing electric driving force and the motion-retarding hydrodynamic drag force from the boundary confinement effect of the neighboring particles is found to be responsible for it. The above findings are also demonstrated experimentally in a very recent study on the diffusiophoretic motion of soft particles through porous collagen hydrogels. The results presented here are useful in various practical applications of soft particles like drug delivery.     

超微粒介孔分子筛Ti-MCM-41的合成及应用

超微粒分子筛;苯乙烯;催化氧化;超微粒介孔分子筛Ti-MCM-41的合成及应用     

STABILITY OF EMULSIFIER-FREE EMULSION COPOLYMERIZATION OF METHYL METHACRYLATE/BUTYL ACRYLATE/SODIUM MONO(ETHYL POLYOXYETHYLENE)MALEATE

A series of new water-soluble bifunctional comonomers having both carboxyl and alkylpolyoxyethylene groups, such as sodium mono(ethyl polyoxyethylene) maleate (ZE series) with variousmolecular weights of polyoxyethylene ethyl ether, were synthesized and characterized. The effects of thestructural factor, the amount and feeding mode of the comonomers, the initiator concentration andpolymerization temperature on the stability of emulsifier-free emulsion copolymerization of methylmethacrylate (MMA) and butyl acrylate (BA) in the presence of a small amount of ZE with potassiumpersulfate as initiator were investigated. Stable, almost monodispersed MMA/BA/ZE emulsifier-free latexparticles were prepared.     

An optimal Steffensen-type family for solving nonlinear equations

In this paper, a general family of Steffensen-type methods with optimal order of convergence for solving nonlinear equations is constructed by using Newton’s iteration for the direct Newtonian interpolation. It satisfies the conjecture proposed by Kung and Traub [H.T. Kung, J.F. Traub, Optimal order of one-point and multipoint iteration, J. Assoc. Comput. Math. 21 (1974) 634-651] that an iterative method based on m evaluations per iteration without memory would arrive at the optimal convergence of order 2^m−1. Its error equations and asymptotic convergence constants are obtained. Finally, it is compared with the related methods for solving nonlinear equations in the numerical examples.     

Initiation mechanisms in copolymerization: Reaction of t-butoxyl radicals with co-monomers ethyl vinyl ether and methyl methacrylate

The radical trapping technique employing 1,1,3,3-tetramethyl-1,3-dihydro-1H-isoindol-2-yloxyl as a scavenger has been used to investigate the reaction of t-butoxyl radicals with mixtures of ethyl vinyl ether and methyl methacrylate. The range of identified products includes those from both addition and hydrogen abstraction with both monomers, head addition with ethyl vinyl ether, and some second monomer addition products. Relative rate constants have been obtained for various pairs of constituent reactions. t-Butoxyl radicals add to ethyl vinyl ether one to two times faster than to methyl methacrylate, depending on which monomer is in excess. The ratio is less than 1 in nonolefinic solvents and as high as 6 in t-butanol. This solvent effect is thought to be due to the radicals complexing to either methyl methacrylate or t-butanol (H-bonding), thereby increasing its electrophilic character. © 1997 John Wiley & Sons, Inc.     

铝粉度对自蔓延高温合成AlB2-Al2O3复合粉体的影响

以金属Al粉和B2O3粉为原料,采用自蔓延高温合成法(SHS)制备AlB2-Al2O3复合粉体.采用X射线衍射仪、扫描电镜和能谱仪分析手段,对所制得的复合粉体进行了表征.研究了Al粉粒度(100目、300目和600目)对自蔓延高温合成方法制备AlB2-Al2O3复合粉体的燃烧学、相组成及微观结构的影响.结果表明:铝粉粒度越小,燃烧温度越高、燃烧波速度越快,复合粉体中AlB2相含量增加,实验测得600目铝粉反应的燃烧温度为2060K,燃烧波速度为2.08 mm/s.复合粉体以AlB2和Al2O3为主晶相,显微结构为数量较少、粒径约5μm的AlB2粉弥散分布于粒径约2 μm的Al2O3和Al的混合粉中.     

多孔介质——自由流界面应力跳跃条件下流动特性解析解

对非对称多孔介质--自由流复合通道内多孔介质内部及多孔介质与自由流体界面处复杂质量、动量输运特性进行研究. 在多孔介质区采用Brinkman-extended Darcy模型并结合速度连续,剪切应力跳跃的界面条件对此复合通道内流体的传递现象进行求解,提出了考虑界面应力跳跃时非对称复合通道各区域流体运动速度及摩擦系数的解析式,分析了界面应力跳跃系数,达西数及无量纲多孔层偏心厚度对流体速度及摩擦系数的影响. 结果表明:改变界面性质可在一定条件下明显控制各区域流体速度分布;在达西数、多孔层偏心厚度一定情况下,界面应力系数的增大会使界面流速减小,而使流体摩擦系数增大,特别是界面应力系数小于0的情况下变化更明显,此时若不考虑界面应力系数则会造成较大误差. 当界面应力系数及多孔层偏心厚度均为较小负数值时,改变多孔层偏心厚度对界面速度的影响要大于改变界面应力系数的情况;而当界面应力系数及多孔层偏心厚度为较大正数值时,情况则相反. 较大达西数下,界面应力系数及多孔层偏心厚度对流体摩擦系数的影响均较大,继续减小达西数至一定程度时,界面应力系数对流体摩擦系数的影响可忽略不计而认为只与多孔层偏心厚度相关,且对较大多孔层偏心厚度更敏感.      

Aerobic oxidation assisted by ligand-free palladium catalysts

Aerobic oxidation of electron-rich benzylic and phenyl allylic alcohols was achieved with high yields with only 0.1 mol.% of Pd(OAc)2 catalyst in the absence of any ligand. This procedure was expected to be valuable for realistic industrial-scale applications from both economic as well as environmental points of view.     

Mechanism of azole antifungal activity as determined by liquid chromatographic/mass spectrometric monitoring of ergosterol biosynthesis

A liquid chromatography/mass spectrometry (LC/MS) method for separation and characterization of ergosterol biosynthetic precursors was developed to study the effect of Posaconazole on sterol biosynthesis in fungi. Ergosterol biosynthetic precursors were characterized from their electron ionization mass spectra acquired by a normal-phase chromatography, particle beam LC/MS method. Fragment ions resulting from cleavage across the D-ring and an abundant M - 15 fragment ion were diagnostic for methyl substitution at C-4 and C-14. Comparison of the sterol profile in control and treated Candida albicans incubations showed depletion of ergosterol and accumulation of C-4 and C-14 methyl-substituted sterols following treatment with Posaconazole. These C-4 and C-14 methyl sterols are known to be incapable of sustaining cell growth. The results demonstrate that Posaconazole exerts its antifungal activity by inhibition of ergosterol biosynthesis. Furthermore, Posaconazole appears to disrupt ergosterol biosynthesis by inhibition of lanosterol 14alpha-demethylase.     

旋流燃烧室内颗粒运动的数值模拟

本文应用流体相湍流脉动速度大小和方向均具有随机性的颗粒相随机轨道模型,对有直流一次风和旋流二次风的旋流燃烧室内的颗粒运动进行了数值模拟。得到的颗粒相轴向总质量流通量、轴向与切向速度分布与实验测量数据相符合,并比 Gosman 颗粒随机轨道模型的模拟结果有一定的改进。