Effect of gamma irradiation on ethylene–octene copolymers

Two ethylene–octene copolymers (POE) were irradiated with ⁶⁰Co gamma radiation and influence of irradiation atmosphere, absorbed dose and heat treatment of samples on the crosslinking were studied. Thermal properties and crystalline morphology of non-irradiated and irradiated POE were determined by using differential scanning calorimetry (DSC) and wide-angle X-ray diffraction (WAXS), respectively. The Charlesby–Pinner equation was used to describe the relationship between absorbed dose and sol fraction. The gel fraction of irradiated POE was lower and decreased with the increase of octene content when irradiated in oxygen, compared to irradiation in nitrogen atmosphere. The gel fraction increased significantly with the increasing of absorbed dose for the two copolymers. Heat treatment of samples prohibited the crosslinking of irradiated POE. The DSC results indicated that a subtle change of thermal properties of POE was observed before and after gamma irradiation at low dose. No change was found from the WAXS spectra of non-irradiated and irradiated POE. For heat-treating samples, the Charlesby–Pinner equation can not fit perfectly with the relationship between the sol fraction and absorbed dose, but it fits well with the crosslinking reaction of POE pellets.     

Investigation of infill-patterns on mechanical response of 3D printed poly-lactic-acid

This paper presents the effect of infill patterns (IPs) on the mechanical response of 3D printed specimens by conducting the low-velocity impact test (LVI) and compression test. The poly-lactic acid (PLA, purity 98 wt% >) material has selected and printed using fused deposition modeling (FDM, speed 20 mm/s, layer height 0.2 mm, no of layers 30, extruded at 200 °C) with four different IPs: triangle, grid, quarter cubic, and tri-hexagon. The LVI test on velocity-time, energy-time and force-displacement, and the compression responses have examined and presented in this study. The LVI test was carried out to determine the penetration energy level, energy absorption capacity (toughness), stiffness, and strength of PLA porous parts (60% infill density) for implant/tissue/recyclable product applications. The results have shown that the triangular pattern has produced the highest absorbed energy in LVI test (penetration energy 7.5 J, and stiffness 668.82 N/mm) due to more sheared/contact layers’ perpendicular to impactor (hemispherical insert); while the grid pattern exhibited the highest compressive strength (72 MPa) due to more layers aligned along the compressive loading direction The SEM fracture surface image of Triangular IP has produced effective raster and layer bonding, less number of voids, more amount of circular beach markings, and absence of ratchet lines leading to possess improved mechanical properties.     

La3Ga5SiO14的BAW传播特性

详细推导计算了声体波(BAW)在La3Ga5SiO14(LGS)晶体中分别沿YZ、XY、XZ面传播的纯切变波,准切变波,准纵波的表达式.绘制了LGS晶体在(100)、(010)、(001)这三个主晶面内声的慢度分布曲线图.计算了声速的最大值并与石英进行比较,结果表明LGS晶体的BAW传播速度一般比石英低1000m/s左右.为该晶体在声体波器件等方面的设计和应用提供了一定的理论指导作用.     

Viscous behavior of linear and three‐branch alkanes: Linking the equilibrium and transport theories

A new model for zero‐shear viscosity, η, is proposed. The model combines the Simha–Somcynsky (SS) statistical thermodynamic theory of liquids with the Eyring Significant Structure (ESS) transport theory. Using the new model, a successful linearization of the experimental viscosity vs. hole fraction data was obtained. A comparison between the new model and Utracki's relation, ln η = a₀ + a₁/(h + a₂) was also made. The former was found to be more successful for both linear and nonlinear structures, provided that an appropriate choice of the degrees of freedom of normal and activated states was made. The proportionality constant of the activation energy and transmission coefficient were also calculated for each species. © 1999 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 37: 879–887, 1999     

Modelling of two‐dimensional laminar flow using finite element method

In this paper, a Galerkin weighted residual finite element numerical solution method, with velocity material time derivative discretisation, is applied to solve for a classical fluid mechanics system of partial differential equations modelling two‐dimensional stationary incompressible Newtonian fluid flow. Classical examples of driven cavity laminar flow and laminar flow past a cylinder are presented. Numerical results are compared with data found in the literature. Copyright © 1999 John Wiley & Sons, Ltd.     

Vorticity‐velocity formulations of the Stokes problem in 3D

This work studies the three‐dimensional Stokes problem expressed in terms of vorticity and velocity variables. We make general assumptions on the regularity and the topological structure of the flow domain: the boundary is Lipschitz and possibly non‐connected and the flow domain may be multiply connected. Upon introducing a new variational space for the vorticity, five weak formulations of the Stokes problem are obtained. All the formulations are shown to lead to well‐posed problems and to be equivalent to the primitive variable formulation. The various formulations are discussed by interpreting the test functions for the vorticity (resp. velocity) equation as vector potentials for the velocity (resp. vorticity). Of the five sets of boundary conditions derived in the paper, three are already known, but only for domains with a trivial topological structure, while the remaining two are new. Copyright © 1999 John Wiley & Sons, Ltd.     

A numerical investigation of flow past a bluff body using three-state anemometry

An application of a new flow measurement technique is described which allows for the non-intrusive simultaneous measurement of flow velocity, density, and viscosity. The viscosity information can be used to derive the flow field temperature. The combination of the three measured variables and the perfect-gas law then leads to an estimate of the flow field thermodynamic pressure. Thus, the instantaneous state of a flow field can be completely described. Three-state anemometry (3SA), a derivative of particle image velocimetry (PIV), which uses a combination of three monodisperse sizes of styrene seeding particles is proposed. A marker seeding is chosen to follow the flow as closely as possible, while intermediate and large seeding populations provide two supplementary velocity fields, which are also dependent on fluid density and viscosity. A simplified particle motion equation, aimed at turbomachinery applications, is then solved over the whole field to provide both density and viscosity data. The three velocity fields can be separated in a number of ways. The simplest and that proposed in this paper is to dye the different populations and view the region of interest through interferometric filters. The two critical aspects needed to enable the implementation of such a technique are a suitable selection of the diameters of the particle populations, and the separation of the velocity fields. There has been extensive work on the seeding particle behaviour which allows an estimate of the suitable particle diameters to be made. A technique is described in this paper to allow the separation of particles in a range of micrometer sized velocity fields through fluorescence (separation through intensity also being possible). Some preliminary results by direct numerical simulation (DNS) of a 3SA image are also presented. The particle sizes chosen were 1 μm and 5 μm, tested on the near-wake flow past a cylinder to investigate viscosity only, assuming uniform flow density. The accuracy of the technique, derived from simulations of swirling flows, is estimated as 0.5% RMS for velocity, 2% RMS for the density and viscosity, and 4% RMS for the temperature estimate. © 1998 John Wiley & Sons, Ltd.     

基于超声波干涉的拟合法计算声速及其误差分析

通过对超声波干涉图样的分析以及数学推导,得到拟合计算声速的方法．实验中,用CassyLab软件记录某一水平面的干涉强度信息（即干涉图样）,用Matlab相关工具包完成拟舍,拟合的结果与原图样吻合得很好,标准偏差也很小．最后分析和探讨了拟合法计算声速的误差来源并提出了改进办法．     

The combined statistical and kinetic modeling of gel/sol partition in free-radical copolymerization of vinyl/divinyl monomers

A general model of the gel/sol partition in the free-radical copolymerization of vinyl/divinyl monomers was developed, combining the statistical and kinetic modeling. It is emphasized that properties of the primary chains born at some conversion are effected by their partner primary chains. It was concluded that the present model had overcome some shortcomings in Flory's and Tobita's model and facilitated taking the influence of kinetics into account, and was shown to be rather general for the free-radical copolymerization of vinyl/divinyl monomers. © 1996 John Wiley & Sons, Inc.     

Synthesis and thermal crosslinking reaction of polymers containing pendant carboxyl and epoxy groups

Polymers containing both pendant carboxyl and epoxy groups were synthesized by the radical copolymerization of p-vinylbenzyl glycidyl ether (VBGE) and itaconic acid monomethyl ester (IAME). The copolymerization proceeded smoothly under various conditions, and polymer soluble in 1,4-dioxane with no gel fraction was obtained. However, the carboxyl-epoxy addition reaction between VBGE and IAME was observed, when DMSO or DMF were used as polymerization solvents. The IR and ¹H-NMR spectrum of copolymers of VBGE and IAME showed the corresponding structure. The thermal crosslinking reaction of the resulting copolymers was examined under various conditions. Tetrabutylammonium bromide (TBAB) showed catalytic activity for the reaction. However, a 100% gel fraction of polymer was achieved after only 15 min without any catalyst, when the crosslinking reaction was performed at 150°C. © 1996 John Wiley & Sons, Inc.