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61.
In the present work, corrosion resistance of surface-coated galvanized steel was quantitatively determined by an analysis
of the alternating current (AC) impedance spectra measured on the salt-spray-tested specimen. To evaluate the corrosion resistance
of the surface-coated galvanized steel, AC impedance spectroscopy was performed on the salt-spray-tested specimen previously
exposed to salt-sprayed corrosive environment. From the analysis of the impedance spectra, the area fraction transient of
white rust θ
2(t) was theoretically derived from the equivalent circuit equation by using two fitting parameters. The values of the two fitting
parameters were determined by fitting the empirical transient equations to the area fraction of the resin coating layer and
to the total resistance obtained from the impedance spectra measured, respectively. From the analyses of θ
2(t) for four kinds of surface-coated galvanized steels with various resin coating layers, it is indicated that as the values
of the two fitting parameters decrease in the order of CP, GI, OD and OM (commercial trade names) specimens, the corrosion
resistance increases in that order as well. Furthermore, from the quantitative comparison of the two fitting parameters with
the polarization resistance of the upper resin coating layer R
p determined from the potentiodynamic polarization curve, it is suggested that the two fitting parameters decrease in value
as well with increasing R
p. 相似文献
62.
The spatial relaxation of electrons to homogeneous states under the action of space-independent electric fields is investigated
in helium, krypton, and N2 plasmas for various electric field strengths. These investigations are based on a new method recently developed for solving
the one-dimensional inhomogeneous electron Boltzmann equation in weakly ionized, collision-dominated plasmas. Elastic as well
as conservative inelastic collisions of electrons with gas atoms have been included in the kinetic treatment. The spatial
relaxation is caused by an imposed direct disturbance in the velocity distribution of the electrons on a spatial boundary.
A pronounced dependence of the relaxation structure and the resultant relaxation length on the atomic data of the electron
collision processes in different gases has been found. Furthermore the relaxation process sensitively depends on the electric
field strength in the region of medium field values. 相似文献
63.
An investigation of heparinase immobilization 总被引:1,自引:0,他引:1
Bernstein Howard Yang Victor C. Langer Robert 《Applied biochemistry and biotechnology》1987,16(1):129-143
A systematic investigation of the parameters that affect the efficiency of immobilizing heparinase onto cyanogen bromide activated
crosslinked 8% agarose beads was conducted. Two experimental measures, the “fraction bound” and the “fraction retained,” were
used to monitor the coupling efficiency. The fraction bound is the portion of the total initial enzyme that is bound to the
agarose gel. The fraction retained is the fraction of bound enzyme that is active. The product of the two measures indicates
the coupling efficiency. The activity of the immobilized heparinase was measured under conditions free of both internal and
external mass transfer limitations, and thus, the fraction retained represents the true immobilized enzyme activity.
Increasing the degree of activation of the beads results in an increase in the fraction bound, the fraction retained, and
consequently, the coupling efficiency. As the ratio of enzyme solution to gel volume increases from 1.5 to 2.2, the fraction
bound remains constant but the fraction retained decreases (heparinase concentration; 0.15 mg/mL and degree of activation;
9.5 μmol of cyanate esters/g of gel). At volume ratios greater than 2.2, both the fraction bound and the fraction retained
decline continuously. Changing the heparinase concentration in the coupling solution changes the coupling efficiency in a
manner similar to that of the volume ratio change.
When heparin is added during the coupling process, the fraction bound declines as the heparin concentration increases, whereas
the fraction retained increases up to a heparin concentration of 12 mg/mL and decreases thereafter. When arginine, lysine,
and glycine are used to block the unreacted cyanate ester groups after the coupling process, the immobilized heparinase shows
different pH optima of 6.5, 6.9, and 7.2, respectively. Based upon these findings, a protocol to optimize heparinase immobilization
is developed. 相似文献
64.
A three-phase model, comprising crystalline, mobile amorphous, and rigid amorphous fractions (χ
c, χ
MA, χ
RA, respectively) has been applied in the study of semicrystalline Nylon-6. The samples studied were Nylon-6 alpha phase prepared
by subsequent annealing of a parent sample slowly cooled from the melt. The treated samples were annealed at 110°C, then briefly
heated to 136°C, then re-annealed at 110°C. Temperature-modulated differential scanning calorimetry (TMDSC) measurements allow
the devitrification of the rigid amorphous fraction to be examined.
We observe a lower endotherm, termed the ‘annealing’ peak in the non-reversing heat flow after annealing at 110°C. By brief
heating above this lower endotherm and immediately quenching in LN2-cooled glass beads, the glass transition temperature and χ
RA decrease substantially, χ
MA increases, and the annealing peak disappears. The annealing peak corresponds to the point at which partial de-vitrification
of the rigid amorphous fraction (RAF) occurs. Re-annealing at 110°C causes the glass transition and χ
RA to increase, and χ
MA to decrease. None of these treatments affected the measured degree of crystallinity, but it cannot be excluded that crystal
reorganization or recrystallization may also occur at the annealing peak, contributing to the de-vitrification of the rigid
amorphous fraction.
Using a combined approach of thermal analysis with wide and small angle X-ray scattering, we analyze the location of the rigid
amorphous and mobile amorphous fractions within the context of the Heterogeneous and Homogeneous Stack Models. Results show
the homogeneous stack model is the correct one for Nylon-6. The cooperativity length (ξA) increases with a decrease of rigid amorphous fraction, or, increase of the mobile amorphous fraction. Devitrification of
some of the RAF leads to the broadening of the glass transition region and shift of T
g. 相似文献
65.
以计量置换吸附理论(SDT A)为基础,从理论上推导出计量吸附模型中表征溶质对固定相亲合势大小的参数βa值与流动相中强置换剂浓度的对数呈线性关系。计量置换模型中的参数n和q(n和q分别代表1摩尔溶剂化溶质被吸附时,从吸附剂表面和从溶质分子表面所释放出的溶剂的物质的量)是计量置换参数Z值的分量,是两个非常有用的参数,可以从这个定量关系中直接获得。推导出的方程用苯的衍生物进行了实验验证,获得了较满意的结果。将这种方法计算得到的分量值与SDT A与计量置换保留模型(SDT R)相结合的方法得到的分量值进行了比较。 相似文献
66.
Excess volumes (VE) ultrasonic sound velocities (u), isentropic compressibilities (Ks) and viscosities (η) have been measured for the binary mixtures of dimethylsulphoxide (DMSO) with 1,2-dichlorobenzene, 1,3-dichlorobenzene, 1,2,4-trichlorobenzene, o-chlorotoluene, m-chlorotoluene, p-chlorotoluene, o-nitrotoluene and m-nitrotoluene at T = 303.15 K. The measured VE values were positive over the entire composition range in all the binary mixtures. Isentropic compressibilities (Ks) have been computed for the same systems from precise sound velocity and density data. Further, deviation in isentropic compressibility (ΔKs) from ideal behaviour was also calculated. The viscosity data are analysed on the basis of corresponding states approach. Deviation in viscosities are positive over the entire composition range. The measured data is explained on the basis of intermolecular interactions between unlike molecules. 相似文献
67.
The regions of variation of density, enthalpy of formation, and detonation velocity of all of the formally possible structual isomers were determined for several molecular formulas of C,H,N,O-containing explosives. The histograms of the distribution of the structual isomers over these parameters were constructed.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 859–862, May, 1995.The authors are grateful to Mrs. I. D. Solodukhina for the design of the graphical material.The work was carried out with the financial support of the Russian Foundation for Basic Research (Project No. 94-03-09323). 相似文献
68.
Denis J. Evans 《Journal of statistical physics》1979,20(5):547-555
Nonequilibrium molecular dynamics calculations are used to show that polyatomic fluids can support antisymmetric stress. In a homogeneous system where the time dependence of vorticity is a step function, it is shown that the rate at which intrinsic angular velocity approaches its steady-state value ( = 1/2 × u) is determined by the magnitude of the antisymmetric part of the pressure tensor. 相似文献
69.
It is of engineering importance to accurately predict the surface cooling characteristics in bath quenching of metals and alloys. In this investigation, the surface cooling characteristics in quenching of Wolfson probe are estimated with reasonable accuracy by solving an inverse heat conduction problem. Regularization method is used for smoothening the input temperature measurements at probe center, for superior inversion estimates. The reverse pool-boiling curve is captured on bath quenching characteristic, plotted as cooling velocity versus surface temperature. The prime advantage is the bypassing of convection coefficients, which are uncertain in pool boiling. 相似文献
70.
The effective ionization coefficients and electron drift velocities in gas mixtures of CF3I with N2 and CO2 obtained from Boltzmann equation analysis 下载免费PDF全文
The electron swarm parameters including the density-normalized effective ionization coefficients(α-η)/N and the electron drift velocities V e are calculated for a gas mixture of CF3I with N2 and CO2 by solving the Boltzmann equation in the condition of a steady-state Townsend(SST) experiment.The overall density-reduced electric field strength is from 100 Td to 1000 Td(1 Td = 10-17V·cm2),while the CF3I content k in the gas mixture can be varied over the range from 0% to 100%.From the variation of(αη)/N with the CF3I mixture ratio k,the limiting field strength(E/N) lim for each CF3I concentration is derived.It is found that for the mixtures with 70% CF3I,the values of(E/N) lim are essentially the same as that for pure SF 6.Additionally,the global warming potential(GWP) and the liquefaction temperature of the gas mixtures are also taken into account to evaluate the possibility of application in the gas insulation of power equipment. 相似文献