船舶密闭舱室火灾过程及其模拟计算

密闭舱室火灾是一个三维非定常过程，压力升高是这一过程的重要特征。本文采用质量守恒的方法进行压力校正，建立了计算密闭舱室火灾过程的数学物理模型，数值计算采用非均匀交错网格，结果与实验和理论分析相符较好。     

建筑物内火灾烟羽流和顶蓬射流诱发的空气运动盐水模拟实验研究

盐水在清水中的扩散与火灾烟气在空气中的蔓延相似，因而可用盐水的扩散来模拟火灾烟气的蔓延；同样地，由于盐水的扩散而导致的环境清水的运动也可用来模拟烟气蔓延诱发的空气运动。基于这一原理，本文用实验的方法，研究了建筑物内初起火灾产生的烟羽流和顶蓬射流所诱发的空气运动，并对走廊空气层生长规律和运动特性进行了初步的测量和分析。所得结果基本合理，对建筑物通风排烟及疏散通道设计有帮助，从而为建筑火灾环境空气的运动的实验研究开辟了新的思路，也为火灾区域模拟提供了实验依据     

不同微波膨胀烟梗的化学感官特性研究

研究不同来源包括产地、部位、年份、品种的烟梗原料经相同的微波膨胀工艺处理后的常规化学成分、致香成分、主流烟气(主要包括抽吸口数、焦油、烟碱及一氧化碳释放量)及感官特性差异,指导微波膨胀梗丝在产品中的配伍应用,为建立不同来源微波膨胀梗原料的品质特征评价体系及微波膨胀梗丝的工业应用提供依据。结果表明:不同产地来源的微波膨胀梗丝常规化学成分、致香成分、主流烟气存在差异。不同年份的微波膨胀梗丝间感官质量无明显差异,不同产地、品种、部位来源的微波膨胀梗丝总体感官质量存在差异。     

轴心受压H型截面钢柱火灾行为的试验研究

本文对4根H型截面钢柱进行了火灾行为的试验研究。全部火灾试验采用自行研制的火灾试验炉,试验结果表明炉子性能稳定,使用方便。试验采用足尺试验形式,柱长3300mm。钢柱轴心受压,其中两个限制轴向变形,另两个不限制轴向变形。柱两端采用单向刀口支座,允许钢柱绕强轴转动。钢柱试验中考虑荷载大小和是否限制轴向变形两个因素。通过试验,得出了钢柱在火灾下的侧向变形和轴向变形随温度变化情况。试验证明:钢柱受火时,轴向变形明显的分为膨胀阶段和压缩阶段。压缩阶段很短,一旦进入压缩阶段,钢柱很快破坏。钢柱受到的外加荷载越大,其极限温度越低。限制轴向变形的钢柱极限温度降低。试验研究为今后钢结构火灾行为研究提供了依据。     

Comfortable, flexible upholstery fire barriers on base of bast, wool and thermostable fibres

The paper presents elastic barrier materials developed at the INF which play a role of filling and fire barrier material at the same time in upholstery furniture, reducing the development and spread of fire on flammable materials. The presented results of flammability and biophysical tests confirm the comfort of products.The developed barrier materials use natural fibres (wool, flax FR) characterized by good air permeability, hygroscopicity, moisture transport, elimination of electrostatic charges and have effect on climate of interiors also when blended with thermostable fibres such as Polyacrylate. These flexible structures based on blend of natural fibres and thermostable fibres with at least two barrier effects i.e. durable resistance to fire, thermal insulation, control of electrostatic phenomena.     

Comprehensive Theoretical and Experimental Studies on the CF3H Fire‐extinguishing Mechanism

In order to clarify the chemical suppression mechanisms of CF₃H, experimental and theoretical studies were conducted respectively in this paper. Firstly, the combustion species in low pressure laminar premixed flat methane flames with CF₃H addition is measured by synchrotron radiation molecular beam mass spectrometry (SR‐MBMS) experimentally. Fire suppression chemistry of CF₃H is investigated by selective detection of combustion radicals and intermediates in experimental process. Secondly, quantum chemistry calculations are performed to calculate the potential energy surfaces (PES) for the CF₃H unimolecular dissociation reaction and reactions of CF₃H with free radical OH and H at the B3LYP/6‐311++G** and QCISD(T)/6‐311++G** levels. Finally, the chemical suppression mechanism of CF₃H was discussed by comparing the theoretical calculation with experimental measurement.     

暴露于环境烟气中的大鼠尿样代谢物分析

4-(甲基亚硝胺基)-1-(3-吡啶基)-1-丁醇(NNAL)是烟草特有亚硝胺4-(甲基亚硝胺基)-1-(3-吡啶)-1-丁酮(NNK)在生物体内的一种代谢标记物,分析暴露于烟气中的生物体内NNAL的含量是研究卷烟烟气对生物体健康影响的有效手段.基于人体的个体差异性很大,本文以饲养的大鼠为研究对象,采用LC-MS/MS...     

地铁车站火灾风险的模糊综合评价

根据地铁车站火灾的特点,确定地铁车站火灾风险的评价指标体系及权重.运用模糊数学原理,建立地铁车站火灾风险的模糊综合评价模型,并应用模型对某地铁车站火灾风险进行评价,较好的反映该地铁车站火灾安全的实际状况.方法为地铁车站火灾风险评价提供了新的思路,也为地铁车站火灾的防治提供理论依据.     

卷烟主流烟气中巴豆醛在线光谱分析方法研究

卷烟主流烟气是卷烟燃烧时被人体吸食到体内的主要气体,其减焦降害已成为全社会高度关注的问题。在各种卷烟主流烟气组分中,巴豆醛以其强烈的基因毒性,成为国家规定的卷烟中七种主要有害指标物之一。传统的巴豆醛分析方法大都采用高效液相色谱法等实验室分析方法,需繁琐的样品前处理过程,无法测量巴豆醛的实时浓度,难以准确评估巴豆醛对人体健康的影响。为了快速、准确地检测卷烟主流烟气中的巴豆醛组分,本研究搭建了一套可以直接与吸烟机耦合的傅里叶红外光谱分析系统（FTIR）,并创新性开发过采样数据驱动光谱分析方法（ODDSA）,从复杂、变动的卷烟主流烟气中准确提取巴豆醛的光谱组分信息。ODDSA方法从实验设计入手,采用随机设计的思路尽可能模拟实际卷烟样品的分布范围,以构建具备良好光谱数据结构的样品集。在此基础上,创新性地将高密度小波变换引入红外光谱数据的处理过程中,以时/频双域过采样的方式提升了光谱解析分辨率,进而降低了其他基质组分对巴豆醛光谱信息的干扰。最后,发展改良竞争自适应重加权采样方法,从多倍冗余的高密度小波系数中准确提取待测物质的最佳变量组合,由此构建高质量的巴豆醛光谱定量分析模型。为了验证ODDSA方法的有效性,实验中采集了15种典型市售卷烟品牌,每个品牌在线采集8支样品的主流烟气红外光谱,随后采用随机挑选的25个验证集样本对ODDSA方法进行验证。结果表明,检验集的线性拟合系数为0.971,相对均方根误差为5.5%,其预测精度能有效满足卷烟主流烟气中巴豆醛的在线分析需求,并可拓展到环境二手烟气中其他组分的在线监测,进而为吸烟与健康评估提供全新手段。     

Fire retardancy of polyethylene‐alumina trihydrate containing clay as a synergist

The fire behavior of polyethylene combined with alumina trihydrate (ATH) and an oligomerically‐modified clay has been studied. The combination of polyethylene with 2.5% inorganic clay and 20% ATH gives a 73% reduction in the peak heat release rate (PHRR), which is the same as that obtained when 40% ATH is used alone. A further increase in the clay loading does not improve the fire properties. Mechanical properties, such as elongation at break, can be improved in comparing compounds with or without clay at the same reduction in PHRR. The oligomerically‐modified clay can also facilitate the melt blending process. Copyright © 2005 John Wiley & Sons, Ltd.