石墨炉原子吸收法中热解涂层石墨管在无标准分析法测定环境样品中铬的应用

本文探讨了热解涂层石墨管测定铬的最佳实验条件,研究了各种酸和干扰物质的基体效应,提出用浓氨水为基体改进剂克服高氯酸的干扰。比较了各原子化温度时的理论和实验特征量。使热解涂层石墨管有可能用于无标准分析法测定各种环境样品中的铬。     

Drag on two nonuniformly structured flocs moving along the axis of a cylindrical tube

The boundary effect on the drag on two identical, nonuniformly structured flocs moving along the axis of a cylindrical tube filled with a Newtonian fluid is investigated at a small to medium larger Reynolds number. A two-layer model is adopted to simulate various possible structures of a floc, and the flow field inside is described by Darcy–Brinkman model. The results of numerical simulation reveal that a convective flow is present in the rear region of a floc when Reynolds number is on the order of 40. The presence of the tube wall and/or the porous structure of a floc has the effect of reducing that convective flow. For a fixed level of the volume-average permeability of a floc, the influence of the tube wall on the drag depends upon floc structure; the influence on a nonuniformly structured floc is more significant than that on a uniformly structured floc. The more nonuniform the floc structure, the more appreciable the deviation of the drag coefficient–Reynolds number curve from a Stokes’-law-like relation becomes. The smaller the volume-average permeability of a floc and/or the smaller the separation distance between the two flocs, the greater is the deviation, but the presence of the tube wall has the effect of reducing that deviation.     

用原子捕获技术提高火焰原子吸收光谱法的灵敏度

采用简易的石英原子捕获器，使Ｃｕ，Ａｇ，Ａｕ，Ｚｎ，Ｃｄ，Ｐｂ，Ｓｂ，Ｂｉ等易挥发元素在空气－乙炔火焰原子吸收光谱法中的灵敏度提高了３～５倍，并有较好的精密度，相对标准偏差在１％左右，方法中用此技术测定了标准物质中Ｐｂ、Ｃｄ的含量，获得了满意的结果，它较之石墨炉原子吸收光地具有快速，简便的特点，具有较大的实用价值。     

用选择离子流动管质谱测定汽油和柴油蒸汽成分

采用选择离子流动管质谱(SIFT／MS)装置，以H30^ 、N0^ 为初始离子对汽油和柴油蒸汽进行了研究，质谱分析表明，汽油和柴油主要由C—H化合物组成，包括烷烃、环烷烃、烯烃、炔烃、二烯烃以及芳香烃。在这几种成分中，烷烃都占有最大的比例；汽油蒸汽和柴油蒸汽最大的区别是柴油蒸汽中长链大分子的挥发性C—H化合物所占的比例远远高于汽油蒸汽。文中还给出了以H30^ 、N0^ 为初始离子所得到的汽油蒸汽的质谱图，以及汽油、柴油蒸汽中各种成分的定量分析结果。     

The effect of gas injection on a thermal argon plasma flow in a water-cooled tube

The effect of gas injection on an atmospheric thermal argon plasma flow in a water-cooled tube was investigated experimentally and numerically. The injection gas is argon, helium, or nitrogen. The static pressure with helium injection increases greatly because of its high thermal conductivity, while little increase occurs for nitrogen injection because of the dissociation. The increasing rate of the static pressure depends on the ratio of the momentum term to the viscosity term. The heat flux to the tube wall with gas injection changes less than that without injection. The numerical results showed variations similar to the experimental ones.     

C12簇及其碳管烷C12H12的理论研究

C60和C70等碳笼烯的发现及其在新物质、新材料等研究领域中的重要性，激励人们去探索合成更多新型多面体碳簇化合物与碳元素类似物[1，2]．最近，两类新型多面体碳管笼烯的设想提出来了[3，4]应用HMO和MNDO方法对其稳定性变化规律、结构和成键特征进行了讨论.关于多苯的vanderWaals簇实验上已有广泛的调查[5，6]，理论上对其二聚物（C6H6）。的不同几何构型与稳定性进行了深入的研究[7]．本文采用abinitio计算有效势（effectivecorePotential）方法，对C12碳管元素簇和C12H12，碳管烷的平衡结构、稳定性和价键特征进行了理论预测．1…     

Influence of the variable wall thickness of the sample tubes and a quartz Dewar on the EPR signal intensity in a single TE102 and double TE104 rectangular cavity

The response of a single TE₁₀₂ and double TE₁₀₄ rectangular cavity to the insertion of samples contained in tubes with variable wall thickness and a quartz Dewar into the cavity has been analyzed. A direct, indirect, and concurrent (positive or negative) “lens effect” inside the double TE₁₀₄ rectangular cavity is discussed. The experimental dependence of the EPR signal intensity on the wall thickness of the sample tube, δ, for the line-like samples with identical length of the sample material column, L=30 mm, recorded in the microwave cavity showed a directly proportional increase of the relative “lens effect” with the increase of the wall thickness of the tube in the interval, δ∈<0.1 mm, >0.5 mm. The insertion of the variable-temperature double-wall quartz Dewar (home-built, resonant frequency shift, ca. −300 MHz) into the single TE₁₀₂ rectangular cavity showed the same relative “lens effect”, with ca. 1.5-time increase of the EPR signal intensity, for a point-like sample and the line-like samples with material columns of diameter of 1 and 1.3 mm, and wall thickness of the sample tubes, δ∈<0.1 mm, >0.5 mm. The increased effect of the Dewar arises because the active volume of the quartz Dewar tube walls is always much more larger than the active volume of the sample tube wall. In the case of the double TE₁₀₄ rectangular cavity, the insertion of the quartz Dewar: (i) into the same cavity, in which the sample is present, caused a direct “lens effect”, with ca. 1.8-fold increase of the EPR signal intensity; however, (ii) into the complementary cavity, in which the sample is absent, caused an indirect “lens effect”, with ca. 0.6-fold decrease of the EPR signal intensity. With the Dewar and sample in one cavity and a large empty sample tube in the complementary cavity, a concurrent (positive or negative) “lens effect” can be observed. Thus, the possible increase/decrease of the EPR signal intensity depends on the volume ratio of the quartz Dewar tube walls and large sample tube wall inserted into the double TE₁₀₄ rectangular cavity. Each of the above phenomena may be a significant source error in quantitative EPR spectrometry unless the samples to be compared in the quantitative EPR analysis are contained in sample tubes having the same wall thickness and each EPR spectra should be recorded inside an identical quartz Dewar.     

不同失效模式下轴压管状结构的吸能特性比较

圆管、方管等管状结构受轴向的压缩作用,是工程上常见的一种结构受力形式.由于几何尺寸、边界条件和材料特性的不同,管状结构可以发生5种不同的失效模式：渐进屈曲、整体失稳、翻转、膨胀和劈裂.本文综述了近年来管状结构在轴压作用下不同失效模式的理论建模、实验测试和数值仿真研究结果,并对5种失效模式的力学响应、能量吸收特性进行了对比与分析.     

侧向冲击载荷下钢管混凝土结构的动力响应及参数分析

采用刚塑性结构模态分析法和数值模拟方法,对侧向冲击载荷作用下的圆截面钢管混凝土结构进行了塑性动力分析。将钢管混凝土等效为刚塑性地基梁模型,给出了钢管混凝土构件跨中侧向变形的模态解析解,得到了冲击载荷作用下影响结构最终侧向变形的无量纲参数。利用ABAQUS/Explicit软件建立了钢管混凝土结构在侧向冲击作用下的动态响应数值模型并进行了计算分析,将理论预测值和数值模拟结果与试验结果进行了交叉对比。结合量纲分析和数值模型对影响构件最终变形的几何、物理参数及初始冲量进行了分析。结果表明：理论预测值和数值模拟结果与试验结果吻合较好,结构的塑性变形与理论假定的塑性铰分布一致。构件几何参数中,长径比和径厚比对其侧向最终变形有较大影响;冲击头相对宽度可改变构件的变形模态;相比于几何参数,钢管和混凝土芯层的物理参数对构件跨中挠度的影响较小;结构的侧向变形与初始冲量成二次幂相关。最后给出了理论分析参数的适用范围。刚塑性响应模态解可较好地预测钢管混凝土结构在侧向冲击载荷作用下的塑性变形行为。

     

0.22 THz高效率行波管的互作用计算

利用CST Microwave Studio 计算双排矩形梳状慢波结构的色散并据此确定了0.22 THz左右频段（D波段）行波管用慢波结构的尺寸参数。将相速再同步技术应用于基于双排矩形梳状慢波结构的D波段行波管中,用CST PIC模拟计算了4例具有不同周期构型的D波段行波管。结果证实：对于无集中衰减器的D波段行波管,在218~232 GHz范围内,相速再同步技术使得输出功率从10~13 W提高到19~28 W,电子效率从1.4%~2.2%提高到2.6%~3.9%;对于具有集中衰减器D波段行波管,在218~232 GHz范围内,相速再同步技术使得输出功率从8~16.8 W提高到32~41 W,电子效率从1.5%~2.8%提高到4.4%~5.7%。此外,无论行波管有无集中衰减器,相速再同步技术都明显改善了行波管的增益平坦度。