全文获取类型
收费全文 | 11780篇 |
免费 | 1997篇 |
国内免费 | 767篇 |
专业分类
化学 | 2657篇 |
晶体学 | 86篇 |
力学 | 539篇 |
综合类 | 66篇 |
数学 | 231篇 |
物理学 | 10965篇 |
出版年
2024年 | 15篇 |
2023年 | 39篇 |
2022年 | 166篇 |
2021年 | 203篇 |
2020年 | 242篇 |
2019年 | 131篇 |
2018年 | 203篇 |
2017年 | 396篇 |
2016年 | 460篇 |
2015年 | 395篇 |
2014年 | 824篇 |
2013年 | 790篇 |
2012年 | 783篇 |
2011年 | 883篇 |
2010年 | 625篇 |
2009年 | 796篇 |
2008年 | 987篇 |
2007年 | 961篇 |
2006年 | 876篇 |
2005年 | 748篇 |
2004年 | 639篇 |
2003年 | 596篇 |
2002年 | 391篇 |
2001年 | 378篇 |
2000年 | 346篇 |
1999年 | 288篇 |
1998年 | 256篇 |
1997年 | 220篇 |
1996年 | 177篇 |
1995年 | 153篇 |
1994年 | 125篇 |
1993年 | 76篇 |
1992年 | 90篇 |
1991年 | 63篇 |
1990年 | 49篇 |
1989年 | 39篇 |
1988年 | 20篇 |
1987年 | 24篇 |
1986年 | 21篇 |
1985年 | 15篇 |
1984年 | 14篇 |
1983年 | 11篇 |
1982年 | 9篇 |
1981年 | 6篇 |
1980年 | 2篇 |
1975年 | 4篇 |
1973年 | 2篇 |
1971年 | 1篇 |
1970年 | 1篇 |
1957年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
91.
I. G. Voigt-Martin Z. X. Zhang D. H. Yan A. Yakimanski R. Matschiner P. Krämer C. Glania R Wortmann N. Detzer D. Schollmeyer 《Colloid and polymer science》1997,275(1):18-37
4-Dimethylamino-3-cyanobiphenyl (4-DMA-3-CB) was characterized with respect to linear and nonlinear optical properties in
a crystal as well as in solution. The crystal structure was studied dependent on the crystallization conditions. It is shown
that the crystal structure exhibiting NLO-activity can completely be solved by a combination of electron diffraction and computer
modeling. There are four molecules per unit cell in the space group Pna21 with dimensions a=10.28 Å, b=22.64 Å, c=5.27 Å. From this model structure the values and orientation of the dipole μ and static second order polarizability β can
be calculated. Their relevance to the values obtained by a combination of polarization dependent measurements of Electric
Field Induced Second Harmonic Generation (EFISH) and Hyper-Rayleigh-Scattering (HRS) in solution are discussed. The molecular
second order polarizability tensor was found to be dominated by one single component. The orientations of the dipole and the
vectorial parts of the second order polarizability delivered by the semiempirical calculations are in good agreement with
the results of the EFISH and HRS-measurements and allow a deeper insight into the nonlinear optical properties of the crystal.
Received: 15 April 1996 Accepted: 21 June 1996 相似文献
92.
利用扫描电镜、热失重-红外、元素分析、低温氮吸附等技术和化学手段对聚羧酸基FFC-1离子交换纤维的结构与性能特点等进行了系统研究.结果表明:FFC-1离子交换纤维为含适量酰肼类交联键的聚羧酸(钠)型离子交换材料,外比表面积大和传质距离短是其反应动力学性能优异的主要原因,FFC-1纤维具有良好的化学与热稳定性。在5mol/L硫酸、硝酸、盐酸和2mol/L氢氧化钠溶液中浸泡,交换容量未见明显降低。但过氧化氢溶液对其功能基有明显破坏,CO2为FFC-1纤维在高温区间(300℃~350℃)的主要分解产物。 相似文献
93.
Coherent anti-Stokes Raman scattering (CARS) microscopy is presented as a new nonlinear optical technique. The combination of vibrational spectroscopy and microscopy allows highly sensitive investigations of unlabelled samples. CARS is an ideal tool for studying a broad variety of samples. The main drawback of the technique is its non-zero-background nature, which implies that the signal has to be detected against a nonresonant background. The need to solve this problem is reflected in the rapid technological developments that have been observed during the last decade. Recent results show that CARS microscopy has the potential to become an important complementary technique that can be used with other well-established microscopic methods. Although it has some limitations, it offers unique access to many problems that cannot be tackled with conventional techniques. For this reason, it can be expected that the impressive growth of the field will continue. 相似文献
94.
FFC-1离子交换纤维对酸碱有害气体吸附性能的研究 总被引:8,自引:0,他引:8
系统考察了不同直径及反离子形式的FFC-1聚羧酸离子交换纤维对酸碱有害气体的穿透吸附,各种温、湿度条件下的吸水率,以及作为有害气体吸附滤除材料的重复使用与再生性能。研究表明:FFC-1纤维直径的减小有利于提高对有害气体的动态吸附容量。在体系温度、相对湿度分别为15℃、50%时,以3D腈纶为起始原料的钠型FFC-1离子交换纤维的吸水率≥350mg/g.纤维;对SO2的穿透吸附容量可达200mg/g.纤维。FFC-1离子交换纤维具有良好的重复使用与再生能力,经20次再生循环使用后,纤维交换容量未见明显变化。 相似文献
95.
JieLiang Bi-qianLiu 《高分子科学》2005,(1):83-92
Plasma-induced surface graft copolymerization of acrylic acid on polypropylene non-woven fabric (PP-g-AA) and polypropylene membrane were reported. The extents of grafting were controlled by the plasma and polymerization condition. Hexadecyltrimethyl ammonium bromide was then coupled with the carboxyl group of PP-g-AA to obtain a polyion complex (PIC). At last, CF4 plasma was used to give PICs hydrophobic property. The moisture regain and water-repellency of the processed PICs was investigated. The surfaces were characterized using ATR FT-IR and XPS. The result indicates that the products have very high ability to adsorb moisture, even better than cotton fiber. At the same time, the products show excellent hydrophobic property, which can‘t be wetted by those reagents whose surface tensions were higher than 327mN/m. 相似文献
96.
CHEN Shuixia LIU Jinrong ZHANG Xiaoping ZENG Hanmin Materials Science Institute Zhongshan University Guangzhou Department of Environmental Science Engineering South China University of Technology Guangzhou P. R. China 《Chinese Journal of Reactive Polymers》2002,(2)
1. INTRODUCTION Microbial pollution will bring about various problems in industry and other vital fields, such as causing decomposing of materials, harming people抯 health. In order to reduce these problems, new antibacterial materials have been demanded. Recently, much attention has been paid to inorganic materials including zinc oxide [1~4]. These inorganic antibacterial materials are now substituting for organic materials to avoid releasing noxious organic molecules harmful to humans;… 相似文献
97.
Poly(4-methyl-1-pentene) (PMP) hollow fiber membranes were prepared by the melt-spun and cold-stretch(MSCS) method. Scanning electronic microscopy (SEM) was used to characterize the section and surface structures of themembranes with special asymmetric structure. The preliminary results of gas permeation measurements indicated that the resultant hollow fiber membranes have the potential ability for oxygen/nitrogen separation. 相似文献
98.
通过镁离子内扩散铌酸锂单晶光纤,以改变晶纤表层的折射率,首次在国内实现了沿不同轴向生长、不同掺杂的铌酸锂单晶光纤的芯-包层波导结构。通过匹配扩散温度、扩散时间、MgO膜厚等扩散参数及选择合适的晶纤直径,实现了晶纤具有阶跃和抛物折射率分布的包层,并对包层晶纤的模式特性进行了观察,得到低次模传输。 相似文献
99.
《Journal of separation science》2003,26(11):1057-1062
The use of glass fiber as a support material for a surface compound serving to generate gaseous standard mixtures of ethene is described. The technique is based on the process of thermal decomposition of the surface compound in a desorber connected on‐line via a multi‐port valve to the calibrated device. The surface compound undergoes thermal decomposition at 245°C, yielding known amounts of ethene. The method enables on‐line preparation of a standard mixture immediately before the calibration step. Consequently, it can be also applied for the generation of standard mixtures containing volatile, malodorous, unstable, and toxic compounds. 相似文献
100.
Masahiro Toyoda Yukio Hamaji Kunisaburo Tomono 《Journal of Sol-Gel Science and Technology》1997,9(1):71-84
The sol-gel processing was applied to the fabrication of PbTiO3 fibers. Pb(CH3COO)2·3H2O and Ti(OC3H
7
i
)4 were refluxed with stirring in 2-methoxyethanol to form Pb-methoxyethoxide and Ti-methoxyethoxide, respectively, followed
by mixing with stirring in 2-methoxyethanol to form Pb−Ti double alkoxide. The hydrolysis and polycondensation reaction of
this double alkoxide gave polymerized products, and as a result the viscosity of the solution increased, suggesting that linear
polymers were produced through the hydrolysis and polycondensation reaction. Homogeneous PbTiO3 gel fibers were drawn from the spinnable viscous solutions, which were wellcrystallized into perovskite type PbTiO3 at 650°C. The heat-treated fibers were a few centimeters long and from 10 to 100 μm in diameter. The fiber was made up of
extremely uniform grains. Electron diffraction revealed a preferred growth of (101) planes along the fiber axis, which might
be due to the linear molecular characteristics of the alkoxide. 相似文献