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51.
利用直流磁控溅射技术在玻璃衬底上沉积了TiO2薄膜,并对其进行了Co离子注入,最后在真空中500 ℃退火50 min,得到系列薄膜样品. 利用剥离-分散方法制备了薄膜的透射电镜样品,并用扫描电镜(SEM)、X射线能量散射谱(EDX)和高分辨透射电镜(HRTEM)对样品做了近似原位观察,研究了薄膜样品中不同Co离子注入深度的成分分布和显微结构. 结果表明,薄膜呈锐钛矿结构,Co元素主要分布在薄膜表层,Co离子的注入使TiO2薄膜的晶粒被部分破坏,并形成CoO,而5
关键词:
2薄膜')" href="#">Co注入TiO2薄膜
电镜原位观察
室温铁磁性 相似文献
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53.
本在2K~20K温区内系统地研究了Er1-xDyxNi2B2C体系中超导转变温度Tc的反铁磁转变温度TN随Dy掺杂含量x的变化.实验发现x=0.3和x=0.8附近的样品具有复杂的磁结构.这些洋品有两个磁转变温度(TN’和TN).对于该体系发现了两个主要的特征:1)在x=0.3附近,超导被抑制,TN’出现一个小的峰值;2)在x=0.8附近,Tc出现一个低谷,TN’出现一个大的宽峰.TN’在x=0.3和x=0.8附近的异常来源于改系统中超导和磁性的共存和相互作用。 相似文献
54.
利用固相反应法制备了名义成分为Ca(Mn2Cu1)Mn4O12的类钙钛矿锰氧化物.x射线衍射表明,为了获得较为致密的样品和减小杂相含量,可以采用高温烧结再在1073K长时间空气中退火的制备方法.样品在低温下同时存在铁磁相和反铁磁相,由于反铁磁相的存在导致样品在4.5K时的磁化强度显著降低,并在8T的高磁场下仍未达到饱和.样品呈半导体导电性质,在85K和6T磁场下磁电阻比的最大值可达-46%.
关键词:
[AC3](B4)O12类钙钛矿锰氧化物
庞磁电阻效应
铁磁性
反铁磁性 相似文献
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Dr. Logesh Mathivathanan Dr. Guillaume Rogez Dr. Nadia Ben Amor Prof. Vincent Robert Prof. Raphael G. Raptis Dr. Athanassios K. Boudalis 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(56):12769-12784
Previously reported ferromagnetic triangles (NnBu4)2[Cu3(μ3-Cl)2(μ-4-NO2-pz)3Cl3] ( 1 ), (PPN)2[Cu3(μ3-Cl)2(μ-pz)3Cl3] ( 2 ), (bmim)2[Cu3(μ3-Cl)2(μ-pz)3Cl3] ( 3 ) and newly reported (PPh4)2[Cu3(μ3-Cl)2(μ-4-Ph-pz)3Cl3] ( 4 ) were studied by magnetic susceptometry, electron paramagnetic resonance (EPR) spectroscopy and ab initio calculations to assess the origins of their ferromagnetism and of the magnetic anisotropy of their ground S=3/2 state (PPN+=bis(triphenylphosphine)iminium, bmim+=1-butyl-3-methylbenzimidazolium, pz−=pyrazolate). Ab initio studies revealed the d character of the magnetic orbitals of the compressed trigonal bipyramidal copper(II) ions. Ferromagnetic interactions were attributed to weak orbital overlap via the pyrazolate bridges. From the wavefunctions expansions, the ratios of the magnetic couplings were determined, which were indeterminate by magnetic susceptometry. Single-crystal EPR studies of 1 were carried out to extend the spin Hamiltonian with terms which induce zero-field splitting (zfs), namely dipolar interactions, anisotropic exchange and Dzyaloshinskii–Moriya interactions (DMI). The data were treated through both a giant-spin model and through a multispin exchange-coupled model. The latter indicated that ≈62 % of the zfs is due to anisotropic and ≈38 % due to dipolar interactions. The powder EPR data of all complexes were fitted to a simplified form of the multispin model and the anisotropic and dipolar contributions to the ground state zfs were estimated. 相似文献
58.
Viktor V. Struzhkin Russell J. Hemley Ho-kwang Mao Yuri A. Timofeev Mikhail I. Eremets 《Hyperfine Interactions》2000,128(1-3):323-343
Numerous recent developments in diamond-cell techniques are making possible a growing range of studies of the electronic and
magnetic properties of materials to megabar pressures. We review recent advances in this area, including magnetic susceptibility,
electrical conductivity, and synchrotron-based spectroscopic techniques. Highly sensitive magnetic susceptibility techniques
have allowed the first observations of superconductivity at megabar pressures, including the observation of a Tc of 17 K in sulfur at 160 GPa, and a nearly pressure-independent Tc to above 230 GPa. The technique has recently been extended to allow measurements of the magnetic properties of ferromagnetic
substances. Advances in the direct measurement of electrical conductivity using miniaturized leads have permitted measurements
on H2O and Xe to above 100 GPa. Pressure-induced high-spin to low-spin transitions have been examined in FeS and FeO using new
high-resolution X-ray emission techniques. New high-pressure inelastic scattering methods, including nuclear inelastic scattering
techniques, have been used to determine the phonon density of states of Fe to above 150 GPa.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
59.
A. Fakhim Lamrani M. Belaiche A. Benyoussef A. El Kenz 《Journal of magnetism and magnetic materials》2010,322(4):454-458
The electronic structure and ferromagnetic properties of rutile TiO2 doped with double-impurities Ti1−2xCrxMnxO2 has been investigated using first-principles calculations within the density-functional theory (DFT) and the local density approximation (LDA), functional for treating the effects of exchange and correlation. They were performed using the scalar-relativistic implementation of the augmented spherical wave (ASW). The advantages of doping TiO2 with double impurities instead of single impurities are the increase of the total moment of the system and the exhibition of the half-metallic ferromagnetic nature in Cr- and Mn-doped TiO2 rutile. These behaviors are due to the hybridization of Cr 3d states and nearest-neighboring O 2p states. The spin-spin interaction between magnetic impurities examined by the total energy between parallel and antiparallel aligned states indicated that the Cr and Mn impurities are energetically favorable to be parallel coupled, which mean that the ferromagnetic state is more stable than the ferrimagnetic one. We proposed a bond magnetic polarons (BMP) model, based on localized carriers, to explain the mechanism of ferromagnetism in these systems. 相似文献
60.
J.M. Wesselinowa 《Journal of magnetism and magnetic materials》2010,322(17):L34
Based on the Heisenberg model including single-ion anisotropy and using a Green's function technique we have studied the influence of doping effects on magnetization M, Neel temperature TN and coercive field Hc of antiferromagnetic nanoparticles. We have shown that the experimentally obtained room temperature magnetization M is due to surface or/and doping effects in antiferromagnetic nanoparticles. 相似文献