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101.
V. Rusanov H. Winkler C. Ober A.X. Trautwein 《The European Physical Journal B - Condensed Matter and Complex Systems》1999,12(2):191-198
M?ssbauer studies were performed on single crystals of guanidinium nitroprusside with different orientations of their principal
crystallographic axes (a, b, c) with respect to the incident radiation. The markedly anisotropic Lamb-M?ssbauer factor f
LM
, i.e.
f
LM
(a) = 0.118(8), f
LM
(b) = 0.174(8), f
LM
(c) = 0.202(8) is in contrast to that of nitroprussides with inorganic anions. The observed anisotropy is ascribed to the anisotropic
vibrational mean-square displacement of the nitroprusside anions as a whole which is due to the specific packing of both,
anions and cations, as well as the very weak chemical bonding between the ions, typical only for guanidinium nitroprusside.
The vibrational anisotropy of iron atoms in barium nitroprusside that has been observed by X-ray structural investigations
has a different origin and therefore does not result in an anisotropic Lamb-M?ssbauer factor. We have also investigated metastable
states in guanidinium nitroprusside that have been populated by means of incoherent irradiation from light-emitting diodes.
With a specific orientation of the guanidinium nitroprusside single crystal a population of the metastable states up to 26%
could be achieved. Populations of comparable size on lithium, sodium and potassium nitroprussides have only been reached using
coherent laser irradiation.
Received 15 December 1998 and Received in final form 3 March 1999 相似文献
102.
Teichroeb JH Forrest JA Ngai V Jones LW 《The European physical journal. E, Soft matter》2006,21(1):19-24
We have used localized surface plasmon resonance (LSPR) to monitor the structural changes that accompany thermal denaturing
of bovine serum albumin (BSA) adsorbed onto gold nanospheres of size 5nm-60nm. The effect of the protein on the LSPR was monitored
by visible extinction spectroscopy. The position of the resonance is affected by the conformation of the adsorbed protein
layer, and as such can be used as a very sensitive probe of thermal denaturing that is specific to the adsorbed protein. The
results are compared to detailed calculations and show that full calculations can lead to significant increases in knowledge
where gold nanospheres are used as biosensors. Thermal denaturing on spheres with diameter > 20 nm show strong similarity
to bulk calorimetric studies of BSA in solution. BSA adsorbed on nanospheres with d ⩽ 15nm shows a qualitative difference in behavior, suggesting a sensitivity of denaturing characteristics on local surface
curvature. This may have important implications for other protein-nanoparticle interactions. 相似文献
103.
104.
The DTL tank is a multi-cell cavity.In a fabricated tank,the measured average axial field E0 for each cell may obviously deviate from the designed value.It is generally thought the deviation is due to the errors in fabrication and assembly.But it is not always true.In this paper,it is shown that the deviation may already exist before fabrication in some cases.It is partly due to the imperfection of the current design procedures.A new design method is introduced to reduce the deviation in the design stage. 相似文献
105.
M. A.?Naveed N. U.?Rehman S.?Zeb S.?Hussain M.?ZakaullahEmail author 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2008,47(3):395-402
This paper reports the effect of helium percentage variation in a capacitive RF helium-nitrogen mixture plasma on various
plasma parameters and concentration of nitrogen active species (N2(C3Π u) and N2
+(B2Σ u
+)). Langmuir probe is used for determination of electron energy distribution functions, effective electron temperature, plasma
potential and electron density. Optical emission spectroscopy is used for determination of electron temperature from Boltzmann's
plot of He–I lines and the relative changes in the concentration of active species by measuring the emission intensities of
nitrogen (0-0) bands of the second positive and the first negative systems. The results demonstrate that electron temperature,
electron density and concentration of active species increase significantly with increase in helium percentage in the mixture
and RF power. 相似文献
106.
Nb/Al-AlOx/Nb tunnel junctions are often used in the studies of macroscopic quantum phenomena and superconducting qubit applications of the Josephson devices. In this work, we describe a convenient and reliable process using electron beam lithography for the fabrication of high-quality, submicron-sized Nb/Al-AlOx/Nb Josephson junctions. The technique follows the well-known selective Nb etching process and produces high-quality junctions with Vm=100 mV at 2.3 K for the typical critical current density of 2.2 kA/cm^2, which can be adjusted by controlling the oxygen pressure and oxidation time during the formation of the tunnelling barrier. We present the results of the temperature dependence of the sub-gap current and in-plane magnetic-field dependence of the critical current, and compare them with the theoretical predictions. 相似文献
107.
This work investigates the problem of detecting gravitational wave (GW) events based on simulated damped sinusoid signals contaminated with white Gaussian noise. It is treated as a classification problem with one class for the interesting events. The proposed scheme consists of the following two successive steps: decomposing the data using a wavelet packet, representing the GW signal and noise using the derived decomposition coefficients; and determining the existence of any GW event using a convolutional neural network (CNN) with a logistic regression output layer. The characteristic of this work is its comprehensive investigations on CNN structure, detection window width, data resolution, wavelet packet decomposition and detection window overlap scheme. Extensive simulation experiments show excellent performances for reliable detection of signals with a range of GW model parameters and signal-to-noise ratios. While we use a simple waveform model in this study, we expect the method to be particularly valuable when the potential GW shapes are too complex to be characterized with a template bank. 相似文献
108.
《Journal of polymer science. Part A, Polymer chemistry》2018,56(1):147-153
The design rules for creating multifunctional organic electronic materials are currently limited. By copolymerizing twisted triphenylamine (TPA) and electron rich dioxythiophene (XDOT) monomers via Direct (Hetero) Arylation Polymerization (DHAP), a set of polymers are obtained that perform as yellow to transmissive electrochromic (EC) films with up to 45% contrast, as well as in electroluminescent (EL) applications, achieving a luminance of ∼450 cd/m2 in yellow‐green polymer light‐emitting diodes (PLEDs). In addition, polymerizing TPA with a donor‐acceptor‐donor monomer results in a low‐bandgap polymer that achieves power conversion efficiencies up to 2.5% when blended with PC71BM in conventional organic photovoltaic (OPV) devices. Incorporation of TPA units into the polymer backbone largely breaks any aggregation and ordering in the solid‐state, leading to highly soluble materials that form smooth, reproducible thin films. The TPA unit also serves to break conjugation throughout the polymer backbone, providing precise control over optical and electronic properties through choice of comonomer. These results suggest that TPA copolymers can be useful for achieving multi‐functionality without sacrificing facile solution processability, making them promising candidates for multifunctional devices like dual EC/EL displays. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2018 , 56, 147–153 相似文献
109.
《Electroanalysis》2018,30(2):345-352
We reported here three simple, low cost and easy to accomplish strategies for the fabrication of microelectrodes and other conductive patterns using ordinary office laser‐printers. In this work, toner patterns were directly printed onto the flexible substrate, acting as a mask to create the intended conductive design. To highlight the versatility of such technology, toner‐printed patterns were employed in two diverse ways: one in which the patterned toner had the exact design of the electrode and other employing a reverse toner‐printed pattern. The first one was used for the adaptation of the well‐known printed circuit board (PCB) fabrication technique, but using direct toner printing (DTP) in an already conductive flexible substrate. The second was employed for the two remaining strategies: one based on the deposition of conductive film, followed by lift‐off process; and another based on drop‐casting of a conductive ink into the formed toner cavities, followed by thermal cure. As proof‐of‐concept, all three DTP strategies were used for the fabrication of miniaturized gold electrodes in polyimide substrate, and electrochemical performance of each obtained electrode was evaluated by cyclic voltammetry. Insights about DTP technology, alignment issues, advantages, limitations and resolution of each presented approach were provided. Finally, direct toner printing showed to be a simple, affordable and quite promising technology for the fabrication of low cost point‐of‐care electrochemical devices using flexible platforms. 相似文献
110.
A new Schiff base was prepared as the condensation product of the reaction of 2‐quinoline carboxaldehyde and ambroxol drug. The Schiff base ligand thus obtained (HL; trans‐4‐[(2‐(2‐quinolinoimino)‐3,5‐dibromobenzyl)amino]cyclohexanol) was further employed as a tridentate ligand for the synthesis of new complexes through reaction with Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) metal ions. The synthesized HL and its metal complexes were characterized using various physicochemical techniques including elemental analysis, Fourier transform infrared and UV–visible spectroscopies, conductimetric and magnetic susceptibility measurements, mass spectrometry and thermal analyses. 1H NMR data indicated that complex formation was through the amino group rather than the aliphatic hydroxyl group. Thermal analysis gave an idea about the decomposition pattern of HL and its complexes. Also, it revealed the number of water molecules in the inner and outer spheres of the complexes. An octahedral geometry for all the complexes has been suggested. HL and its complexes were screened for their antimicrobial activity against various species of bacteria and fungi using the disc diffusion method. The Cr(III) complex had the highest antimicrobial activity. 相似文献