全文获取类型
收费全文 | 4783篇 |
免费 | 526篇 |
国内免费 | 371篇 |
专业分类
化学 | 2383篇 |
晶体学 | 100篇 |
力学 | 54篇 |
综合类 | 24篇 |
数学 | 15篇 |
物理学 | 3104篇 |
出版年
2024年 | 5篇 |
2023年 | 32篇 |
2022年 | 115篇 |
2021年 | 129篇 |
2020年 | 103篇 |
2019年 | 131篇 |
2018年 | 136篇 |
2017年 | 191篇 |
2016年 | 205篇 |
2015年 | 189篇 |
2014年 | 294篇 |
2013年 | 510篇 |
2012年 | 345篇 |
2011年 | 313篇 |
2010年 | 251篇 |
2009年 | 303篇 |
2008年 | 299篇 |
2007年 | 316篇 |
2006年 | 262篇 |
2005年 | 184篇 |
2004年 | 173篇 |
2003年 | 135篇 |
2002年 | 138篇 |
2001年 | 122篇 |
2000年 | 101篇 |
1999年 | 83篇 |
1998年 | 80篇 |
1997年 | 76篇 |
1996年 | 47篇 |
1995年 | 57篇 |
1994年 | 44篇 |
1993年 | 46篇 |
1992年 | 35篇 |
1991年 | 21篇 |
1990年 | 19篇 |
1989年 | 21篇 |
1988年 | 68篇 |
1987年 | 20篇 |
1986年 | 10篇 |
1985年 | 16篇 |
1984年 | 12篇 |
1983年 | 4篇 |
1982年 | 8篇 |
1981年 | 13篇 |
1980年 | 8篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1973年 | 1篇 |
1972年 | 2篇 |
1971年 | 1篇 |
排序方式: 共有5680条查询结果,搜索用时 15 毫秒
21.
22.
聚异丁烯高活性端基含量及相对分子质量测定方法的研究 总被引:2,自引:0,他引:2
综合使用核磁,VPO和近红外光谱分析技术对聚异丁烯活性端基含量以及相对分子质量的测定进行了详细研究,分别建立核测定聚异丁烯活性端基含量以及其他烯键含量和近红外光谱快速测量聚异聚丁烯活性端基含量。其他烯键含量和相对分子质量的分析方法。成对t检验结果表明,近红外光谱分析方法测定结果与核磁和VPO方法测定结果之间无显著性差异。 相似文献
23.
24.
用区域分解算法结合蒙特卡罗法求坦克温度场和红外辐射出射度 总被引:3,自引:0,他引:3
本文将区域分解算法和蒙特卡罗法相结合,求坦克温度场和红外辐射出射度.采用蒙特卡罗法计算辐射传递系数,可以考虑界面的复杂辐射特性,如:镜反射、各向异性发射、各向异性反射等;可直接考虑界面的复杂几何特性,如:相互遮挡、太阳入射方向上的投影面积等.引入辐射传递系数,分离了计算的难点,使得在时间域(计算步骤)上能把整个问题分解为若干个子问题并行处理、在空间域(计算区域)上将坦克分解为若干个子区域,缩小计算规模,并可使用多个处理器并行计算;同时减轻了蒙特卡罗法编程的难度,缩短了计算时间. 相似文献
25.
采用从头计算方法,计算了反式和顺式聚乙炔的氢原子在垂直于聚乙炔分子面方向振动的红外光谱,计算表明,Gibson等用红外吸收实验所测得的谱线的确是聚乙炔的CH面外振动产生的谱线,经100℃长时间加热后,顺式聚乙炔变为反式聚炔,但波数为740cm^-1的谱级仍保留5%的强度。 相似文献
26.
Ajay K. Saini Clifford M. Carlin Howard H. Patterson 《Journal of polymer science. Part A, Polymer chemistry》1992,30(3):419-427
New model compounds for poly[N,N′-bis(phenoxyphenyl)pyromellitimide] have been synthesized in order to investigate the formation of imine bonds which are proposed to form during the curing process and lead to crosslinking in the bulk polymer. Raman studies show that terminal amines can react with imide carbonyls during curing to form C?N bonds. The Raman band due to C?N appears at 1656 cm?1 and the band due to C?O closest to the imine bond is observed at 1742 cm?1. These results are in agreement with previously published results on vapor deposited polyimide films. 相似文献
27.
Michaël Lejeune Andrea Valsesia Martin Kormunda Pascal Colpo François Rossi 《Surface science》2005,583(1):L142
In this work, chemically and topographically nanopatterned surfaces were produced by a top-down processing approach for biosensing devices. The nanopatterning was the result of the combination of plasma polymerisation (pp) of biofunctional materials and colloidal lithography techniques. The morphological and chemical properties induced by the plasma deposition-etching treatment were characterised by optical method combining ellipsometry and Fourier Transform Infrared spectroscopy studies. This method supported by atomic force microscopy measurements, allowed the full optical characterization of each step of the top-down process. The optical characterization of the end-up nanopatterned samples demonstrated that the chosen process is able to produce well-defined nanostructured surfaces with controlled chemical and morphological properties. 相似文献
28.
R. Rehm M. Walther J. Schmitz J. Fleißner F. Fuchs J. Ziegler W. Cabanski 《Opto-Electronics Review》2006,14(1):19-24
The first fully operational mid-IR (3–5 μm) 256×256 IR-FPA camera system based on a type-II InAs/GaSb short-period superlattice
showing an excellent noise equivalent temperature difference below 10 mK and a very uniform performance has been realized.
We report on the development and fabrication of the detecor chip, i.e., epitaxy, processing technology and electro-optical
characterization of fully integrated InAs/GaSb superlattice focal plane arrays. While the superlattice design employed for
the first demonstrator camera yielded a quantum efficiency around 30%, a superlattice structure grown with a thicker active
layer and an optimized V/III BEP ratio during growth of the InAs layers exhibits a significant increase in quantum efficiency.
Quantitative responsivity measurements reveal a quantum efficiency of about 60% for InAs/GaSb superlattice focal plane arrays
after implementing this design improvement.
The paper presented there appears in Infrared Photoelectronics, edited by Antoni Rogalski, Eustace L. Dereniak, Fiodor F. Sizov, Proc. SPIE Vol. 5957, 595707 (2005). 相似文献
29.
Tamara Elzein Virginie Kreim Achraf Ghorbal Sophie Bistac 《Journal of Polymer Science.Polymer Physics》2006,44(22):3272-3281
Friction‐deposited layers of atactic polystyrene (PS) on inert and OH‐grafted gold substrates were the subject of this study to establish a relationship between the friction process and the resulting anisotropy of the transferred polymer chains. We show, by using polarization‐modulation infrared reflection‐absorption spectroscopy that the deposited PS chains involve an anisotropy in which PS main backbone is rather perpendicular to the friction support, fact that is surprising when compared with the majority of polymers where the anisotropy is along the sliding direction. Moreover, our calculation of the orientation angles revealed that PS chains are more perpendicular in the transferred layers than in spin‐coated films. This particular anisotropy is probably due to a parallel reorientation of the phenyl ring on the friction support whatever the surface chemistry is. On the other hand, this study was useful to rectify the assignment of infrared bands unclearly reported in the literature. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3272–3281, 2006 相似文献
30.
太赫兹半导体探测器研究进展 总被引:4,自引:0,他引:4
太赫兹(THz)探测器是THz技术应用的关键器件之一.基于半导体的全固态THz量子阱探测器(THzQWIP)具有探测响应速度快、制作工艺成熟、体积小和易集成等优点.文章简要介绍了THz探测器的分类和特点,重点介绍了THzQWIP的工作原理和研究进展. 相似文献