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21.
In the last years, the development of new methods for analyzing accurate and precise individual metalloproteins is of increasing importance, since numerous metalloproteins are excellent biomarkers of oxidative stress and diseases. In that way, methods based on the use of post column isotopic dilution analysis (IDA) or enriched protein standards are required to obtain a sufficient degree of accuracy, precision and high limits of detection. This paper reports the identification and absolute quantification of Cu,Zn-superoxide dismutase (Cu,Zn-SOD) in cytosol and mitochondria from mice hepatic cells using a innovative column switching analytical approach. The method consisted of orthogonal chromatographic systems coupled to inductively coupling plasma-mass spectrometry equipped with a octopole reaction systems (ICP-ORS-MS) and UV detectors: size exclusion fractionation (SEC) of the cytosolic and mitochondrial extracts followed by online anion exchange chromatographic (AEC) separation of Cu/Zn containing species. After purification, Cu,Zn-SOD was identified after tryptic digestion by molecular mass spectrometry (MS). The MS/MS spectrum of a doubly charged peptide was used to obtain the sequence of the protein using the MASCOT searching engine. This optimized methodology reduces the time of analysis and avoids the use of sample preconcentration and clean-up procedures, such as cut-off centrifuged filters, solid phase extraction (SPE), precipitation procedures, off-line fractions insolates, etc. In this sense, the method is robust, reliable and fast with typical chromatographic run time less than 20 min. Precision in terms of relative standard deviation (n = 5) is of 3–5% and detection limits is 0.21 ng Cu g−1. 相似文献
22.
Hong‐Jian Wang Paul v. R. Schleyer Judy I. Wu Yan Wang Hai‐Jun Wang 《International journal of quantum chemistry》2011,111(5):1031-1038
The resonance energies (REs) of neutral three membered ring analogs of the cyclopropenyl cation, computed using block localized wave function (BLW) methods, reveal considerable variations. The RE's of cyclopropenes substituted with exocyclic double bonded groups C?X, (X = O, NH, CH2, S, PH, SiH2) increase with the electronegativity of X in the same row (SiH2 < PH < S and CH2 < NH < O). The extra cyclic resonance energies (ECREs) (an energetic measure of aromaticity based on comparisons with the RE's of acyclic models) of these derivatives range from +10.5 kcal/mol for cyclopropenone (X = O) (somewhat aromatic; the benzene ECRE is 29.3 kcal/mol) to ?2.4 kcal/mol (slightly antiaromatic) for X = SiH2. Additional disubstitution of the C?C double bond by X′ groups (X′ = CH3, NH2, OH, SiH3, PH2, SH) increases the REs considerably, but has only small effects on the ECREs. Even the ECRE of deltic acid (X = O, X′ = OH) is only increased to +13.3 kcal/mol. The conclusion based on ECRE's, that all 12 of the three membered rings are only marginally aromatic/antiaromatic, is supported by the satisfactorily plot (R2 = 0.92) of ECRE against values of NICS(0)πzz (a superior nucleus chemical independent shift magnetic index of aromaticity), which range only from ?6.1 ppm (diatropic) for deltic acid (cf., ?35.5 ppm for benzene and ?14.2 ppm for the parent cyclopropenium ion) to +8.9 ppm (paratropic) for the silicon derivative, X = SiH2, X′ = SiH3. © 2010 Wiley Periodicals, Inc. Int J Quantum Chem, 2011 相似文献
23.
We consider certain vacua of four‐dimensional SU(N) gauge theory with the same field content as the 𝒩 = 4 supersymmetric Yang‐Mills theory, resulting from potentials which break the 𝒩 = 4 supersymmetry as well as its global SO(6) symmetry down to SO(3) × SO(3). We show that the theory behaves at intermediate scales as Yang‐Mills theory on M4 × SL2 × SR2, where the extra dimensions are fuzzy spheres with magnetic fluxes. We determine in particular the structure of the zero modes due to the fluxes, which leads to low‐energy mirror models. 相似文献
24.
Reply to: “Comment on Probing the Properties of Polynuclear Superhalogens without Halogen Ligand via ab Initio Calculations: A Case Study on Double‐Bridged [Mg2(CN)5]−1 Anions by Li et al. ”
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Jin‐Feng Li Miao‐Miao Li Dr. Hongcun Bai Yin‐Yin Sun Prof. Jian‐Li Li Dr. Bing Yin 《Chemphyschem》2016,17(18):2947-2947
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26.
Gautam Bhattacharyya 《Pramana》2009,72(1):37-54
In this talk, I shall first discuss the Standard Model Higgs mechanism and then highlight some of its deficiencies making
a case for the need to go beyond the Standard Model (BSM). The BSM tour will be guided by symmetry arguments. I shall pick
up four specific BSM scenarios, namely, supersymmetry, little Higgs, gauge-Higgs unification, and the Higgsless approach.
The discussion will be confined mainly on their electroweak symmetry breaking aspects.
相似文献
27.
This is a summary of the beyond the Standard Model (including model building) working group of the WHEPP-X workshop held at
Chennai from January 3 to 15, 2008.
Participants: Neelima Agarwal, S K Agarwalla, C S Aulakh, A Belyaev, S S Biswal, B Bhattacharjee, G Bhattacharyya, L Calibbi, D Choudhury,
E J Chun, D Das, A De Roeck, N G Deshpande, E Dudas, A Giri, D Grellshceid, R Godbole, S Goswami, M Guchait, M Hirsch, R Kaul,
B Kodrani, M C Kumar, A Kundu, Y Mambrini, P Mathews, B Mellado, R Mohanta, S Mohanty, A Nyffeler, S Pakvasa, M K Parida,
M Passera, C Petridou, S Poddar, P Poulose, A Rajaraman, G Rajasekaran, V Ravindran, Kumar Rao, D P Roy, Probir Roy, K A Saheb,
V H Satheeshkumar, T Schwetz, A Tripathi, R Vaidya and S Vempati 相似文献
28.
Malcolm Fairbairn 《Contemporary Physics》2017,58(1):1-24
In 2010, the MoEDAL (MOnopole and Exotics Detector at the LHC) experiment at the Large Hadron Collider (LHC) was unanimously approved by European Centre for Nuclear Research’s Research Board to start data taking in 2015. MoEDAL is a pioneering experiment designed to search for highly ionising manifestations of new physics such as magnetic monopoles or massive (pseudo-)stable charged particles. Its groundbreaking physics programme defines a number of scenarios that yield potentially revolutionary insights into such foundational questions as: are there extra dimensions or new symmetries; does magnetic charge exist; what is the nature of dark matter; and, how did the Big Bang develop. MoEDAL’s purpose is to meet such far-reaching challenges at the frontier of the field. The innovative MoEDAL detector employs unconventional methodologies tuned to the prospect of discovery physics. The largely passive MoEDAL detector, deployed at Point 8 on the LHC ring, has a dual nature. First, it acts like a giant camera, comprised of nuclear track detectors – analysed offline by ultra fast scanning microscopes – sensitive only to new physics. Second, it is uniquely able to trap the particle messengers of physics beyond the Standard Model for further study. MoEDAL’s radiation environment is monitored by a state-of-the-art real-time TimePix pixel detector array. A new MoEDAL sub-detector designed to extend MoEDAL reach to mini-charged, minimally ionising particles is under study. 相似文献
29.
30.
LIU Yu-Xiao WANG Yong-Qiang DUAN Yi-Shi 《理论物理通讯》2007,48(4):675-679
We study fermionic zero modes in the self-dual vortex background on an extra two-dimensional Riemann surface in (5+1) dimensions. Using the generalized Abelian-Higgs model, we obtain the inner topological structure of the self-dual vortex and establish the exact self-duality equation with topological term. Then we analyze the Dirac operator on an extra torus and the effective Lagrangian of four-dimensional fermions with the self-dual vortex background. Solving the Dirac equation, the fermionic zero modes on a torus with the self-dual vortex background in two simple cases are obtained. 相似文献