Synthesis and photoluminescent and electrochromic properties of aromatic poly(amine amide)s bearing pendent N‐carbazolylphenyl moieties

A series of novel poly(amine amide)s ( IIa – IIl ) with pendent N‐carbazolylphenyl units having inherent viscosities of 0.25–1.06 dL/g were prepared via direct phosphorylation polycondensation from various dicarboxylic acids and a carbazole‐based aromatic diamine. Except for poly(amine amide) IIc , derived from trans‐1,4‐cyclohexanedicarboxylic acid, all the other amorphous poly(amine amide)s were readily soluble in many polar solvents, such as N,N‐dimethylacetamide and N‐methyl‐2‐pyrrolidone (NMP), and could be cast into transparent and flexible films. The aromatic poly (amine amide)s had useful levels of thermal stability associated with relatively high glass‐transition temperatures (268–331 °C), 10% weight loss temperatures in excess of 540 °C, and char yields at 800 °C in nitrogen higher than 60%. These polymers exhibited maximum ultraviolet–visible absorption at 293–361 nm in NMP solutions. Their photoluminescence in NMP solutions exhibited fluorescence emission maxima around 362 and 448–499 nm for aromatic–aliphatic poly(amine amide)s IIa – IIc and aromatic poly (amine amide)s IId – IIl , respectively. The fluorescence quantum yield in NMP solutions ranged from 0.34% for IIj to 4.44% for IIa . The hole‐transporting and electrochromic properties were examined with electrochemical and spectroelectrochemical methods. Cyclic voltammograms of the poly(amine amide) films cast onto an indium tin oxide coated glass substrate exhibited reversible oxidation at 0.81 V and irreversible oxidation redox couples at 1.20 V versus Ag/AgCl in acetonitrile solutions, and they revealed excellent stability of the electrochromic characteristics, with a color change from yellow to green at applied potentials ranging from 0.00 to 1.05 V. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4108–4121, 2006     

Running time experiments on some algorithms for solving propositional satisfiability problems

Satisfiability problems are of importance for many practical problems. They are NP-complete problems. However, some instances of the SAT problem can be solved efficiently. This paper reports on a study concerning the behaviour of a variety of algorithmic approaches to this problem tested on a set of problems collected at FAW. The results obtained give a lot of insight into the algorithms and problems, yet also show some general technical and methodological problems associated with such comparisons.     

进化规划动态寻优机理分析

为了从整体上揭示进化规划 ( EP)算法的内在运行机制 ,探寻算法的动态寻优机理 ,本文从种群角度出发 ,建立了一种种群动态寻优微分方程模型 ,并对该模型进行了理论分析 .数值模拟结果说明了所建模型的正确性 ,并得出了一些有意义的结论     

车用涡轮增压器混流涡轮的设计

为了改善高比转速下增压器的涡轮性能，本文为匹配Ｊ６１１０Ｚ柴油机的ＨＩＦ增压器设计了混流涡轮．设计中采用了结合叶轮准三元流动分析的涡轮性能预测新方法．混流涡轮的性能试验结果显示，与径流涡轮相比，混流涡轮流通能力更大，并且能在更低的速度比ｕ／ｃｏ下得到更高的涡轮峰值效率．     

Plankton growth dynamic driven by plankton body size in deterministic and stochastic environments

In this paper, we establish a new phytoplankton–zooplankton model by considering the effects of plankton body size and stochastic environmental fluctuations. Mathematical theory work mainly gives the existence of boundary and positive equilibria and shows their local as well as global stability in the deterministic model. Additionally, we explore the dynamics of V-geometric ergodicity, stochastic ultimate boundedness, stochastic permanence, persistence in the mean, stochastic extinction, and the existence of a unique ergodic stationary distribution in the corresponding stochastic version. Numerical simulation work mainly reveals that plankton body size can generate great influences on the interactions between phytoplankton and zooplankton, which in turn proves the effectiveness of mathematical theory analysis. It is worth emphasizing that for the small value of phytoplankton cell size, the increase of zooplankton body size can not change the phytoplankton density or zooplankton density; for the middle value of phytoplankton cell size, the increase of zooplankton body size can decrease zooplankton density or phytoplankton density; for the large value of phytoplankton cell size, the increase of zooplankton body size can increase zooplankton density but decrease phytoplankton density. Besides, it should be noted that the increase of zooplankton body size cannot affect the effect of random environmental disturbance, while the increase of phytoplankton cell size can weaken its effect. There results may enrich the dynamics of phytoplankton-zooplankton models.     

Controllable Preparation of Nanosized LiMnPO4/C with Rod-Like Morphology by Hydrothermal Method with Excellent Electrochemical Performance

The nanosized rod-like LiMnPO₄/C cathode materials have successfully in situ synthesized on the surface of flaky structure MnPO₄ · H₂O self-sacrificing template by the hydrothermal method. The crystal microstructure, micro shape, and electrochemical parameters of LiMnPO₄/C are comprehensively studied by XRD, SEM, TEM, and electrochemical measurement methods. The physical and chemical properties analysis confirms that the vinyl acetate solution (VAc-H₂O) with a proper molar ratio is beneficial to generate orthorhombic olivine structure LiMnPO₄ with microporous structure and nanorod-shaped morphology. The electrochemical measurement results indicate that LMP-X1-AA sample delivers an initial discharge capacity of 148.1 mAh g⁻¹ at 0.05 C, the capacity retention rate still maintains at 89.2% after 200 cycles. As the discharge rate increases to 1 C, the discharge capacity still remains at 133.4 mAh g⁻¹. The results indicate that the synergistic effect of nanosized rod-like morphology and conductive carbon coating is beneficial to improving the lithium ions diffusivity and electrochemical properties of LiMnPO₄ materials.     

双重网络嵌入对公司IPO后市场表现的影响研究

将社会网络嵌入理论从单一网络拓展至双重网络,分析上市公司同时嵌入风险投资网络和承销商网络对公司IPO上市后市场表现的影响。利用2004～2017年有风险投资支持的IPO公司数据,实证检验结果表明：(1)单独嵌入风险投资网络中心位置、单独嵌入承销商网络中心位置,均会提高公司IPO后市场表现;(2)同时嵌入风险投资网络中心位置和承销商网络中心位置,对公司IPO后短期市场表现的正向影响会相互替代;(3)同时嵌入风险投资网络中心位置和承销商网络中心位置,对公司IPO后长期市场表现的正向影响会互相补充。     

Active learning for OPM in FMF systems

Optical performance monitoring (OPM) is essential to guarantee the robust and reliable operation of few-mode fiber (FMF)-based transmission. The available OPM methods including the analytical models such as the enhanced Gaussian noise model provide high accuracy along with high computational complexity which makes them improper for real-time implementations. As an alternative approach, machine learning (ML)-based OPM removes this barrier at the cost of leveraging a large training dataset. However, generating a field or synthetic dataset for FMF-based transmission is very hard and time-consuming. As a specific ML deployment, active learning (AL) is designed to work with a small training dataset, therefore, in this paper, we employ AL for OPM in FMF-based transmission. Results indicate that the proposed AL-based OPM can properly estimate the generalized signal-to-noise ratio by using a very small training dataset and achieve the root mean squared error similar to that obtained by working on large training datasets.     

共线式热电发电机在侧面散热情况下的性能

热电材料是一种环境友好型功能材料,其可以实现热能与电能的相互转化,在热电发电、热电制冷中具有许多应用.传统的热电发电机为$\pi$型结构,要求热电腿的长度相等,在某些情况该结构不利于热电发电机的优化设计.热电发电机在高温工况下会引起强烈的热应力甚至应力集中,从而缩短了其工作寿命.另外,热电发电机的工作温度于环境温度,这样必然会有一部分热量散失到环境中,从而影响热电发电机的性能.针对该现象,本文建立了考虑散热的新型共线式热电发电机模型,该模型的热电腿可以独立进行优化,基于有限元方法,对考虑侧面散热的共线式热电发电机进行了仿真模拟,分析了其在狄利克雷边界条件下的热电性能和力学性能,得到了热电发电机的温度场、电势场、应力场,探究了不同强度的对流散热系数对热电发电机热电性能和力学性能的影响.结果表明,对流散热会降低热电发电机的能量转化效率,当对流换热系数达到~100W/(m$^{2}\cdot$\textcelsius) 时,效率为~0.0479,该值比绝热状态的转化效率0.066 7 低28%.对流散热使热电发电机侧面热损失增加,降低了热应力.在实际应用中,应合理优化设计隔热系统,提高能量的转化效率.      

HIGH PERFORMANCE SPARSE SOLVER FOR UNSYMMETRICAL LINEAR EQUATIONS WITH OUT-OF-CORE STRATEGIES AND ITS APPLICATION ON MESHLESS METHODS

A new direct method for solving unsymmetrical sparse linear systems(USLS) arising from meshless methods was introduced. Computation of certain meshless methods such as meshless local Petrov-Galerkin (MLPG) method need to solve large USLS. The proposed solution method for unsymmetrical case performs factorization processes symmetrically on the upper and lower triangular portion of matrix, which differs from previous work based on general unsymmetrical process, and attains higher performance. It is shown that the solution algorithm for USLS can be simply derived from the existing approaches for the symmetrical case. The new matrix factorization algorithm in our method can be implemented easily by modifying a standard JKI symmetrical matrix factorization code. Multi-blocked out-of-core strategies were also developed to expand the solution scale. The approach convincingly increases the speed of the solution process, which is demonstrated with the numerical tests.