无胺合成[Fe]ZSM-5分子筛的结构鉴定及其催化性能的研究

不用有机胺为模板剂,在碱性介质中采用水热合成法成功地合成了[Fe]ZSM-5分子筛.用X射线衍射、透射电镜、红外光谱、顺磁共振谱、X射线光电子能谱和穆斯堡尔谱等对其结构进行了表征,结果表明,Fe原子进入了分子筛骨架,并处于四面体的配位环境.在由甲醇转化为汽油的过程中,以本文合成的[Fe]ZSM-5与用有机胺为模板剂合成的[Fe]ZSM-5分子筛为催化剂相比,其活性和选择性几乎相同,且都比通常的H[Al]ZSM-5好,C₅组分以上的选择性大于80%,且芳烃(包括脂环烃)和异构烃的含量达75%以上.     

手性环境中障碍电磁散射问题的积分方程方法

正1引言特殊介质中的电磁散射问题是一个重要的研究课题,是近些年来才开展起来的.此研究中,手性介质的电磁散射问题得到了很多关注.电磁波在手性介质中的传播是由Maxwell方程组和Drude-Born-Fedorov本构方程共同刻画的.手性介质可以由介电常数ε,磁导率μ和手性导纳β来描述.近些年来,关于手性介质中的电磁散射问题已有一些结果.Ammari,Hamdache and Nedelec~[2],Ammari and Nedelec~[3,4]给出了关于Drude-Born-Fedorov模型、表示定理,Drude-Born-Fedorov的     

The survival probability of critical and subcritical branching processes in finite state space Markovian environment

Let ${\left(Z_n\right)}_{n\ge 0}$ be a branching process in a random environment defined by a Markov chain ${\left(X_n\right)}_{n\ge 0}$ with values in a finite state space $\mathbb{X}$. Let ${\mathbb{P}}_i$ be the probability law generated by the trajectories of ${\left(X_n\right)}_{n\ge 0}$ starting at $X_0=i\in \mathbb{X}.$ We study the asymptotic behaviour of the joint survival probability ${\mathbb{P}}_i\left(Z_n>0,X_n=j\right)$, $j\in \mathbb{X}$ as $n\to +\infty$ in the critical and strongly, intermediate and weakly subcritical cases.     

Stochastic modeling of quality of systems operating in a heterogeneous environment

We consider systems that are subject to an external mixed Poisson shock process. Each shock can result in a failure of a system with a given probability and is survived with the complementary probability. Each shock additionally decreases the quality function that describes the performance of a system, thus forming the corresponding stochastic process. Expectations (unconditional and conditional on survival) and relevant variability characteristics for the stochastic quality function are derived. Some monotonicity properties of the conditional quality function are investigated and the future values of this function are derived.     

“If You Can Turn a Rectangle into a Square, You Can Turn a Square into a Rectangle ...” Young Students Experience the Dragging Tool

This paper describes a study of the cognitive complexity of young students, in the pre-formal stage, experiencing the dragging tool. Our goal was to study how various conditions of geometric knowledge and various mental models of dragging interact and influence the learning of central concepts of quadrilaterals. We present three situations that reflect this interaction. Each situation is characterized by a specific interaction between the students’ knowledge of quadrilaterals and their understanding of the dragging tool. The analyses of these cases offer a prism for viewing the challenge involved in changing concept images of quadrilaterals while lacking understanding of the geometrical logic that underlies dragging. Understanding dragging as a manipulation that preserves the critical attributes of the shape is necessary for constructing the concept images of the shapes.     

Some concepts of positive dependence for bivariate interchangeable distributions

In this work we consider some familiar and some new concepts of positive dependence for interchangeable bivariate distributions. By characterizing distributions which are positively dependent according to some of these concepts, we indicate real situations in which these concepts arise naturally. For the various families of positively dependent distributions we prove some closure properties and demonstrate all the possible logical relations. Some inequalities are shown and applied to determine whether under- (or over-) estimates, of various probabilistic quantities, occur when a positively dependent distribution is assumed (falsely) to be the product of its marginals (that is, when two positively dependent random variables are assumed, falsely, to be independent). Specific applications in reliability theory, statistical mechanics and reversible Markov processes are discussed. This work was partially supported by National Science Foundation GP-30707X1. It is part of the author's Ph.D. dissertation prepared at the University of Rochester and supervised by A. W. Marshall. Now at Indiana University.     

随机环境中独立过程的Hydrodynamic极限

本文研究随机环境中独立过程的Hydrodynamic极限,在恰当的条件下,构造出了随机环境中的独立过程,并通过对偶公式得到了该粒子模型的宏观偏微分方程。     

关于环境地质学的一些基本问题探讨

简要阐述了作者对有关环境地质学的一些基本问题的见解,包括;环境地质与地质环境的科学涵义;环境地质学与相关学科的关系;地质环境保护在整个环境保护中的应有地位;地质灾害的形成步骤及其防治途径;环境地质学的亟待完善领域等。同时也涉及整个环境科学的一些问题。     

过载-振动复合环境下液浮积分陀螺仪动力学分析

采用有限元数值计算方法对液浮积分陀螺仪在过载—振动复合环境中的动力学特性进行研究。对液浮积分陀螺仪浮子组件谐态和模态进行了分析计算，获得了复合载荷下浮子组件质心的附加偏移的数据，从而为分析陀螺仪的附加误差提供了依据。     

两个相邻建筑物周围风环境的数值模拟

高层建筑物及其群体周围所引起的风环境问题正日益受到人们的重视。本文用数值模拟方法对两幢串列布置高层建筑周围的流场进行了模拟，讨论了建筑物高度、间距比等因素对风环境特性的影响。为了与两个相邻建筑物的流场进行比较，本文同时计算了单个建筑物周围流动的分布情况。数值模拟结果对揭示高层建筑群区域内再生风载荷的形成机理提供了一定的分析方法，为城市规划和高层建筑住宅小区设计提供了一定的理论参考和依据。