全文获取类型
收费全文 | 23093篇 |
免费 | 3679篇 |
国内免费 | 3656篇 |
专业分类
化学 | 15697篇 |
晶体学 | 198篇 |
力学 | 1868篇 |
综合类 | 192篇 |
数学 | 1699篇 |
物理学 | 10774篇 |
出版年
2024年 | 96篇 |
2023年 | 299篇 |
2022年 | 713篇 |
2021年 | 762篇 |
2020年 | 1038篇 |
2019年 | 770篇 |
2018年 | 762篇 |
2017年 | 851篇 |
2016年 | 1035篇 |
2015年 | 908篇 |
2014年 | 1236篇 |
2013年 | 1933篇 |
2012年 | 1298篇 |
2011年 | 1414篇 |
2010年 | 1259篇 |
2009年 | 1533篇 |
2008年 | 1474篇 |
2007年 | 1528篇 |
2006年 | 1504篇 |
2005年 | 1222篇 |
2004年 | 1146篇 |
2003年 | 1037篇 |
2002年 | 816篇 |
2001年 | 714篇 |
2000年 | 710篇 |
1999年 | 624篇 |
1998年 | 563篇 |
1997年 | 458篇 |
1996年 | 390篇 |
1995年 | 351篇 |
1994年 | 300篇 |
1993年 | 240篇 |
1992年 | 205篇 |
1991年 | 210篇 |
1990年 | 148篇 |
1989年 | 127篇 |
1988年 | 120篇 |
1987年 | 92篇 |
1986年 | 83篇 |
1985年 | 74篇 |
1984年 | 60篇 |
1983年 | 28篇 |
1982年 | 55篇 |
1981年 | 49篇 |
1980年 | 47篇 |
1979年 | 46篇 |
1978年 | 21篇 |
1977年 | 21篇 |
1976年 | 13篇 |
1974年 | 11篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
941.
Green Approach to the Fabrication of Superhydrophobic Mesh Surface for Oil/Water Separation 下载免费PDF全文
We report a simple and environment friendly method to fabricate superhydrophobic metallic mesh surfaces for oil/water separation. The obtained mesh surface exhibits superhydrophobicity and superoleophilicity after it was dried in an oven at 200 °C for 10 min. A rough silver layer is formed on the mesh surface after immersion, and the spontaneous adsorption of airborne carbon contaminants on the silver surface lower the surface free energy of the mesh. No low‐surface‐energy reagents and/or volatile organic solvents are used. In addition, we demonstrate that by using the mesh box, oils can be separated and collected from the surface of water repeatedly, and that high separation efficiencies of larger than 92 % are retained for various oils. Moreover, the superhydrophobic mesh also possesses excellent corrosion resistance and thermal stability. Hence, these superhydrophobic meshes might be good candidates for the practical separation of oil from the surface of water. 相似文献
942.
This research examines and quantifies the influence of ion solvation parameters on the affinity of monovalent anions for strong-base anion resins. A data set comprising resin selectivity coefficients and solvation parameters from the literature is statistically analyzed using correlation and multiple regression techniques. The affinity of monovalent anions for the resin phase correlated well to ionic radii. Solvation parameters such as the hydration number, and entropy, enthalpy and free energy of hydration are also strongly correlated to selectivity. Using the stepwise regression procedure on subsets of independent variables, the entropy of hydration, which characterizes the structure-influencing nature of ions in solution, is incorporated as the sole parameter in the predictive model for resin selectivity. The data are best correlated by the exponential form of the regression equation, and the physical meaning of the correlation is shown to be reasonable. A simple rule for categorizing ions as structure-makers and structure-breakers is proposed, and the results are consistent with conventional classifications. 相似文献
943.
To figure out the influence of isotope effect on product polarizations of the N(2D)+D2 reactive system and its isotope variants, quasi-classical trajectory(QCT) calculation was performed on Ho’s potential energy surface(PES) of 2A″ state. Product polarizations such as product distributions of P(θr), P(φr) and P(θr,φr), as well as the generalized polarization-dependent differential cross sections(PDDCSs) were discussed and compared in detail among the four product channels of the title reactions. Both the intermolecular and intramolecular isotope effects were proved to be influential on product polarizations. 相似文献
944.
Three C60‐carbazole adducts have been synthesized by 1, 3‐dipolar cycloaddition reaction. Intramolecular energy/electron transfer from carbazole to C60 was observed by steady‐state absorption and fluorescence spectra. The fluorescence spectra of these adducts were similar to each other and dependent on the excitation wavelength and solvent. 相似文献
945.
Shura Hayryan Chin‐Kun Hu Shun‐Yun Hu Rung‐Ji Shang 《Journal of computational chemistry》2001,22(12):1287-1296
The determination of the three‐dimensional (3D) structure of a protein or peptide is a very important research problem in biological and medical sciences. Anfinsen's experiments (Science 1973, 181, 223) on renaturation of denatured proteins have shown that the native 3D structure of a (small) protein at low (room) temperatures is uniquely determined by its amino acid sequence, which suggests that it might be possible to determine the 3D structure of a protein from its amino acid sequence by pure computations. As a step toward that goal, in this article we present a simple approach for parallelization of multicanonical Monte Carlo simulations of proteins with continuous potentials. Our method is based on the parallel calculation of the protein energy function. The algorithm is tested by simulated annealing and multicanonical simulations of two small peptides, and known results are reproduced accurately. An acceptable degree of parallelization can be achieved in the simulation of Protein L using up to 30 PCs. © 2001 John Wiley & Sons, Inc. J Comput Chem 22: 1287–1296, 2001 相似文献
946.
Five solid complexes of zinc with L‐α‐methionine, L‐α‐phenylalanine and L‐α‐histidine were prepared. The constant‐volume combustion energies of the complexes, ΔEc (coordination), were determined by a precise rotating bomb calorimeter at 298.15 K. They were ‐ 2969.03 ± 0.34, ‐2929.46 ± 1.59, ‐9597.13 ± 6.12, ‐4378.98 ± 3.27 and ‐14047 ± 6.75 kJ/mol, respectively. Their standard enthalpies of combustion, ΔHθm,c(coordination, s, 298.15 K), and standard enthalpies of formation, ΔHθm,f (coordination, s, 298.15 K), were calculated. They were ‐2959.73 ± 0.34, ‐2923.88 ± 1.59, ‐9649.18 ± 6.12, ‐4373.40 ± 3.27, ‐14048.53 ± 6.75 kj/mol and ‐1180.94 ± 0.92, ‐1401.26 ± 1.77, ‐2501.69 ± 6.50, ‐1381.47 ± 3.49, ‐1950.19 ± 7.65 kJ/mol, respectively. 相似文献
947.
生物质空气-水蒸气气化制取合成气热力学分析 总被引:2,自引:4,他引:2
基于Gibbs自由能最小化原理,计算了包括H2O(l)和C(s)在内的,生物质空气 水蒸气气化体系热力学平衡,对比分析了常压气化和加压气化的特点,通过回归分析得到了不同压力下,气化产物中可燃气体分率最高时的水蒸气/生物质质量比(S/B,Steam to Biomass Ratio)与空气当量比(ER,Equivalence Ratio)的关系曲线,为探讨适于制取合成气的气化工艺和条件提供初步的理论指导。研究表明,相对于常压气化,加压气化体系的平衡温度较高,平衡状态下可燃气体分数较低,但CH4含量明显增加;一定温度和当量比下,加压气化使得气化产物中可燃气体分数达到最高所对应的S/B比增大,即需要消耗更多水蒸气;通过调节S/B比,可以比较方便地控制产物中H2和CO的比例。以常压为例,T=1173K,S/B=0.17时,气化产物中H2/CO约为1.1∶1,而S/B=1.02时,气化产物中H2/CO约为2∶1;不同压力下最佳S/B比和ER有很好的线性关系,温度为1173K时,最佳S/B比与压力及ER〖的关系为S/B=-1.48×ER-4.49 E×10-5×p2 + 5.83 E×10-3×p + 0.32。 相似文献
948.
Recent experimental work carried out in this laboratory on the ultrafast dynamics of myoglobin (Mb) is summarized with a stress on structural and vibrational energy relaxation. Studies on the structural relaxation of Mb following CO photolysis revealed that the structural change of heme itself, caused by CO photodissociation, is completed within the instrumental response time of the time-resolved resonance Raman apparatus used (approximately 2 ps). In contrast, changes in the intensity and frequency of the iron-histidine (Fe-His) stretching mode upon dissociation of the trans ligand were found to occur in the picosecond regime. The Fe-His band is absent for the CO-bound form, and its appearance upon photodissociation was not instantaneous, in contrast with that observed in the vibrational modes of heme, suggesting appreciable time evolution of the Fe displacement from the heme plane. The band position of the Fe-His stretching mode changed with a time constant of about 100 ps, indicating that tertiary structural changes of the protein occurred in a 100-ps range. Temporal changes of the anti-Stokes Raman intensity of the v4 and v7 bands demonstrated immediate generation of vibrationally excited heme upon the photodissociation and decay of the excited populations, whose time constants were 1.1 +/- 0.6 and 1.9 +/- 0.6 ps, respectively. In addition, the development of the time-resolved resonance Raman apparatus and prospects in this research field are described. 相似文献
949.
V. P. Korolev 《Journal of Structural Chemistry》2007,48(3):573-577
Changes in the thermal expansion coefficient and isothermal compressibility in homological series of n-alcohols at 298 K are discussed. It is shown that only methanol exhibits abnormal behavior. Volumetric coefficients of hypothetical solvents such as pseudo-water and pseudo-methanol are determined. Internal pressure values of liquids are calculated. The internal pressure of pseudo-water exceeds that of water, whereas the situation is opposite for the cohesion energy density. 相似文献
950.
Diverse existing lines for the calculation of excited states are exposed, with an emphasis on those methods that consider
both types of correlation energy: the dynamic and the non-dynamic one. We analyze the possibility of to calculate the dynamic
correlation energy using a correlation energy density functional applied to a multi-determinantal wavefunction, which would
include the non-dynamic correlation energy, versus the use of mono-determinantal wavefunctions, which are not able to include
the long-range correlation energy, and versus the use of variational or perturbative calculations from multi-determinantal
wavefunctions, with their excessive computational cost. The results obtained with several methods are compared.
Contribution to the Serafin Fraga Memorial Issue. 相似文献