全文获取类型
收费全文 | 1772篇 |
免费 | 175篇 |
国内免费 | 102篇 |
专业分类
化学 | 539篇 |
晶体学 | 12篇 |
力学 | 105篇 |
综合类 | 19篇 |
数学 | 671篇 |
物理学 | 703篇 |
出版年
2024年 | 5篇 |
2023年 | 12篇 |
2022年 | 21篇 |
2021年 | 28篇 |
2020年 | 35篇 |
2019年 | 52篇 |
2018年 | 36篇 |
2017年 | 48篇 |
2016年 | 62篇 |
2015年 | 45篇 |
2014年 | 75篇 |
2013年 | 185篇 |
2012年 | 86篇 |
2011年 | 79篇 |
2010年 | 67篇 |
2009年 | 84篇 |
2008年 | 123篇 |
2007年 | 95篇 |
2006年 | 88篇 |
2005年 | 93篇 |
2004年 | 69篇 |
2003年 | 64篇 |
2002年 | 69篇 |
2001年 | 58篇 |
2000年 | 71篇 |
1999年 | 62篇 |
1998年 | 50篇 |
1997年 | 27篇 |
1996年 | 38篇 |
1995年 | 28篇 |
1994年 | 19篇 |
1993年 | 18篇 |
1992年 | 15篇 |
1991年 | 8篇 |
1990年 | 12篇 |
1989年 | 9篇 |
1988年 | 14篇 |
1987年 | 11篇 |
1986年 | 10篇 |
1985年 | 11篇 |
1984年 | 10篇 |
1983年 | 7篇 |
1982年 | 9篇 |
1981年 | 14篇 |
1980年 | 6篇 |
1979年 | 3篇 |
1978年 | 7篇 |
1976年 | 2篇 |
1975年 | 3篇 |
1969年 | 2篇 |
排序方式: 共有2049条查询结果,搜索用时 15 毫秒
31.
《Electroanalysis》2005,17(3):239-245
Oxygen dependence of a tyrosinase‐based electrochemical biosensor for determination of phenol in aqueous and organic media was systematically investigated. The result demonstrated that the enzymatic coupling reaction rate of tyrosinase (deoxy form) and O2 to regenerate tyrosinase (oxy form) is a kinetically fast reaction, and the significant change of O2 concentration in aqueous solution did not affect the coupling reaction. The further increase of O2 concentration did not increase the overall oxidation reaction rate of the substrate at low substrate concentration (e.g.,<10 μM phenol) when O2 concentration was greater than 8.9 ppm. The oxygen dependence was observed in the case of high substrate concentration due to insufficient amount of O2 available for the regeneration of tyrosinase. In other words, the upper linear range is oxygen dependent for tyrosinase biosensors. The phenol biosensors employing microelectrodes had wider upper linear ranges than macroelectrodes in both aqueous and organic phase, which can be explained by the oxygen dependence. 相似文献
32.
ESR study of free radicals formed upon UV irradiation of nitropentafluoroacetone in various solvents
B. L. Tumanskii V. I. D'yachenko Yu. I. Lyakhovetskii N. N. Bubnov S. P. Solodovnikov A. F. Kolomiets 《Russian Chemical Bulletin》1993,42(3):466-468
The formation of CF3C(O)CF2N(O.)O2CF2C(O)CF3 free radicals upon the UV irradiation of nitropentafluoroacetone (1) in toluene and mesitylene is established by ESR. The most likely cause of their formation is the one-electron oxidation of the solvents by photoexcited1 followed by decay of the radical anion formed from1 with the expulsion of an NO2 anion and attachment of the radical to a molecule of original1. The irradiation of 1 in triethylsilane results in the elimination of a fluoride ion and fixation of a CF3COCFN(O–)O' radical. UV irradiation of ketone1 in pentane results in the abstraction of a hydrogen atom from the solvent and the formation of a CF3COCF2N(OH)O ' radical.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 512–514, March, 1993. 相似文献
33.
在标准Rough集理论的指导下,利用偏序关系性质构造了不同分类,并以此为基础探讨了上、下近似集,从而构建了基于偏序关系的Rough集模型。新模型将Rough集理论的应用范围由等价关系扩展到偏序关系。为了更好地增强模型的实用性和灵括性,一方面从程度、精度、概率等角度出发分别对其进行了扩展,另一方面引入依赖度使其适用于研究各种非严格的偏序关系。给出了实例分析,并结合现实生活中的现象阐述了模型的应用价值。 相似文献
34.
The enhanced low-dose-rate sensitivity (ELDRS) and dose-rate dependence of vertical NPN transistors are investigated in this article.The results show that the vertical NPN transistors exhibit more degradation at low dose rate,and that this degradation is attributed to the increase on base current.The oxide trapped positive charge near the SiO2-Si interface and interface traps at the interface can contribute to the increase on base current and the two-stage hydrogen mechanism associated with space charge effect can well explain the experimental results. 相似文献
35.
High-power operation of diode-pumped fiber lasers at wavelength near 2μm are demonstrated with short length of heavily Tm3 -doped silica glass fibers. With 7-cm long fiber, a laser at near 2 μm is obtained with the threshold of 135 mW, maximum output power of 1.09 W, and slope efficiency of 9.6% with respect to the launched power from a laser diode at 790 nm. The output stability of this fiber laser is within 5%.The dependence of the performance of fiber lasers on the operation temperature and cavity configuration parameters is also investigated. 相似文献
36.
An optical sensor using a quartz core microcantilever was fabricated by etching clad layer from optical fiber. The temperature dependence of the resonance frequency of this sensor was measured in atmosphere and water. The temperature coefficient of the resonance frequency in water was 1.3×10−3/°C, which was about one order larger than that (2.3×10−4/°C) in atmosphere. This was caused by increase of additional mass due to temperature dependence of the viscosity of water, while, the increase of the resonance frequency in atmosphere was caused by temperature dependence of Young’s modulus of the quartz core. These results were evaluated theoretically using a “string-of-beads” model. 相似文献
37.
We suggest an electrochemical etching method with viscous etchant to enhance the sharpness of tip of scanning probe microscope. The viscosity of the etchant mixed with HCl solution and glycerol was used as a control parameter in addition to the voltage applied to the tip. In order to improve the sharpness of the tip, a nano-scale meniscus formed between the end of the tip and the liquid level was used. The shapes, aspect ratios, and radii of tips were measured depending on the concentration of the etchant. It was found that the tip etched with the mixed liquid with glycerol was sharper than the tip with the pure HCl solution. This can be explained by the fact that the meniscus formed by viscous liquid is maintained with a thinner diameter and causes final etching until the meniscus bridge is ruptured. 相似文献
38.
Let denote a Hermite process of order and self-similarity parameter . This process is -self-similar, has stationary increments and exhibits long-range dependence. When , it corresponds to the fractional Brownian motion, whereas it is not Gaussian as soon as . In this paper, we deal with a Vasicek-type model driven by , of the form . Here, and are considered as unknown drift parameters. We provide estimators for and based on continuous-time observations. For all possible values of and , we prove strong consistency and we analyze the asymptotic fluctuations. 相似文献
39.
40.