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121.
The CO2-broadened water coefficients (half-widths, line shifts, and temperature dependence of the widths) are predicted using a fully complex Robert-Bonamy formulation for the 937 allowed and forbidden perpendicular type transitions of (000)-(000) between 200 and 900 cm−1 in order to facilitate atmospheric remote sensing of Mars and Venus. In addition, empirical Lorentz line widths and pressure-induced frequency-shifts of CO2-broadened H216O are obtained at room temperature for 257 perpendicular transitions of the (010)-(000) fundamental. For this, calibrated spectra recorded at 0.0054 cm−1 resolution are measured assuming Voigt line shapes. For transitions between 1287 and 1988 cm−1 with rotational quanta up to J = 13 and Ka = 6, the widths vary from 0.045 to 0.212 cm−1 atm−1 at 300 K; the pressure-shifts are quite large and range from −0.0386 to +0.0436 cm−1 atm−1. For the (010)-(000) band, the RMS and mean observed and calculated differences for CO2-broadened H2O half-widths are 12% and −1.9%, respectively, while the RMS and mean ratios of the observed and calculated pressure-induced shift coefficients are 1.6 and 0.79, respectively. For pairs of transitions involving Ka = 0 and 1, such as 20 2 ← 31 3 and 31 3 ← 20 2, both the calculated and observed pressure induced shifts in positions are opposite in sign and often similar in magnitude. The data are too limited to characterize vibrational dependencies of the widths, however. 相似文献
122.
The use of the far‐infrared spectral range presents a novel approach for analysis of the hydrogen bonding in proteins. Here it is presented for the analysis of Fe? S vibrations (500–200 cm?1) and of the intra‐ and intermolecular hydrogen bonding signature (300–50 cm?1) in the Rieske protein from Thermus thermophilus as a function of temperature and pH. Three pH values were adequately chosen in order to study all the possible protonation states of the coordinating histidines. The Fe? S vibrations showed pH‐dependent shifts in the FIR spectra in line with the change of protonation state of the histidines coordinating the [2Fe? 2S] cluster. Measurements of the low‐frequency signals between 300 and 30 K demonstrated the presence of a distinct overall hydrogen bonding network and a more rigid structure for a pH higher than 10. To further support the analysis, the redox‐dependent shifts of the secondary structure were investigated by means of an electrochemically induced FTIR difference spectroscopic approach in the mid infrared. The results confirmed a clear pH dependency and an influence of the immediate environment of the cluster on the secondary structure. The results support the hypothesis that structure‐mediated changes in the environment of iron? sulfur centers play a critical role in regulating enzymatic catalysis. The data point towards the role of the overall internal hydrogen bonding organization for the geometry and the electronic properties of the cluster. 相似文献
123.
DONG Rui-Xin YAN Xun-Ling YANG Bing 《理论物理通讯》2008,50(8):532-536
A double helix model of charge transport in DNA molecule is given and the transmission spectra off our DNA sequences are obtained. The calculated results show that the transmission characteristics of DNA are not only related to the longitudinal transport but also to the transverse transport of molecule. The periodic sequence with the same composition has stronger conduction ability. With the increasing of bases composition, the conductive ability reduces, but the weight of θ direction rises in charge transfer. 相似文献
124.
ZHANG Yan-Bin PING Jia-Lun LV Xiao-Fu ZONG Hong-Shi 《理论物理通讯》2008,50(7):125-128
In this paper, the gluon propagator in Landau gauge has been studied on a lattice, including the quenched and the unquenched one. The small geometry size of lattice we use is 16^3 × 32, and the big one is 20^3 × 64. For the quenched approximation, we fit the numerical results and give a little different fitting values. We also obtain unquenched effects by comparing the gluon propagator resulting from the quenched and unquenched configurations, for both the two-flavor and three-flavor cases. For the unquenched configurations, an obvious quark mass dependence has not been found in the small quark mass case, but is found in the three-flavor case when the quark mass is big. 相似文献
125.
In this paper objectivity and material frame-indifference are systematically discussed, because changing the observer and
changing the motion of a material with respect to an observer independent standard frame of reference have to be distinguished
carefully. Objectivity and observer invariance of the physical laws and of the constitutive mappings are introduced. Semi-objectivity
and objectivity of different time derivative operators are investigated. As examples, changing the observer in liquid crystal
theory and changing the motion in linear heat conducting materials is considered. 相似文献
126.
127.
A fluid queue with ON periods arriving according to a Poisson process and having a long-tailed distribution has long range
dependence. As a result, its performance deteriorates. The extent of this performance deterioration depends on a quantity
determined by the average values of the system parameters. In the case when the the performance deterioration is the most
extreme, we quantify it by studying the time until the amount of work in the system causes an overflow of a large buffer.
This turns out to be strongly related to the tail behavior of the increase in the buffer content during a busy period of the
M/G/∞ queue feeding the buffer. A large deviation approach provides a powerful method of studying such tail behavior.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
128.
Commodity futures have long been used to facilitate risk management and inventory stabilization. The study of commodity futures prices has attracted much attention in the literature because they are highly volatile and because commodities represent a large proportion of the export value in many developing countries. Previous research has found apparently contradictory findings about the presence of long memory or more generally, long-range dependence. This note investigates the nature of long-range dependence in the volatility of 14 energy and agricultural commodity futures price series using the improved Hurst coefficient (H) estimator of Abry, Teyssière and Veitch. This estimator is motivated by the ability of wavelets to detect self-similarity and also enables a test for the stability of H. The results show evidence of long-range dependence for all 14 commodities and of a non-stationary H for 9 of 14 commodities. 相似文献
129.
Various empirical theories of ultrasonic velocity have been applied to three binary liquid mixtures, under pressures up to
200 MPa and their validity have been tested. A pressure dependent study of ultrasonic velocities has been made at 303.15 K.
The agreement between theory and experiment is found to be quite satisfactory. 相似文献
130.