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111.
Intermolecular photoinduced electron transfer (PET) in a gas phase was studied using carbazole vapor fluorescence quenching by halomethanes (CHCl3, CH2Br2, CCl4, CHBr3). The fluorescence quenching rate constants k
q changing from 2.3·105 sec–1·torr–1 in mixtures with CHCl3 to 4.6·106 sec–1·torr–1 in mixtures with CHBr3 at a constant temperature of 403 K were estimated. The dependence of the carbazole fluorescence decay rates in the presence of halomethanes on the free energy change G during transfer of the electron from carbazole to halomethanes is considered. It is suggested to take into account the influence of the vibrational energy of the carbazole molecule E
vib and its temperature changes in estimation of the G values. The differences between PET in the gas and liquid phases were analyzed. It is found that for mixtures with CCl4 and CHBr3 the negative temperature dependence of k
q is observed, when the decay rates and efficiencies of the intermolecular PET decreased with temperature increase in the range 403–573 K, i.e. these mixtures the electron transfer is not a barrier-restricted process. 相似文献
112.
David Eisenbud Craig Huneke Bernd Ulrich 《Proceedings of the American Mathematical Society》2003,131(3):701-708
In this paper we show that the Rees algebra can be made into a functor on modules over a ring in a way that extends its classical definition for ideals. The Rees algebra of a module may be computed in terms of a ``maximal' map from to a free module as the image of the map induced by on symmetric algebras. We show that the analytic spread and reductions of can be determined from any embedding of into a free module, and in characteristic 0--but not in positive characteristic!--the Rees algebra itself can be computed from any such embedding.
113.
Baha-Eldin Khaledi Subhash Kochar 《Annals of the Institute of Statistical Mathematics》2001,53(3):620-630
Consider a multivariate mixture model where the random variables X
1, ..., X
n
given (1, ...,
n
), are conditionally independent. Conditions are obtained under which different kinds of positive dependence hold among X
i
's. The results obtained are applied to a variety of problems including the concomitants of order statistics and of record values; and to frailty models. 相似文献
114.
115.
We study rate of convergence in the strong law of large numbers for finite and infinite variance time series in both contexts of weak and strong dependence. 相似文献
116.
Beghin Luisa Knopova Viktoria P. Leonenko Nikolai N. Orsingher Enzo 《Journal of statistical physics》2000,99(3-4):769-781
We analyze the asymptotic behavior of the rescaled solution to the linear Korteweg–de Vries equation when the initial conditions are supposed to be random and weakly dependent. By means of the method of moments we prove the Gaussianity of the limiting process and we present its correlation function. The same technique is applied to the analysis of another third-order heat-type equation. 相似文献
117.
Deutsch and Hayden have proposed an alternative formulation of quantum mechanics which is completely local. We argue that
their proposal must be understood as having a form of ‘gauge freedom’ according to which mathematically distinct states are
physically equivalent. Once this gauge freedom is taken into account, their formulation is no longer local.
相似文献
118.
通过在形成超重核的重离子俘获和熔合过程中引入位垒分布函数的方法对双核模型做了进一步发展. 超重核形成过程中的俘获、熔合和蒸发3个阶段分别采用了半经验的耦合道模型、数值求解主方程和统计蒸发模型的方法来描述. 计算了近年来Dubna小组利用热熔合反应48Ca(243Am, 3n—5n)288—286115和48Ca(248Cm,
3n—5n)293—291116合成超重新核素的蒸发余核激发函数. 系统分析了48Ca轰击锕系元素U,Np,Pu,Am,Cm合成超重核Z=112—116产生截面的同位素依赖性. 给出了合成超重新核素最佳的弹靶组合和入射能量, 即有最大的超重核产生截面. 计算说明, 壳修正能和中子分离能是影响超重核生成截面产生同位素依赖性的主要因素. 相似文献
119.
S.J.Sanders 《中国物理 C》2007,31(12):1137-1140
Identified particle elliptic flow results are presented for the Au+Au reaction at sNN=200GeV as a function of transverse momentum and pseudorapidity. Data at pseudorapidities η≈0,1, and 3.4 were obtained using the two BRAHMS spectrometers. Differential v2 (η,pt) values for a given particle type are
found to be essentially constant over the covered pseudorapidity range, in contrast to the integral v2 values which have previously been observed to decrease at forward rapidities. A softening of the particle spectra at forward angles is found to account for at least part of the integral v2 falloff. The data are found to be consistent with existing constituent quark scaling systematics. 相似文献
120.
The fluorescence property of xTbF3-BaF2-AlF3-GeO2+ySmF3 (x=0.01-40 mol%, y=0-5 wt%) glasses were investigated. The enhancement of Sm3+ fluorescence was recognized in the presence of Tb3+. Increasing Tb3+ content, the emission color changed from green to orange. When the intensity of fluorescence at 540 nm originated from Tb3+ is compared with that at 600 nm originated from Sm3+, the information about the concentration quenching of Tb3+ and Sm3+ was obtained. From these results, rare earth ions were dispersed identically in the glasses. After heating to 673 K or cooling to 77 K, the emission color of 20TbF3-20BaF2-10AlF3-50GeO2/mol%+0.05 wt% SmF3 glass was reversibly changed from orange to green. In addition, while the emission from 10TbF3-20BaF2-10AlF3-60GeO2+0.01 wt% SmF3 glass was green, its crystallized sample, prepared by annealing at 1073 K, exhibited an orange emission due to Sm3+ at room temperature. 相似文献