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151.
Due to a lack of at least 2 orders of magnitude in the amount of sample nuclei, single crystal surfaces are out of reach for
conventional NMR measurements. Our aim is to prove that highly polarized 129Xe provides a technique to overcome this restriction. Therefore an apparatus for polarizing 129Xe up to 0.7 by spin transfer from optically pumped Rb has been designed as well as an NMR spectrometer in combination with
a UHV chamber with sample cleaning, cooling and characterization abilities and a special manifold of glass stopcocks with
a liquid nitrogen cooled trap for dosing nitrogen free polarized Xe into the chamber onto the surface.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
152.
Nobuhiro Kawatsuki Imin Sai Tohei Yamamoto 《Journal of polymer science. Part A, Polymer chemistry》1999,37(21):4000-4006
We present (1) the linearly polarized (LP) ultraviolet (UV) photoreaction of block copolyesterethers comprising a hard segment of polyester and soft segment of poly(tetramethylene ether) (PTMG) and (2) the alignment behavior of liquid crystals (LCs) on the resultant photoreacted polymer films. Two kinds of copolyesterethers with different polyester segments of poly(hexamethylene p-phenylenediacrylate) (1a) or poly(hexamethylene p-phenylenediacrylate)-co-poly(hexamethylene 1,4-dibenzoate) (1b) were used in this study. The LP–UV irradiation resulted in a negative optical anisotropy for both polymer films, and a homogeneous photoalignment of LCs was achieved on the photoreacted polymer film. The LC alignment was perpendicular to the electric vector of the incident polarized light for 1a, whereas a reversion of the alignment from parallel to perpendicular was observed for 1b, depending on the irradiation doses. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 4000–4006, 1999 相似文献
153.
设计了X波段COBRA透镜型天线,利用电磁波在不同介质传播速度的差异,通过放置于圆锥喇叭口径处不同厚度的介质透镜改变TM01模不同扇区的相位,从而改变TM01模在普通喇叭口径处的轴对称分布,将轴对称的口径场分布转换为线对称,进而实现线极化或圆极化的轴向辐射。通过添加匹配介质,减小介质对微波的反射和驻波特性的影响;延伸喇叭到透镜边缘,使移相过程在波导内完成,有效地控制了电磁场模式。天线增益在中心工作频率为9.3 GHz时为19 dB,口径效率25%,辐射效率大于90%,反射系数小于1.3,轴比小于2 dB, 3 dB相对带宽大于30%,几乎可以覆盖整个X波段。 相似文献
154.
[Eu(pda)2]? and [Eu(bda)2]? (pda=1,10‐phenanthroline‐2, 9‐dicarboxylic acid; bda=2,2′ bipyridine 5,5′‐dicarboxylic acid) have an achiral D2d structure in crystals. These complexes exhibit circularly polarized luminescence (CPL) in water containing chiral amino acids. In this work, induced CPL of [Eu(pda)2]? and [Eu(bda)2]? in water solutions containing a mixture of d ‐ and l ‐ amino acids were examined. Plots of glum values of the induced CPL as a function of mol‐fraction of l ‐ and d ‐ arginine reveal that [Eu(pda)2]? favors homo‐association ([Eu(pda)2]?‐(l ‐arginine)2 or [Eu(pda)2]?‐(d ‐arginine)2) over hetero‐association {[Eu(pda)2]?‐(l ‐arginine)?(d ‐arginine)}. This suggests that association of an arginine molecule induces a structural change in [Eu(pda)2]? to promote chiral selective association to another arginine, i.e., homo‐allosteric association. On the other hand, the system of [Eu(pda)2]? with histidine favors hetero‐allosteric association over homo‐association. No allosteric effect is recognized in CPL from [Eu(bda)2]?. 相似文献
155.
156.
以单束正交线偏振光为光源,利用角向偏振显示器,采用CCD摄像机进行图像采集,利用Matlab软件进行图像处理,设计了一种由He-Ne激光器、角向偏振显示器组成的偏振光偏振方向显示系统,并研究了其角度特性.实验结果表明:系统在起偏器的起偏角分别为0°、90°、180°、270°、360°时,角向偏振显示器偏振显示角度的测量准确度分别为0.480°、0.168°、0.528°、0.421°、0.340°,测量精确度分别为0.208°、0.576°、0.660°、0.603°、0.466°,测量数据拟合曲线的线性相关系数为0.999.结合1/4波片,检偏器和分光比为50:50的分束器,构建了椭圆偏振光测量系统,完成了椭圆偏振光测量实验,椭圆率为0.198. 相似文献
157.
研究了利用摩擦空穴注入层3,4-乙撑二氧噻吩:聚苯乙烯磺酸(PEDOT:PSS)作为定向层实现聚芴(PFO)薄膜的偏振电致发光,蓝光的色坐标为(0.20,0.21).从聚合物薄膜的紫外可见吸收和光致发光偏振特性,研究了不同定向层摩擦强度、退火温度以及退火时间下PFO薄膜的二向色性,并证明退火温度是决定器件偏振性能的关键因素.当摩擦强度为25 mm退火温度和时间分别为200℃和30 min时,得到较好的偏振性能,器件的电致发光偏振率约为3.
关键词:
偏振发光
摩擦定向
聚合物电致发光
空穴注入层 相似文献
158.
159.
160.
F. Liang Y. H. Yang J. Wang 《The European Physical Journal B - Condensed Matter and Complex Systems》2009,69(3):337-341
We propose an electrical scheme for the generation of a pure spin current without a charge current in a two-terminal device,
which
consists of a scattering region of a two-dimensional electron gas
(2DEG) with Rashba (R) and/or Dresselhaus (S) spin-orbit interaction (SOI)
and two normal leads. The SOI is modulated by a time-dependent gate
voltage to pump a spin current. Based on a tight-binding model and
the Keldysh Green’s function technique, we obtain the analytical
expression of the spin current. It is shown that a pure spin current
can be pumped out, and its magnitude could be modulated by
device parameters such as the oscillating frequency of the SOI, as
well as the SOI strength. Moreover, the spin polarisation direction of
the spin current could also be tuned by the strength ratio between
RSOI and DSOI. Our proposal provides not only a fully electrical means
to generate a pure spin current but also a way to control the spin
polarisation direction of the generated spin current. 相似文献