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61.
Nadiah Zafar Geraldine Agusti Hatem Fessi 《Journal of Dispersion Science and Technology》2017,38(4):577-583
Researchers work on different optimization methods to come up with preparation methods, which show the desired or targeted outcomes. Moreover, nowadays, research is more focused on developing formulations which contain biodegradable polymers. The objective of the present systematic study was to achieve the abovementioned goals by using a cationic ammonio methacrylate copolymer (Eudragit® RS100). A Double-emulsion solvent evaporation technique was used. This methodology was chosen because the particles formed by this method allow encapsulation of both hydrophilic and hydrophobic active molecules. It also has applications in diverse fields such as drug delivery, food, cosmetics, and pharmaceutical industries.The aim of this research work was to investigate the influence of various process control parameters, such as stabilizer chemical nature and amount, ultra Turrax® stirring speed and time, the morphology, size, and size distribution of the final dispersions. Then, the prepared particles were characterized using a Scanning Electron Microscope (SEM) and a Laser Diffraction Particle Size Analyzer. This study helped us to know which parameters have a drastic effect on the colloidal properties of the particles. 相似文献
62.
An aromatic amphiphilic molecule based on branched oligo(ethylene oxide) was synthesized. Evaporation‐driven ring formation and Langmuir–Blodgett films are investigated by utilizing this rigid–flexible block molecule. The size of the rings is strongly dependent on the solvent evaporation rate and the concentration of the molecule. In case of fast evaporation, volcano‐like rings are formed by evaporating solution of high concentration. Perfectly symmetrical rings with diameters in the range of 2–6 μm are obtained by evaporating solution of low concentration. The formation mechanism of the ring is briefly discussed. The molecule at the air–water interface exhibits excellent amphiphilic properties. Upon transferring the monolayer onto solid substrates, AFM revealed the formation of fine and long, straight fibers. By combining the data obtained from the isotherms, AFM, water contact angle measurements, and UV/Vis and fluorescence spectra, the fibers are suggested to be formed by π–π stacking interaction of the aromatic rod segments as the oligo(ethylene oxide) branches are submerged in the water subphase upon compression. The fiber formation is associated with the transformation of the aromatic rod segments from the face‐on conformation to the edge‐on conformation. 相似文献
63.
64.
R. Cristescu C. PopescuA.C. Popescu S. GrigorescuI.N. Mihailescu A.A. CiucuS. Iordache A. AndronieI. Stamatin E. Fagadar-CosmaD.B. Chrisey 《Applied Surface Science》2011,257(12):5293-5297
We report the deposition by MAPLE of metallized nanostructured (5,10,15,20-tetraphenyl)porphinato manganese(III) chloride thin films onto gold screen-printed electrodes, or 〈1 1 1〉 Si substrates. The deposited nanostructures were characterized by atomic force microscopy and exhibited globular structures with average diameters decreasing with laser fluence. Raman spectroscopy showed that no major decomposition appeared. We have investigated the Mn(III)-metalloporphyrin thin films by cyclic voltammetry in order to evaluate the potential bio/chemosensing activity on dopamine neurotransmitter analyte. We have found that the manganese(III)-porphyrin is appropriate as a single mediator for dopamine sensing in the specific case of gold screen-printed electrodes. 相似文献
65.
E. S. Voropai A. P. Zazhogin K. I. Chervyakovskii 《Journal of Applied Spectroscopy》2003,70(2):195-200
The process of formation of a radiating discharge cloud in the case of a diffusion mechanism of impurity exit to the surface of a molten small-weight sample is considered. An analytical expression describing the behavior of the relative rate of impurity entry into a discharge is obtained. 相似文献
66.
67.
Hydrogenated amorphous-Si/SiO2 (a-Si:H/SiO2) superlattices with different a-Si : H thickness in the range of a few nanometers have been fabricated by ultra high vacuum evaporator (UHV evaporator). The photoluminescence (PL) of our superlattices is observed in the visible spectral region and the peak energy shifts to higher energy as the a-Si : H layer thickness decreases. The temperature dependence of the PL spectra reveals four sub-bands by fitting. Bands at 2.2, 1.9, 1.65 and 1.45 eV are detected and are attributed to E′δ centers, nonbridging-oxygen–hole centers (NBOHC), Si/SiO2 interface and a-Si : H layer, respectively. We explain the overall blueshift of the PL spectra by the modification of the contribution of these sub-bands. 相似文献
68.
Muhammad M. R. Qureshi Chao Zhu Chao-Hsin Lin Liang-Shih Fan 《中国颗粒学报》2006,4(3):147-152
A three-dimensional simulation study is performed for investigating the hydrodynamic behaviors of a cross-flow liquid nitrogen spray injected into an air-fluidized catalytic cracking (FCC) riser of rectangular cross-section. Rectangular nozzles with a fixed aspect ratio but different fan angles are used for the spray feeding. While our numerical simulation reveals a generic three-phase flow structure with strong three-phase interactions under rapid vaporization of sprays, this paper tends to focus on the study of the effect of nozzle fan angle on the spray coverage as well as vapor flux distribution by spray vaporization inside the riser flow. The gas-solid (air-FCC) flow is simulated using the multi-fluid method while the evaporating sprays (liquid nitrogen) are calculated using the Lagrangian trajectory method, with a strong two-way coupling between the Eulerian gas-solid flow and the Lagrangian trajectories of spray. Our simulation shows that the spray coverage is basically dominated by the spray fan angle. The spray fan angle has a very minor effect on spray penetration. The spray vaporization flux per unit area of spray coverage is highly non-linearly distributed along the spray penetration. The convection of gas-solid flow in a riser leads to a significant downward deviation of vapor generated by droplet vaporization, causing a strong recirculating wake region in the immediate downstream area of the spray. 相似文献
69.
70.
M.C.P. van Eijk M.A. Cohen Stuart S. Rovillard J. De Coninck 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,1(2):233-244
Nonequilibrium processes play a key role in the adsorption kinetics of macromolecules. It is expected that the competition
between transport of polymer towards an interface and its subsequent spreading has a significant influence on the adsorbed
amount. An increase of the transport rate can lead to an increase of the adsorbed amount, especially when the polymer has
too little time to spread at the interface. In this study we present both molecular dynamics simulations and analytical calculations
to describe some aspects of the adsorption kinetics. From MD simulations on a poly(ethylene oxide) chain in vacuum near a
graphite surface, we conclude that the spreading process can, in first approximation, be described by either a simple exponential
function or by first-order reaction kinetics. Combining these spreading models with the transport equations for two different
geometries (stagnation-point flow and overflowing cylinder) we are able to derive analytical equations for the adsorption
kinetics of polymers at solid-liquid and at liquid-fluid interfaces.
Received: 18 July 1997 / Received in final form: 27 October 1997 / Accepted: 6 November 1997 相似文献