全文获取类型
收费全文 | 10363篇 |
免费 | 2603篇 |
国内免费 | 1015篇 |
专业分类
化学 | 7052篇 |
晶体学 | 190篇 |
力学 | 126篇 |
综合类 | 69篇 |
数学 | 72篇 |
物理学 | 6472篇 |
出版年
2024年 | 9篇 |
2023年 | 84篇 |
2022年 | 227篇 |
2021年 | 279篇 |
2020年 | 369篇 |
2019年 | 280篇 |
2018年 | 290篇 |
2017年 | 286篇 |
2016年 | 440篇 |
2015年 | 483篇 |
2014年 | 575篇 |
2013年 | 1048篇 |
2012年 | 656篇 |
2011年 | 690篇 |
2010年 | 565篇 |
2009年 | 640篇 |
2008年 | 640篇 |
2007年 | 777篇 |
2006年 | 758篇 |
2005年 | 596篇 |
2004年 | 510篇 |
2003年 | 530篇 |
2002年 | 416篇 |
2001年 | 419篇 |
2000年 | 344篇 |
1999年 | 320篇 |
1998年 | 256篇 |
1997年 | 277篇 |
1996年 | 185篇 |
1995年 | 193篇 |
1994年 | 153篇 |
1993年 | 122篇 |
1992年 | 87篇 |
1991年 | 69篇 |
1990年 | 66篇 |
1989年 | 48篇 |
1988年 | 50篇 |
1987年 | 39篇 |
1986年 | 42篇 |
1985年 | 28篇 |
1984年 | 34篇 |
1983年 | 10篇 |
1982年 | 14篇 |
1981年 | 20篇 |
1980年 | 15篇 |
1979年 | 7篇 |
1978年 | 10篇 |
1975年 | 6篇 |
1974年 | 3篇 |
1973年 | 7篇 |
排序方式: 共有10000条查询结果,搜索用时 46 毫秒
121.
122.
We investigated iron and cobalt films with 20% carbon concentration with nanocrystalline structure. One of the aims of this work is to analyze the physical nature of high-speed structural self-assembling as often happens in explosive crystallization processes in these films. 相似文献
123.
P. Bonville M. Rams K. Królas J.-P. Sanchez P. C. Canfield O. Trovarelli C. Geibel 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,55(1):77-84
We have examined the magnetic properties of the heavy electron compounds
YbAgGe and YbPtIn by 170Yb M?ssbauer spectroscopy down to 0.1 K, and
the crystal field properties of YbAgGe by Perturbed Angular Correlations
(PAC) measurements up to 900 K. In YbAgGe, we show that each of the two
magnetically ordered phases below 0.8 K involves a specific incommensurate
modulation of the Yb moment. An analysis of existing low temperature specific
heat data suggests the
persistence of fluctuations of the correlated Yb spins down to 0.1 K.
The PAC data allow to discriminate among proposed Yb3+ crystal field
level schemes. In YbPtIn, we show that the low temperature magnetic order
phase has an antiferro-para structure, where zero moment Yb ions coexist with
large moment ones, and that a 90° moment reorientation occurs at
1.4 K. 相似文献
124.
利用微扰展开技术推导出变参数波振器的小信号增益两个近似求积表达式并将其计算结果与数值模拟结果进行了比较,二者吻合很好。利用近似解析式对小信号增益进行了初步探讨,得到了电子入射能量可低于初始谐振能,能散度允许范围受波振器设计影响以及降低锥度改变率可提高小信号增益等新结论。 相似文献
125.
Brad M. Rosen Virgil Percec 《Journal of polymer science. Part A, Polymer chemistry》2007,45(21):4950-4964
Atom transfer radical polymerization (ATRP) and single electron‐transfer living radical polymerization (SET‐LRP) both utilize copper complexes of various oxidation states with N‐ligands to perform their respective activation and deactivation steps. Herein, we utilize DFT (B3YLP) methods to determine the preferred ligand‐binding geometries for Cu/N‐ligand complexes related to ATRP and SET‐LRP. We find that those ligands capable of achieving tetrahedral complexes with CuI and trigonal bipyramidal with axial halide complexes with [CuIIX]+ have higher energies of stabilization. We were able to correlate calculated preferential stabilization of [CuIIX]+ with those ligands that perform best in SET‐LRP. A crude calculation of energy of disproportionation revealed that the same preferential binding of [CuIIX]+ results in increased propensity for disproportionation. Finally, by examining the relative energies of the basic steps of ATRP and SET‐LRP, we were able to rationalize the transition from the ATRP mechanism to the SET‐LRP mechanism as we transition from typical nonpolar ATRP solvents to polar SET‐LRP solvents. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4950–4964, 2007 相似文献
126.
Renhe Chu Jichang Yan Suoyuan Lian Yuehong Wang Fucheng Yan Dawei Chen 《Solid State Communications》2004,130(12):789-792
The interesting shape (shuttle-like, sphere with needles, uniform particles) rutile titania were prepared by the hydrolysis of TiCl4 in high acidic aqueous solution in the absence or presence of PEG-1000. PEG-1000 acted as dispersant, which could control the shape and size of the precipitate of titania. As a result, shuttle-like nanocrystalline appeared and the aggregation was improved with the increase of the amount of acid and the decrease of the concentration of TiCl4 in the absence of PEG-1000. Uniform nanoparticles were obtained in the presence of PEG-1000 and the diameter of the particles decreased with increasing the amount of PEG-1000. This process simplification will lower production cost and make continuous process possible. The products were analyzed using X-ray diffractometer, transmission electron microscopy. 相似文献
127.
K. Held D. Vollhardt 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,5(3):473-478
The importance of Hund's rule coupling for the stabilization of itinerant ferromagnetism is investigated within a two-band
Hubbard model. The magnetic phase diagram is calculated by finite-temperature quantum Monte-Carlo simulations within the dynamical
mean-field theory. Ferromagnetism is found in a broad range of electron fillings whereas antiferromagnetism exists only near
half filling. The possibility of orbital ordering at quarter filling is also analyzed.
Received: 26 February 1998 / Accepted: 17 April 1998 相似文献
128.
129.
T. González-Lezana G. Delgado-Barrio P. Villarreal F.X. Gadéa 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,20(2):227-232
The stabilization method is applied to the case of interacting resonances in the photo-dissociation of van der Waals clusters
composed by a rare gas atom bound to a dihalogen molecule. The study of an illustrative two-dimensional model consisting in
a T-shaped NeI2 molecule shows the adequacy of the method whenever the projection of the stabilization wave functions on the assumed prepared
initial state is accounted for. The agreement of the fragmentation cross-sections with some previous results using the effective
resolvent method and accurate close-coupling calculations is excellent. The method reveals its utility as a complementary
tool since allows, through the analysis of the stabilization wave function in terms of zero-order levels, a precise characterization
of the resonant states involved.
Received 5 April 2002 / Received in final form 24 May 2002 Published online 19 July 2002 相似文献
130.
T. V. Ramakrishnan H. R. Krishnamurthy S. R. Hassan G. Venketeswara Pai 《Journal of Chemical Sciences》2003,115(5-6):767-774
Manganites of the LA1−x
Ca
x
MnO3 family show a variety of new and poorly understood electronic, magnetic and structural effects. Here we outline a new approach
recently proposed by us, where we argue that due to strong Jahn-Teller (JT) coupling with phonons the twofold degeneratee
g
states at the Mn sites dynamically reorganize themselves into localised, JT polaronsl with exponentially small inter-site hopping, and band-like, nonpolaronic statesb, leading to anew 2-band model for manganites which includes strong Coulomb and Hund’s couplings. We also discuss some results from a dynamical mean-field theory treatment
of the model which explains quantitatively a wide variety of experimental results, including insulator-metal transitions and
CMR, in terms of the influence of physical conditions on the relative energies and occupation of thel andb states. We argue that this microscopic coexistence of the two types of electronic states, and their relative occupation and
spatial correlation is the key to manganite physics.
Dedicated to Professor C N R Rao on his 70th birthday 相似文献