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991.
The synthesis, characterization and thermal behavior of new monomeric allylpalladium (II) complexes with dichalcogenoamidodiphosphinate anions are reported. The complexes [R = H, R′ = Pri, E = S (1a); R = H, R′ = Pri, E = Se (1b); R = H, R′ = Ph, E = S (1c); R = H, R′ = Ph, E = Se (1d); R = Me, R′ = Pri, E = S (2a); R = Me, R′ = Pri, E = Se (2b); R = Me, R′ = Ph, E = S (2c); R = Me, R′ = Ph, E = Se (2d)] have been prepared by room temperature reaction of [Pd(η3-CH2C(R)CH2)(acac)] (acac = acetylacetonate) with dichalcogenoimidodiphosphinic acids in acetonitrile solution. The complexes have been characterized by multinuclear NMR (1H, 13C{1H}, 31P{1H}, 77Se{1H}), FT-IR and elemental analyses. The crystal structures of complexes 1a, 1d and 2d have been reported and they consist of a six-membered PdE2P2N ring (E = S for 1a and Se for 1d and 2d) and an allyl group, C3H4R(R = H for 1a and 1d and Me for 2d). Thermogravimetric studies have been carried out for few representative complexes. The complexes thermally decompose in argon atmosphere to leave a residue of palladium chalcogenides, which have been characterized by PXRD, SEM and EDS. 相似文献
992.
993.
994.
The mechanisms of reactions between CC13OO• radical and quercetin, rutin and epigallocatechin gallate (EGCG) have been studied using pulse radiolytic technique. It is
suggested that the electron transfer reaction is the main reaction between CC13OO• radical and rutin, EGCG, but there are two main pathways for the reaction of CC13OO• radical with quercetin, one is the electron transfer reaction, the other is addition reaction. The reaction rate constants
were determined. It is proved that quercetin and rutin are better CC13OO• radical scavengers than EGCG. 相似文献
995.
Masahisa Wada Takeshi Okano Junji Sugiyama Fumitaka Horii 《Cellulose (London, England)》1995,2(4):223-233
We have investigated unlignified tension wood and normally lignified wood celluloses inPopulus maximowiczii with particular reference to the composition of two crystalline phases I/I (triclinic/ monoclinic). Four independent techniques, which enable us to detect the two phases, CP/MAS13C NMR, Fourier transform infrared microscopy, selected-area electron diffraction, and X-ray diffraction were applied. Because of the low crystallinity of wood celluloses, particularly in the case of celluloses in the lignified cell wall, no single method was decisive enough to be able to determine the composition of the two phases as one can with highly crystalline materials. The I dominant structure (monoclinic crystal type) was, however, preferred for both tension and normal wood celluloses. 相似文献
996.
Structure and Photoelectric Characteristics of Functional Polymers and of Compositions Based on Them 总被引:1,自引:0,他引:1
The electronic processes in disordered organic solids were analyzed, classified, and summarized. They include the photogeneration of charge pairs, electron transport, geminal and bimolecular recombination, and the capture of charge carriers in local electronic states. General criteria were formulated for the targeted search for and the creation of new prospective polymers and their compositions with organic pigments and related compounds having specific photoelectric characteristics for electrographic and holographic media, photoelectric converters, and electroluminescent and photorefractive devices. 相似文献
997.
High-mobility two-dimensional electron gases at oxide interfaces: Origin and opportunities 下载免费PDF全文
Our recent experimental work on metallic and insulating interfaces controlled by interfacial redox reactions in SrTiO3-based heterostructures is reviewed along with a more general background of two-dimensional electron gas(2DEG)at oxide interfaces.Due to the presence of oxygen vacancies at the SrTiO3surface,metallic conduction can be created at room temperature in perovskite-type interfaces when the overlayer oxide ABO3has Al,Ti,Zr,or Hf elements at the B sites.Furthermore,relying on interface-stabilized oxygen vacancies,we have created a new type of 2DEG at the heterointerface between SrTiO3and a spinelγ-Al2O3epitaxial film with compatible oxygen ion sublattices.This 2DEG exhibits an electron mobility exceeding 100000 cm2·V 1·s 1,more than one order of magnitude higher than those of hitherto investigated perovskite-type interfaces.Our findings pave the way for the design of high-mobility all-oxide electronic devices and open a route toward the studies of mesoscopic physics with complex oxides. 相似文献
998.
999.
主要介绍自由电子激光相干强太赫兹源(FEL-THz)装置上的砷化镓光阴极直流高压注入器的研究进展,并讨论其驱动未来高重复频率短波长自由电子激光器的差距。通过综合砷化镓阴极寿命的三大影响因素,提出了其工作寿命的定性物理模型;通过该模型对阴极和注入器进行优化,在直流高压电子枪上得到了5 mA, 32 min的连续稳定输出;测量了电子束在4.8 mA下归一化发射度约为4.0 mmmrad,阴极热发射度约为0.6 mmmrad,电子束本征横向能量约为92 meV,250 keV电子束在距离阴极90.6 cm处纵向均方根长度约为11.5 ps。这一束流状态已经基本满足FEL-THz需求。 相似文献
1000.