全文获取类型
收费全文 | 3927篇 |
免费 | 711篇 |
国内免费 | 292篇 |
专业分类
化学 | 1503篇 |
晶体学 | 122篇 |
力学 | 703篇 |
综合类 | 46篇 |
数学 | 418篇 |
物理学 | 2138篇 |
出版年
2024年 | 5篇 |
2023年 | 36篇 |
2022年 | 67篇 |
2021年 | 86篇 |
2020年 | 97篇 |
2019年 | 103篇 |
2018年 | 111篇 |
2017年 | 119篇 |
2016年 | 122篇 |
2015年 | 107篇 |
2014年 | 191篇 |
2013年 | 444篇 |
2012年 | 241篇 |
2011年 | 226篇 |
2010年 | 201篇 |
2009年 | 248篇 |
2008年 | 272篇 |
2007年 | 262篇 |
2006年 | 260篇 |
2005年 | 226篇 |
2004年 | 200篇 |
2003年 | 163篇 |
2002年 | 165篇 |
2001年 | 113篇 |
2000年 | 100篇 |
1999年 | 77篇 |
1998年 | 95篇 |
1997年 | 81篇 |
1996年 | 67篇 |
1995年 | 82篇 |
1994年 | 63篇 |
1993年 | 46篇 |
1992年 | 41篇 |
1991年 | 42篇 |
1990年 | 29篇 |
1989年 | 24篇 |
1988年 | 22篇 |
1987年 | 11篇 |
1986年 | 16篇 |
1985年 | 17篇 |
1984年 | 13篇 |
1983年 | 5篇 |
1982年 | 10篇 |
1981年 | 4篇 |
1980年 | 3篇 |
1979年 | 2篇 |
1978年 | 5篇 |
1977年 | 3篇 |
1973年 | 3篇 |
1970年 | 1篇 |
排序方式: 共有4930条查询结果,搜索用时 31 毫秒
61.
The oxidative polycondensation of 4-[(pyridin-3-ylimino)methyl]phenol (4-PIMP) with O2, H2O2, and NaOCl was studied in an aqueous alkaline medium between 50°C and 90°C. Oligo-4-[(pyridin-3-ylimino)methyl]phenol (O-4-PIMP)
prepared was characterized by 1H-NMR, 13C-NMR, FT-IR, UV-VIS, size-exclusion chromatography, and elemental and thermal analyses techniques. At the optimum reaction
conditions, the yield of O-4-PIMP was 18.9%, 39.4%, and 46.8% using H2O2, O2, and NaOCl oxidant, respectively. According to the TG analysis, the initial degradation temperature of O-4-PIMP was 218°C,
which was by 50°C higher than that of 4-PIMP. Thermal analyses of 4-PIMP and O-4-PIMP were carried out in N2 atmosphere at 15–1000°C. The highest occupied molecular orbital, the lowest unoccupied molecular orbital, and electrochemical
energy gaps of 4-PIMP and O-4-PIMP were determined from the onset potentials for n-doping and p-doping, respectively. Also, optical band gaps of 4-PIMP and O-4-PIMP were determined according to UV-VIS measurements. 相似文献
62.
The purpose of this study is to investigate the influence of nickel, which is an alloying element in commonly used metallic biomaterials, on the biomaterials mineralization process. An electrochemical method was developed to quantify this metal ion in osteoblast-like cell culture medium (OST) by performing adsorptive cathodic stripping voltammetry (CSV) with dimethylglyoxime (DMG) at a mercury film microelectrode (MFM). The optimized analytical conditions and the square-wave CSV parameters for the analysis are: DMG concentration: 5.00 × 10−4 mol L−1; ammonium chloride buffer: 0.10 mol L−1 (pH 9.2); frequency: 50 Hz, amplitude 20 mV; step: 2 mV; adsorption time: 10 s, deposition potential: −0.70 V and reduction potential: −1.20 V. The limit of detection was 7.70 × 10−9 mol L−1 for an adsorption time of 10 s. The results achieved by CSV using the MFM were compared to those obtained by atomic absorption spectrometry (AAS) to ensure the reliability of the electrochemical method. The mineralization process was evaluated by biochemical and histochemical assays. 相似文献
63.
镓是第一个根据化学元素周期律预言并在自然界中证实的元素,是室温下电导率和热导率均为最大的液态物质,镓在电子工业中得到了广泛应用,被誉为电子工业“脊梁”。近十几年来,镓的更多应用潜力被发掘出来,在电子工业、散热、增材制造、柔性机器、生物医学等领域均有重要的应用前景。 相似文献
64.
C. DurioA. Daidouh N. ChouaibiC. Pico M.L. Veiga 《Journal of solid state chemistry》2002,168(1):208-216
New sodium orthophosphates of general formula Na2M3(PO4)3 belonging to the alluaudite-type structure have been synthesized and characterized by neutron and X-ray powder diffraction. The nature of the M3 elements (M3=GaMn2, GaCd2, InMn2 and FeMnCd) was chosen in order to analyze their influence on electrical and magnetic properties. The conductivity of these materials was measured by the complex impedance method and the transport mechanism was studied from complex permittivities and modulus formalism. Electrical results including charge/discharge experiments showed two main behaviors: GaCd2 and FeMnCd behave as purely ionic conductors whereas GaMn2 and InMn2 are mixed ionic-electronic conductors. The magnetic susceptibility data reveal the antiferromagnetic behavior of FeMnCd, InMn2 and GaMn2, with a weak ferromagnetic transition at low temperatures. 相似文献
65.
A new catalytic kinetic spectrophotometric method has been developed for the determination of trace amount of manganese (II) in nonionic microemulsion medium. The method is based on the catalytic effect of manganese (II) on the oxidation of dahlia violet by potassium periodate with nitrilotriacetic acid as an activitor in the presence of nonionic microemulsion. Under the optimum conditions, the calibration graph is linear in the range of 0.0004-0.0056 μg ml−1 of manganese (II) at 580 nm. The detection limit achieved is 3.75×10−5 μg ml−1. Manganese (II) in foodstuff samples was determined with satisfactory results. 相似文献
66.
含吲哚核端基多甲川菁染料的合成及性能 总被引:6,自引:0,他引:6
我们曾合成了具有桥环的硫三碳菁及多甲川苯乙烯菁,并测定了光学性能。本文报道吲哚环为端基的桥链三碳菁和四甲川苯乙烯菁的合成及在有机溶剂中电子吸收光谱及溶解性能的测定。所用仪器同前,7种多甲川菁染料的合成反应如下: 相似文献
67.
The electrochemical and in-situ surface-enhanced Raman spectroscopy (SERS) techniques were used to investigate the electrooxidation behavior of methanol in acidic, neutral and alkaline media at a Pt-Ru nanoparticle modified glassy carbon (Pt-Ru/GC) electrode. The results showed that methanol could be dissociated spontaneously at the Pt-Ru/GC electrode to produce a strongly adsorbed intermediate, CO. It was found that CO could be oxidized more easily in the alkaline medium than in the acidic and neutral media. The peak potential of methanol oxidation was shifted from 0.663 and 0.708 V in the acidic and neutral media to -0.030 V in the alkaline medium, which is due to that the adsorption strength of CO on the Pt surface in the alkaline medium is weaker than that in the acidic and neutral media. The final product of the methanol oxidation is CO2. However, in the alkaline medium, CO2 produced would form CO3^2- and HCO3^- resulting in the decrease in the alkaline concentration and then in the decrease in the performance of DMFC. Therefore, the performance of the alkaline DMFC is not Stable. 相似文献
68.
白藜芦醇分子的转动惯量和电偶极矩 总被引:4,自引:0,他引:4
通过分子轨道理论和杂化轨道理论推断出较稳定的白藜芦醇分子是平面型分子,然后根据白藜芦醇分子结构特点计算了该化合物的一种稳定异构体的转动惯量,用矢量合成法计算了其电偶极矩,为微波辅助白藜芦醇萃取理论研究提供转动惯量和电偶极矩的数据. 相似文献
69.
The relationship between the current and the bulk concentration of complex ions during concurrent specific adsorption of an electrochemically active complex ion and a complexing ligand is considered. The effect of parameters that characterize adsorption of such ions and the structure of the electrical double layer on this relationship is analyzed.__________Translated from Elektrokhimiya, Vol. 41, No. 7, 2005, pp. 817–822.Original Russian Text Copyright © 2005 by Rogozhnikov. 相似文献
70.
无DMSO、无血清细胞冻存液在临床级细胞产品的冷冻保存中具有重要的应用价值。本文以K562细胞为模型,设置含10%(v/v)DMSO及胎牛血清的冻存液为阳性对照,含10%(v/v)甘油的RPMI 1640培养基冻存液为阴性对照组,含10%(v/v)甘油及0.01%(w/v)γ-PGA的RPMI 1640培养基冻存液为实验组,考察了在无DMSO、无血清细胞冻存体系中γ-聚谷氨酸对细胞的冷冻保护作用。将K562细胞以1×10^6cells/mL的密度分别悬浮在上述冻存液中,置于液氮冻存10周,检测复苏后K562的细胞复苏率、细胞形态以及复苏后细胞的扩增情况,以评判γ-聚谷氨酸在无DMSO无血清冻存液中对K562细胞的冷冻保护作用。结果显示,实验组的细胞复苏率为(83.00±3.00)%,明显高于阴性对照组的(70.33±5.51)%(p<0.05)和阳性对照组的(71.00±2.65)%(p<0.05);且实验组冻存后的细胞形态完整,冻存前后细胞的平均直径及圆度基本一致,细胞复苏后培养24h后的细胞活性为(88.83±14.29)%,明显高于阴性对照组的(67.51±5.20)%(p<0.05),与阳性对照组的(78.75±3.31)%没有显著性差异,同时复苏后细胞扩增的延滞期明显缩短。可见,在无DMSO、无血清的甘油冻存体系中添加γ-PGA可显著提高细胞的冻存效果,具有良好的实际应用价值。 相似文献