全文获取类型
收费全文 | 7522篇 |
免费 | 1377篇 |
国内免费 | 303篇 |
专业分类
化学 | 1472篇 |
晶体学 | 230篇 |
力学 | 1802篇 |
综合类 | 62篇 |
数学 | 938篇 |
物理学 | 4698篇 |
出版年
2025年 | 26篇 |
2024年 | 139篇 |
2023年 | 141篇 |
2022年 | 158篇 |
2021年 | 211篇 |
2020年 | 271篇 |
2019年 | 275篇 |
2018年 | 259篇 |
2017年 | 333篇 |
2016年 | 331篇 |
2015年 | 252篇 |
2014年 | 421篇 |
2013年 | 639篇 |
2012年 | 447篇 |
2011年 | 493篇 |
2010年 | 359篇 |
2009年 | 429篇 |
2008年 | 422篇 |
2007年 | 413篇 |
2006年 | 389篇 |
2005年 | 325篇 |
2004年 | 305篇 |
2003年 | 289篇 |
2002年 | 221篇 |
2001年 | 202篇 |
2000年 | 194篇 |
1999年 | 185篇 |
1998年 | 152篇 |
1997年 | 154篇 |
1996年 | 134篇 |
1995年 | 98篇 |
1994年 | 77篇 |
1993年 | 51篇 |
1992年 | 63篇 |
1991年 | 62篇 |
1990年 | 40篇 |
1989年 | 31篇 |
1988年 | 40篇 |
1987年 | 33篇 |
1986年 | 27篇 |
1985年 | 28篇 |
1984年 | 14篇 |
1983年 | 6篇 |
1982年 | 19篇 |
1981年 | 7篇 |
1980年 | 5篇 |
1979年 | 10篇 |
1978年 | 9篇 |
1977年 | 6篇 |
1957年 | 2篇 |
排序方式: 共有9202条查询结果,搜索用时 15 毫秒
51.
52.
Bindiya Chana 《Journal of Macromolecular Science: Physics》2017,56(11-12):863-872
The optical, electrical and acoustical properties of polymer solutions based on polyvinyl pyrrolidone (PVP) doped with cupric sulphate (CuSO4) were studied. The polymer solutions were prepared by varying the concentration of Cu in the PVP using a simple chemical route. The UV-visible spectroscopy results showed that the optical absorbance decreased with an increase in wavelength from 300 to 700 nm. The optical band gaps were found to decrease with addition of the Cu salt in the polymer. The refractive index also showed significant variation with the doping of the CuSO4. The electrical conductivity of the polymer solutions was found to increase with temperature as well as concentration of Cu while the activation energy of electrical conduction decreased with concentration of Cu. The ultrasonic velocities of the polymer solutions were measured at a frequency of 1 MHz using an ultrasonic interferometer. The ultrasonic velocity and surface tension were increased while the adiabatic compressibility, acoustic impedance and intermolecular free length, the average distance between the surfaces of the coils of adjacent molecules, were decreased with increase in the concentration of CuSO4 in the PVP. 相似文献
53.
The Franck–Condon factors and r‐centroids, which are very closely related to relative transition probabilities, have been evaluated by a more reliable numerical integration procedure for the B1π–X1Σ+, C1Σ+–X1Σ+, F1Σ+–X1Σ+, and G1π–X1Σ+ band systems of the YF molecule, using suitable potentials. 相似文献
54.
In this paper, we explore the use of nanostructures for a number of fascinating applications. These applications based on nanostructures include (1) optical sensors, (2) nanopixel printing, (3) improving the resolution of imaging techniques, and (4) lithography. In the sensing field, nanostructures are exploited for advanced sensor performance, namely, the label-free and enhanced sensitivity of (1) the surface plasmon resonance sensor and (2) the extraordinary optical transmission sensor and (3) the high sensitivity and selectivity of surface-enhanced Raman spectroscopy. In addition, research using nanostructures for visual applications was introduced for (1) harnessing nanostructures for full-color pixel printing and (2) exploiting metallic nanostructures to enhance the imaging resolution under diffraction limits based on the plasmonic effect. Finally, we introduce low cost, high accuracy, and fast lithographic methods based on the plasmonic effect by exploiting metallic nanostructures. 相似文献
55.
56.
首次报告在A3M2Ge3O12∶Cr(A=Cd2+,Ca2+;M=Al3+,Ga3+,Sc3+)锗酸盐石榴石体系中,Cr3+离子室温下的红—近红外(R—NIR)宽发射带光谱性质。随位于八面体格位上的Al3+→Ga3+→Sc3+和十二面体格位上的Cd2+→Ca2+组成顺序变化,室温下,Cr3+离子的4T2→4A2能级跃迁的R-NIR宽发射带,发射峰及光谱的长波和短波边逐渐向低能长波边移动。这是由于晶场强度减弱,阳离子的离子半径增大的结果。在镉(钙)铝和镉(钙)镓锗酸盐体系中,少量Sc3+取代八面体上的Al3+和Ga3+时,可使Cr3+的R-NIR荧光发射强度增强。 相似文献
57.
Nikolay Tyutyulkov Ivo Kanev Oskar Polansky Jürgen Fabian 《Theoretical chemistry accounts》1977,46(3):191-203
The analysis of experimental data for singlet transitions (E
n) of even polyenes (I), cations (II) and anions (III) of odd polyenes show that for infinite chains E
(I)/E
(II)=E
(I)/E
(III) = 2:1. It is shown that the energy gap is equal for the three systems. In cases (II) and (III) there is a level (NBMO) in the gap which is vacant in (II) and occupied in (III). That is why the first optical transition in (II) and (III) depends on the semiwidth of the gap. 相似文献
58.
CAI Shu-Hui LI Jun LIU Chun-WanFujian Institute of Research on the Structure of Matter Chinese Academy of Sciences State Key Laboratory of Structural Chemistry Fuzhou Fujian China 《中国化学》1994,12(5):385-391
The band structures of several analogous superconducting A-15 type solid compounds, Nb3X (X=Si, Ge, Sn, Pb), have been calculated by use of the tight-binding method within the Extended Huckel approximation (EHT). By analysis of their energy bands, densities of states and crystal orbital overlap populations, the dependence of the superconducting transition temperatures (Tc) on the electronic structures and bondings is qualitatively elucidated. 相似文献
59.
Yanjun Gong Yongxian Guo Fayuan Ge Wei Xiong Jie Su Yang Sun Chuang Zhang An-Min Cao Yifan Zhang Jincai Zhao Yanke Che 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(26):10423-10428
The light-driven crawling of a molecular crystal that can form three phases, (α, β, and γ) is presented. Laser irradiation of the molecular crystal can generate phase-dependent transient elastic lattice deformation. The resulting elastic lattice deformation that follows scanning irradiation of a laser can actuate the different phases of molecular crystal to move with different velocity and direction. Because the γ phase has a large Young's modulus (ca. 26 GPa), a force of 0.1 μN can be generated under one laser spot. The generated force is sufficient to actuate the γ-formed molecular crystals in a wide dimensional range to move longitudinally at a velocity of about 60 μm min−1, which is two orders of magnitude faster than the α and β phases. 相似文献
60.
Shotaro Hayashi Fumitaka Ishiwari Takanori Fukushima Shohei Mikage Yutaka Imamura Motomichi Tashiro Michio Katouda 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(37):16329-16335
Elastic organic crystals have attracted considerable attention as next-generation flexible smart materials. However, the detailed information on both molecular packing change and macroscopic mechanical crystal deformations upon applied stress is still insufficient. Herein, we report that fluorescent single crystals of 9,10-dibromoanthracene are elastically bendable and stretchable, which allows a detailed investigation of the deformation behavior. We clearly observed a Poisson effect for the crystal, where the short axes (b and c-axes) of the crystal are contracted upon elongation along the long axis (a-axis). Moreover, we found that the Poisson's ratios along the b-axis and c-axis are largely different. Theoretical molecular simulation suggests that the tilting motion of the anthracene may be responsible for the large deformation along the c-axis. Spatially resolved photoluminescence (PL) measurement of the bent elastic crystals reveals that the PL spectra at the outer (elongated), central (neutral), and inner (contracted) sides are different from each other. 相似文献