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81.
In this paper the distribution of the maximum number of customers in a retrial orbit for a single server queue with Markovian arrival process and phase type services is studied. Efficient algorithm for computing the probability distribution and some interesting numerical examples are presented.  相似文献   
82.
微通道板增益疲劳机理研究   总被引:2,自引:0,他引:2  
微通道板的增益疲劳是微通道板的主要问题之一,本文分析了微通道板的表面结构模型,同通道板活性表面上碱金属的逸出和碳的增加是导致微通道板的增益疲劳的主要原因,另外,探讨碱金属逸出的机理和碳污染的来源,介绍延长微通道板工作寿命的有效方法。  相似文献   
83.
We study single server periodic queues in the day equilibrium conditions. The following characteristics of interest are considered at time of dayt: Vp(t)-the work load, Lp(t)-the number of customers and up(t)-the departure rate. We give relationships between E[Vp(t)], E[Lp(t)] and up(t). We also prove that E[Vp(t)] < and E[Lp(t)] < provided the second moment of the service time is finite.  相似文献   
84.
Some cationic surfactants such as cetyltrimethylammonium bromide (CTAB) show a very spectacular viscoelasticity in solution, in even very diluted states, with some aromatic substances added, such as salicylic acid. Formerly, the authors established that the remarkable solution behaviour was the result of the entanglement of such enormously elongated giant micelles, based on recognition of the existence of large aggregates, through direct observation of them as substantial images under the electron microscope.In this report, we further confirm the relation between micelle length and solution viscoelasticity after arbitrarily obtaining different size aggregates by altering the media pH, or by admixing shorter chain length surfactants than CTAB, which alone did not induce viscoelasticity.  相似文献   
85.
In this report, the role of local polymer-solvent π-π-interaction on rotational dynamics of phenyl rings of poly[2-methoxy-5-(2′-ethyl-hexyloxy)-1,4-phenylenevinylene] (MEH-PPV) is examined by utilizing nuclear magnetic resonance (NMR) spectroscopy. We have found that an aromatic solvent can couple strongly with the phenyl rings via favorable local π-π-interaction, causing a restriction of the ring rotation. The dynamic process takes place at much faster rate in a non-aromatic solvent. NMR line shape analysis indicates the existence of two side chain configurations with relatively long life-time in toluene and pyridine while a single time-averaged configuration is detected in chloroform and tetrahydrofuran. Addition of chloroform or cyclohexane to a solution of MEH-PPV in toluene is accompanied by an increase of the rotational dynamics. This indicates that the expansion or collapse of main chain upon varying solvent quality play a minor role on the rotational dynamics. The relationship between the dynamics of ring rotation and photophysics of MEH-PPV in solution is discussed.  相似文献   
86.
反相高效液相色谱法的多波长同时测定预混合饲料中的脂溶性维生素A,α-E,D_3,K_3李桂凤,李缙扬,郝征红,聂燕,孟兆宏,李学春(山东省农业科学院中心实验室济南250100)1前言对脂溶性维生素的分析,被许多国内外分析专家认为是高难度的分析项目。本...  相似文献   
87.
88.
The molecular weight distribution (MWD) and arm length distribution of AB, Ar type condensation polymers obtained by adding AB monomers in batches have been derived by statistical and kinetic methods. Calculations show the MWD of condensation polymers obtained by this process is much narrower than that of one batch reaction and agrees with the Monte Carlo results very well.  相似文献   
89.
M~++BrCN─→MCN~++Br气相反应的从头算研究朱荣顺,戴树珊(云南大学化学系,昆明,650091)关键词气相反应,过渡金属阳离子,溴化氰,从头算,相对论赝势对过渡金属离子与一些小分子的气相反应已有大量的实验和理论研究[1~5],MichelS...  相似文献   
90.
Recent developments in quantitative surface analysis by Auger (AES) and x-ray photoelectron (XPS) spectroscopies are reviewed and problems relating to a more accurate quantitative interpretation of AES/XPS experimental data are discussed. Special attention is paid to consideration of elementary physical processes involved and influence of multiple scattering effects on signal line intensities. In particular, the major features of core-shell ionization by electron impact, Auger transitions and photoionization are considered qualitatively and rigorous approaches used to calculate the respective transition probabilities are analysed. It is shown that, in amorphous and polycrystalline targets, incoherent scattering of primary and signal Auger and photoelectrons can be described by solving analytically a kinetic equation with appropriate boundary conditions. The analytical results for the angular and energy distribution, the mean escape depth, and the escape probability as a function of depth of origin of signal electrons as well as that for the backscattering factor in AES are in good agreement with the corresponding Mote Carlo simulation data. Methods for inelastic background subtraction, surface composition determination and depth-profile reconstructions by angle-resolved AES/XPS are discussed. Examples of novel techniques based on x-ray induced photoemission are considered.  相似文献   
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