Study on the binding of 2,3-diazabicyclo[2.2.2]oct-2-ene with bovine serum albumin by fluorescence spectroscopy

The interaction of 2,3-diazabicyclo[2.2.2]oct-2-ene (DBO) with bovine serum albumin (BSA) has been studied using absorption and steady state fluorescence techniques. Fluorescence spectrum of BSA (λ_exi=280 nm) in the presence of DBO clearly shows that DBO acts as a quencher. The number of binding sites ‘n’ and apparent binding constant ‘K’ were measured by Stern-Volmer equation. Synchronous fluorescence and absorption spectra were used to study protein conformation. The interaction between DBO and BSA is consistent with static quenching and the conformational changes of BSA observed.     

磷化物三元混晶中电子-声子相互作用的维度和体积效应

考虑电子-声子耦合强度因维度而异,导出了描述三维、二维和一维混晶中电子-声子相互作用的哈密顿量。考虑构成三元混晶的两种二元晶体的晶格失配会使混晶体积随元素组分比改变,在推导三维、二维和一维三元混晶中极化子自陷能量和重整化有效质量时计入了离子相对位移与二元晶体原胞体积的关系。结果表明:磷化物三元混晶中极化子自陷能量和重整化有效质量随元素组分的变化关系呈明显的非线性特征,对晶格适配明显、电子-声子耦合较强的材料,体积效应不可忽略。维度越低,非线性特征和体积效应越明显。     

Effective nucleon-nucleon interactions and nuclear matter equation of state

Nuclear matter equations of state based on Skyrme, Myers-Swiatecki and Tondeur interactions are written as polynomials of the cubic root of density, with coefficients that are functions of the relative neutron excess δ. In the extrapolation toward states far away from the standard one, it is shown that the asymmetry dependence of the critical point ( ,) depends on the model used. However, when the equations of state are fitted to the same standard state, the value of is almost the same in Skyrme and in Myers-Swiatecki interactions, while is much lower in Tondeur interaction. Furthermore, does not depend sensitively on the choice of the parameter γ in Skyrme interaction. Received: 5 May 2000 / Accepted: 16 January 2001     

苯乙酮类化合物的碳谱研究

本文分析了九个被羟基和和（或）甲氧基取代的苯乙酮类化合物的碳谱数据，首次提出了理论计算这类化合物芳环碳化学位移的计算公式以及羟基和甲氧基的取代参数。羟基的取代参数分别为：３０．４（Ｚ），－１３．２（Ｚ）（Ｚｍ）和－７．８（Ｚｐ），甲氧基的取代参数分别为：３０．５（Ｚｉ），－１４．１（Ｚｏ），０．６（Ｚｍ）和－７．２（Ｚｐ）。计算公式分别为：δＣ１＝１３７．３＋ΣＺδＣ４＝１３３．０＋ΣＺresume     

光栅常数的简便测量方法

本文给出光栅常数两种简便测量方法。     

质子自旋性质的研究

考虑了正、反海夸克对和胶子混杂态对质子波函数的影响，质子的一些自旋相关性质：轴矢流耦合常数ＧＡ／ＧＶ，结构函数ｇ１ｎ和ｇ１ｐ的计算得到了改进．     

S-wave baryons in an equally mixed scalar-vector square root potential model of independent quarks

A relativistic model of independent quarks based on Dirac equation with an equally mixed scalar-vector square root confining potential is used to compute the quark core contributions to the static properties like magnetic moments, charge radii and axial vector coupling constant ratios of the baryon octet. The results obtained with appropriate corrections due to centre-of-mass motion agree fairly well with experimental values. The model is also extended to the study of magnetic moments of the quark core of baryons in the charmed andb-flavoured sectors and the overall predictions so obtained compare well with other model predictions.     

脊形波导中导模传输与损耗的分析与计算

本文运用有效折射率法把脊形波导化成等效二维平板波导后,再运用微分法求出弱吸收情况下波导模的吸收损耗,其方法简便,精确度高.     

几种叔丁墓酚化合物的核磁共振研究

研究了11种叔丁基酚化合物的化学位移和偶合常数,并讨论了影响因素.