Synthesis,Crystal Structure and Luminescent Property of a Novel Pt（Ⅱ） Complex with Weak Metal-metal Interaction

The title complex cis-bis（tetrahydrothiophene）-bis（nitrate） platinum（H）, （tht）2Pt（NO3）2, was the reducing product from potassium hexachloroplatinate（IV） K2PtC16 where the platinum is tetra-valenced. Crystal data for CsH16N206PtS2： monoclinic, space group P21/c, a = 9.8833（5）, b = 8.6744（4）, c = 18.6407（9）A,β = 114.401（3）°, V = 1455.35（12）A3 Z = 4, Mr = 495.44, Dc = 2.261 g/cm3, F（000） = 944,μ = 9.950 mm-1, 2（MoKa） = 0.71073 A, T= 293（2） K, 2θmax = 54.96°, GOOF = 1.033, R = 0.0350 and wR = 0.0785 for 2572 observed reflections with I 〉 2σ（I）. X-ray diffraction studies reveal that the title complex has interesting weak metal-metal interactions and two molecules linked by metal-metal interaction exist as a group. Luminescent spectrum illuminates red emission of the complex at room temperature.     

允许卖空的资本市场中存在非负均衡价格向量的充要条件

For the capital market satisfying standard assumptions that are widely adopted in the equilibrium analysis,a necessary and sufficient condition for the existence and uniqueness of a nonnegative equilibrium price vector that clears the mean-variance capital market with short sale allowed is derived. Moreover, the given explicit formula for the equilibrium price shows clearly the relationship between prices of assets and statistical properties of the rate of return on assets, the desired rates of return of individual investors as well as other economic quantities.The economic implication of the derived condition is briefly discussed. These results improve the available results about the equilibrium analysis of the mean-variance market.     

Specific Interactions. Intermolecular Forces,Steric Requirements,and Molecular Size

Specific interactions or recognition processes are extremely important in many fields of chemistry and biology: typical examples are the enzyme-substrate and the antigen-antibody reactions. Quantitative predictions require a knowledge of steric fit, intermolecular forces, and molecular size. These considerations should facilitate design of new drugs.     

Ultrasonic measurements on the solutions of lanthanum and cerium soaps in non-aqueous medium

The ultrasonic velocity and density measurements of lanthanum and cerium soaps in a mixture of 60 % benzene and 40 % methanol (v/v) were used to evaluate various acoustic and thermodynamic parameters and to determine the CMC. The results were interpreted in terms of soap-solvent interaction.     

Phase transitions in diluted magnets: Critical behavior,percolation, and random fields

Transition metal halides provide realizations of Ising,XY, and Heisenberg antiferromagnets in one, two, and three dimensions. The interactions, which are of short range, are generally well understood. By dilution with nonmagnetic species such as Zn⁺⁺ or Mg⁺⁺ one is able to prepare site-random alloys which correspond to random systems of particular interest in statistical mechanics. By mixing two magnetic ions such as Fe⁺⁺ and Co⁺⁺ one can produce magnetic crystals with competing interactions-either in the form of competing anisotropies or competing ferromagnetic and antiferromagnetic interactions. In this paper the results of a series of neutron scattering experiments on these systems carried out at Brookhaven over the past several years are briefly reviewed. First the critical behavior in Rb₂Mn_0.5Ni_0.5F₄ and Fe_cZn_1–cF₂ which correspond to two-dimensional and three-dimensional random Ising systems, respectively, are discussed. Percolation phenomena have been studied in Rb₂Mn_cMg_l–cF₄, Rb₂Co_cMg_l–cF₄, KMn_cZ_l-cF₃, and Mn_cZn_l–cF₂ which correspond to two-and three-dimensional Heisenberg and Ising models, respectively. In these casesc is chosen to be in the neighborhood of the nearest-neighbor percolation concentration. Application of a uniform field to the above systems generates a random staggered magnetic field; this has facilitated a systematic study of the random field problem. As we shall discuss in detail, a variety of novel, unexpected phenomena have been observed.     

Applicability of Raoult's law in nonideal mixed solvents

In general, the vapor-pressure change due to the addition of a solute to a solvent mixture does not follow Raoult's law. We have demonstrated thermodynamically that if one adds to a binary solvent mixture solute and solvents in such a way that the vapor-phase composition remains constant, then the decrease of total pressure follows Raoult's law; a supplementary term which vanishes for very dilute solute concentration is introduced as a consequence of the nonideality of the ternary solution. Precise vapor-pressure measurements of dilute solutions of electrolytes and nonelectrolytes in a 40.000 wt. % water-tetrahydrofuran mixture are used in order to illustrate the applicability of Raoult's law under the above conditions. These may be regarded as a particular case of what has been called endostatic conditions, i.e., addition of a solute under constant solvent activity ratio.     

The synthesis and characterization of amine-terminated poly(aryl ether ketone)s as a function of side group and molecular weight

It is shown that amine-terminated poly(aryl ether ketone)s based on the reaction of 4,4'-difluorobenzophenone, and a substituted hydroquinone [either methylhydroquinone (MePK), t-butylhydroquinone (tBPK), or phenylhydroquinone (PhPK)] of controlled molecular weight and high amine-termination efficiency can be synthesized by a two-step reaction technique. Attempts to synthesize analogous materials by a one-step method were shown to be unsuccessful. The side groups are shown to have a large influence on the aromatic proton chemical shifts and this effect is characterized. The side groups and molecular weight are also shown to influence the thermal transitions of the respective polymers. The tBPK polymer possessed the highest glass transition temperature, while the MePK polymer was found to be the only semi-crystalline polymer; a unit cell is proposed. The side groups and molecular weight effects are also characterized as a function of thermal stability and mechanical properties. © 1994 John Wiley & Sons, Inc.     

A point implicit unstructured grid solver for the euler and Navier–Stokes equations

An upwind finite element technique that uses cell-centred quantities and implicit and/or explicit time marching has been developed for computing hypersonic laminar viscous flows using adaptive triangular grids. The approach is an extension to unstructured grids of the LAURA algorithm due to Gnoffo. A structured grid of quadrilaterals is laid out near a solid surface. For inviscid flows the method is stable at Courant numbers of over 100000. A first-order basic scheme and a higher-order flux-corrected transport (FCT) scheme have been implemented. This technique has been applied to the problem of predicting type III and IV shock wave interactions on a cylinder, with a view to simulating the pressure and heating rate augmentation caused by an impinging shock on the leading edge of a cowl lip of an engine inlet. The predictions of wall pressure and heating rates compare very well with experimental data. The flow features are distinctly captured with a sequence of adaptively generated grids.     

Experimental study on the retention of silica particles in gravitational field-flow fractionation effects of the mobile phase composition

Effects of mobile phase composition can play an effective role in modulating the retention of particles in gravitational field-flow fractionation (GFFF), the simplest and cheapest among field-flow fractionation (FFF) techniques. In the framework of an optimized procedure for the GFFF characterization of particulate systems, an experimental approach to the effects of the mobile phase composition on the retention of silica particles retention is presented. The role of the ionic strength and the presence of surfactant are emphasized, with special regards to the shape of the particles. Moreover, the first experimental evidence of potential-barrier GFFF is reported.     

Is there a photon excess or photon deficit in the cosmic events?

Summary Bjorken predicted in the recent past about the large excess emission of photons in high-energy collisions and this was subsequently corroborated by some experimentalists as well. Obviously, this phenomenon is just opposite in nature to pro-centauro events marked by the production of photonless hadrons. In this note we will try to trace the outlines of this confusing and contradictory situation, probe quantitatively into this excess emission of photons (called progammaisation events) and compare them mainly with Bjorken's disoriented-chiral-condensate (DCC) model.