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71.
《Comptes Rendus Chimie》2014,17(7-8):687-700
The influence of the presence of H2O on the contact between carbon, used as model soot, and a model four-way catalyst (1% Pt–10% BaO/Al2O3) was investigated. NOx adsorption/TPD cycles at 300 °C together with XRD, XPS and DRIFTS characterizations showed that only surface nitrate species are destabilized by the carbon present in the catalytic bed, leading to a decrease of the NOx storage capacity and carbonate species formation. In another way, injection of water in the reactive gas flow decreases also the NOx storage capacity of the catalyst, but promotes the formation of stable nitrate species. A non-cumulative effect of carbon and water was observed. It was proposed that a competition between the destabilization, by carbon, of weakly bonded surface nitrate species and the enhancement of bulk nitrate species formation in the presence of water occurs. 相似文献
72.
To study phase transition kinetics on submillisecond time scale a sensitive ultrafast nanocalorimeter was constructed. Controlled
ultrafast cooling, as well as heating, up to 106K/s was attained. The method was applied for the measurements of the superheating phenomenon in a set of linear polymers:
iPS, PBT, PET, and iPP. A power law relation between the superheating and the heating rate holds in the heating rate range
10-2-104K/s. A limiting superheating of about 10% of the melting temperature was observed at rates above 104-105K/s. This limit depends on annealing conditions before sample melting. The observed superheating limit, as well as the power
law, can be accounted for the internal stresses near the crystalline amorphous interface in semicrystalline polymers induced
by heating, which are related to the thermal expansion gradients inherent in a semicrystalline material. 相似文献
73.
Changing the orientational order in liquid-crystal
elastomers leads to internal stresses and changes of the sample
shape. When this effect is induced by light, due to
photoisomerization of constituent molecular moieties, the
photomechanical actuation results. We investigate quantitatively
how the intensity and the polarization of light affect
photoactuation. By studying dissolved, as well as covalently
bonded azo-dyes, we determine the changes in absorption and the
response kinetics. For the first time we compare the response of
aligned monodomain, and randomly disordered polydomain nematic
elastomers, and demonstrate that both have a comparable
photoresponse, strongly dependent on the polarization of light.
Polarization-dependent photoactuation in polydomain elastomers
gives an unambiguous proof of its mechanism since it is the only
experiment that distinguishes from the associated thermal
effects. 相似文献
74.
This paper investigates finite-stretching corrections
to the classical Milner-Witten-Cates theory for semi-dilute
polymer brushes in a good solvent. The dominant correction to the
free energy originates from an entropic repulsion caused by the
impenetrability of the grafting surface, which produces a
depletion of segments extending a distance μ∝L-1
from the substrate, where L is the classical brush height. The
next most important correction is associated with the
translational entropy of the chain ends, which creates the
well-known tail where a small population of chains extend beyond
the classical brush height by a distance ξ∝L-1/3.
The validity of these corrections is confirmed by quantitative
comparison with numerical self-consistent field theory. 相似文献
75.
Y.-X. Ping B. Zhang Z. Cheng 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,44(1):175-180
The generation of continuous variable entanglement via
atomic coherence in a two-mode three-level cascade atomic system
is discussed according to the entanglement criterion proposed by
Duan et al. [Phys. Rev. Lett. 84, 2722 (2000)].
Atomic coherence between the top and bottom levels is induced with
two photons of a strong external pump field. It shows that
entanglement for the two-mode field in the cavity can be generated
under certain conditions. Moreover, by means of the input-output
theory, we show that the two-mode entanglement could also be
approached at the output. 相似文献
76.
P. F. Yu J. G. Cai J. M. Liu G. T. Shen 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,44(1):151-158
We investigate the phase decoherence effects on
the entanglement of a two-qubit anisotropic Heisenberg
model
with a nonuniform magnetic field in the x–z-plane. As a
measure of the entanglement, the concurrence of the system is
calculated. It is shown that when the magnetic field is along the
z-axis, the nonuniform and uniform components of the field have
no influence on the entanglement for the cases of
and
, respectively. But when
the magnetic field is not along the z-axis, both the uniform and
the nonuniform components of the field will introduce the
decoherence effects. It is found that the effects of the
Heisenberg chain's anisotropy in the Z-direction on the
entanglement are dependent on the direction of the field.
Moreover, the larger the initial concurrence is, the higher value
it will exhibit during the time evolution of the system for a
proper set of the parameters ν, Δ, θ, γ
, B and b. 相似文献
77.
In this study, a phase-change memory device was fabricated and the origin of device failure mode was examined using transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDS). Ge2Sb2Te5 (GST) was used as the active phase-change material in the memory device and the active pore size was designed to be 0.5 m. After the programming signals of more than 2×106 cycles were repeatedly applied to the device, the high-resistance memory state (reset) could not be rewritten and the cell resistance was fixed at the low-resistance state (set). Based on TEM and EDS studies, Sb excess and Ge deficiency in the device operating region had a strong effect on device reliability, especially under endurance-demanding conditions. An abnormal segregation and oxidation of Ge also was observed in the region between the device operating and inactive peripheral regions. To guarantee an data endurability of more than 1×1010 cycles of PRAM, it is very important to develop phase-change materials with more stable compositions and to reduce the current required for programming. 相似文献
78.
We investigate the multifractal properties of price increments in the cases of derivative and spot markets. Through the multifractal detrended fluctuation analysis, we estimate the generalized Hurst and the Renyi exponents for price fluctuations. By deriving the singularity spectrum from the above exponents, we quantify the multifractality of a financial time series and compare the multifractal properties of two different markets. The different behavior of each agent-group in transactions is also discussed. In order to identify the nature of the underlying multifractality, we apply the method of surrogate data to both sets of financial data. It is shown that multifractality due to a fat-tailed distribution is significant. 相似文献
79.
Using a master equation for the reduced density matrix of open quantum system, the influence of coordinate-dependent microscopical diffusion coefficients on the decay rate from a potential well is studied. For different temperatures, frictions, heights of barrier and ratios of stiffnesses of the potential in the minimum and on the top of the barrier, the quasistationary decay rates are obtained with the sets of coordinate-dependent and -independent microscopical diffusion coefficients, and coordinate-dependent phenomenological diffusion coefficients. 相似文献
80.
Recently pattern formation in layered structures, showing complicated superimposed patterns, has been modeled by coupling two Turing systems linearly, i.e., passively, such that the characteristic length scales of the independent systems are well separated. Here we propose a model of two non-linearly coupled Turing systems to study pattern formation in layered membrane-like structures, where the coupling plays an active role and changes the kinetics of the uncoupled systems. Extensive numerical simulations show that non-linear coupling generates a number of new regular patterns different from the ones observed earlier with linearly coupled systems. Some of them turn out to be superimposed patterns with different length scales, but many are not. Also, contrary to the linear coupling case, the strength of the non-linear coupling is found to play an important role in the formation and selection of patterns. 相似文献