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101.
Theoretical study of (e, 2e) triple differential cross sections of pyrimidine and tetrahydrofurfuryl alcohol molecules using multi-center distorted-wave method
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We report theoretical studies of electron impact triple differential cross sections of two bio-molecules,pyrimidine and tetrahydrofurfuryl alcohol,in the coplanar asymmetric kinematic conditions with the impact energy of 250 eV and ejected electron energy of 20 eV at three scattering angles of-5°,-10°,and-15°.Present multi-center distorted-wave method well describes the experimental data,which was obtained by performing(e,2e)experiment.The calculations show that the secondary electron produced by the primary impact electron is strongly influenced by the molecular ionic multi-center potential,which must be considered when the low energy electron interacts with DNA analogues. 相似文献
102.
Margarita A. Epishina Alexander S. Kulikov Leonid L. Fershtat 《Molecules (Basel, Switzerland)》2022,27(8)
A series of novel 1,4-dihydrobenzo[1,2,4][e]triazines bearing an acetyl or ester moiety as a functional group at the C(3) atom of the 1,2,4-triazine ring were synthesized. The synthetic protocol is based on an oxidative cyclization of functionally substituted amidrazones in the presence of DBU and Pd/C. It was found that the developed approach is suitable for the preparation of 1,4-dihydrobenzo[e][1,2,4]triazines, but the corresponding Blatter radicals were isolated only in few cases. In addition, a previously unknown dihydrobenzo[e][1,2,4]triazolo[3,4-c][1,2,4]triazine tricyclic open-shell derivative was prepared. Studies of thermal behavior of the synthesized 1,4-dihydrobenzo[1,2,4][e]triazines revealed their high thermal stability (up to 240–250 °C), which enables their application potential as components of functional organic materials. 相似文献
103.
Hans Westman 《Annals of Physics》2009,324(8):1585-1611
We investigate the interplay and connections between symmetry properties of equations, the interpretation of coordinates, the construction of observables, and the existence of physical relativity principles in spacetime theories. Using the refined notion of an event as a “point-coincidence” between scalar fields that completely characterise a spacetime model, we also propose a natural generalisation of the relational local observables that does not require the existence of four everywhere invertible scalar fields. The collection of all point-coincidences forms in generic situations a four-dimensional manifold, which is naturally identified with the physical spacetime. 相似文献
104.
An indirect laser-induced method for selective removal of large copper areas from a printed circuit board is theoretically and experimentally investigated. The results show that the threshold condition for the process involves phase transition of the epoxy-based substrate resin. Optimal parameters for maximizing process speed are found and discussed. 相似文献
105.
《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(45):14183-14186
Yttrium aluminum borate (YAB) powders prepared by sol–gel process have been investigated to understand their photoluminescence (PL) mechanism. The amorphous YAB powders exhibit bright visible PL from blue emission for powders calcined at 450 °C to broad white PL for higher calcination temperature. Thanks to 13C labelling, NMR and EPR studies show that propionic acid initially used to solubilize the yttrium nitrate is decomposed into aromatic molecules confined within the inorganic matrix. DTA‐TG‐MS analyses show around 2 wt % of carbogenic species. The PL broadening corresponds to the apparition of a new band at 550 nm, associated with the formation of aromatic species. Furthermore, pulsed ENDOR spectroscopy combined with DFT calculations enables us to ascribe EPR spectra to free radicals derived from small (2 to 3 rings) polycyclic aromatic hydrocarbons (PAH). PAH molecules are thus at the origin of the PL as corroborated by slow afterglow decay and thermoluminescence experiments. 相似文献
106.
M. Sajid 《Numerical Methods for Partial Differential Equations》2010,26(1):221-228
This article investigates the analytic solution for the flow of a third grade fluid past an infinite porous plate. The method of parameter differentiation is used to linearized the governing flow equation. The solution of the obtained linear equation is developed by differential transform method in combination with the method of superposition. The obtained results are compared with existing results in the literature and an excellent agreement is found. This shows that the parameter differentiation is a powerful technique for solving nonlinear problems. © 2009 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq, 2010 相似文献
107.
Ronald G. Larson 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2012,124(11):2596-2598
108.
Feng Guo 《Physica A》2009,388(12):2315-2320
The stochastic resonance in a bias monostable system subject to frequency mixing force and multiplicative and additive noise is investigated. Based on the adiabatic elimination theory, the analytic expressions of the signal-to-noise ratio (SNR) for the fundamental and higher harmonics are obtained. It is shown that the SNR is a non-monotonic function of the intensities of the multiplicative and additive noise, as well as the system parameter. Moreover, the SNR for the fundamental harmonic decreases with the increase of the system bias, while the SNR for the higher harmonics behaves non-monotonically as the system bias varies. 相似文献
109.
V. Lepiller A. Goharzadeh A. Prigent I. Mutabazi 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,61(4):445-455
We have investigated the influence of a weak radial
temperature gradient in a wide gap and large aspect ratio
Couette-Taylor system. The inner cylinder is rotating and can be
heated or cooled, the outer cylinder is at rest and immersed in a
large thermal bath. We found that a radial temperature gradient
destabilizes the Couette flow leading to a pattern of traveling
helicoidal vortices occurring only near the bottom of the system.
The size of the pattern increases as the rotation frequency of the cylinder is increased. We
have characterized the spatiotemporal properties of the pattern and we have shown that it
behaves as a wall mode found in the simulation of the
complex Ginzburg-Landau equation with homogeneous boundary
conditions. 相似文献
110.
Y. Xiang S. J. Xiong F. Y. Hong 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2008,47(2):257-260
A bipartite quantum state (for two systems in any dimensions) can be
decomposed as a superposition of many components. For a
superposition of more than two components we prove that there is a
bound of the entanglement of the superposition state which can be
expressed according to entanglements of its component states.
Especially, if the component states are mutually bi-orthogonal, the
entanglement of the superposition state can be exactly given in
terms of the entanglements of the states being superposed. 相似文献