关于参数设计中调节因子的一个注记

参数设计是日本质量专家田口倡导的一种质量工程方法,调节因子的存在性在参数设计中非常重要.在附加了分布假定的条件下,本文对傅珏生等的定理给出了证明,也指出了从函数结构上研究参数设计的重要性.     

Synthesis of Hollow-flower-ball-like Cd4(OH)5Cl3 Using Microwave Irradiation Method

Novel mesoporous hollow‐flower‐ball‐like Cd₄Cl₃(OH)₅ was selectively synthesized using microwave‐irradiation process. The structure of the resultant Cd₄Cl₃(OH)₅ was characterized by scanning electron microscopy (SEM), X‐ray powder diffraction (XRD), high resolution transmission electron microscopy (HRTEM) and low temperature nitrogen sorption isotherms. The concentration of the reagents and the reaction time affect the formation of this hollow‐flower‐ball‐like structure of this complex. The formation of this interesting structure may be attributed to the self‐assembly of smaller inorganic building blocks during the crystallization process of Cd₄(OH)₅Cl₃ crystals. The photocatalytic activity of as‐prepared Cd₄(OH)₅Cl₃ was evaluated by the degradation of salicylic acid and 4‐chlorophenol in water under UV‐irradiation.     

One Pot Synthesis of Amphiphilic Hyperbranched Poly-(amino ester)and Its Dynamic Surface Activity

Amphiphilic hyperbranched poly(amino ester)s with hydrophilic multi‐ethoxylated triacrylate backbone and hydrophobic long alkyl side chain were firstly synthesized via one pot Michael addition polymerization. The poly‐(amino ester) could dissolve in cold water and self‐assemble into loose micelle. Under 50–1000 ms bubble, the dynamic surface tension (DST) of the poly(amino ester) aqueous solution (0.5 wt%) still maintained in the range of 32–28 mN/m. The aqueous solutions of poly(amino ester)s with different molecular weights showed the lower critical solution temperature (LCST) in the range of 8–50°C, which could also be tuned by its pH. Capped with hydrophobic groups on the terminal units and partially neutralized with acid, the poly(amino ester)s still kept their stable dynamic surfactant behaviors, indicating promising application.     

Whole-wafer fabrication process for three-terminal double stacked tunnel junctions

A new fabrication process for three-terminal superconducting devices consisting of two Josephson junctions in a stacked configuration is reported. The process is based on the deposition of the whole Nb/Al_xO_y/Nb-Al/Al_xO_y/Nb multilayer on a Si crystalline wafer without any vacuum breaking. Lift-off techniques, anodization processes and a SiO film deposition have been adopted for patterning and insulating the two tunnel stacked junctions. Devices have been characterized in terms of current-voltage (I-V) curves and Josephson critical current vs. the externally applied magnetic field. They show high quality factors (V _m values up to 65 mV at 4.2 K), and good current uniformity. Received 5 June 2001     

Chiral separations of metoprolol and some analogs with carbon dioxide on chiralcel OD and chiralpak AD stationary phases. Use of chemometrics

Summary The influence of methanol concentration, column temperature, and column back-pressure on the enantios-electivity of the separation of eighteen amino alcohols in supercritical-fluid chromatography has been investigated by use of statistical experimental design. The enantioselective retention of the amino alcohols was studied using Chiralcel OD and Chiralpak AD as the chiral stationary phases and the experimental responses obtained—retention factors (k) and selectivity factors (α)—were evaluated by use of the partial least squares algorithm. The performance of the columns was compared and the enantioselectivity of the Chiralcel OD column was found to be superior. Almost all the racemic amino alcohols tested were separated and separation factors as high as 4.5 were obtained by use of the Chiralcel OD column. Experimental results from a factorial design with three centerpoints resulted in a statistical model based on linear terms only. The first-eluted enantiomers, which, when identified, were found to be theR forms, had similar retention times, whereas the retention times of theS forms were more varied. The column temperature had a greater effect on enantioselectivity than methanol content. Changes in the system back-pressure had no significant influence on enantioselectivity. The results obtained from the factorial design were used to predictk and α. Differences between predicted and experimental data were less than 10%. The effect on enantioselectivity of protolytic mobile phase additives, e. g. dimethyloctylamine, acetic acid, and trifluoroacetic acid, and of mobile-phase flow-rate, were also studied, as was the effect of solute structure. The position of substituents on the aromatic ring, type of alkyl group attached to the nitrogen atom, and the number of methylene groups between the stereogenic center and the nitrogen atom all affected enantioselectivity. The chromatographic system developed could be used to determine enantiomeric purity even if the chiral impurity eluted after the main peak.     

强脉冲载荷作用下弹-塑性薄圆板的大挠度动力响应

利用有限变形弹塑性连续体的最小加速度原理 ,建立了分析圆板动力响应问题的数值方法 ,并通过对均匀分布的脉冲载荷作用下铰支圆板位移响应的细致分析 ,探讨了响应过程中的饱和冲量现象 ,指出对于高载范围内的脉冲载荷 ,相应于最大变形的饱和冲量确实是存在的。结果还表明 ,虽然圆板的弹塑性动力分析非常复杂 ,但基于最小加速度原理的数值计算方法却具有简单、直接的优点。     

Double-Network Heparin Dynamic Hydrogels: Dynagels as Anti-bacterial 3D Cell Culture Scaffolds

Double cross-linked dynamic hydrogels, dynagels, have been prepared through reversible imine bonds and supramolecular interactions, which showed good pH responsiveness, injectability, self-healing property and biocompatibility. With the further encapsulation of heparin, the obtained hydrogels exhibited good anti-bacterial activity and promotion effects for 3D cell culture.     

Noncooperative stochastic games under a n-stage local contraction assumption

We consider a class of noncooperative stochastic games with general state and action spaces and with a state dependent discount factor. The expected time duration between any two stages of the game is not bounded away from zero, so that the usual N-stage contraction assumption, uniform over all admissible strategies, does not hold. We propose milder sufficient regularity conditions, allowing strategies that give rise with probability one to any number of simultaneous stages. We give sufficient conditions for the existence of equilibrium and ∈-equilibrium stationary strategies in the sense of Nash. In the two-player zero-sum case, when an equilibrium strategy exists, the value of the game is the unique fixed point of a specific functional operator and can be computed by dynamic programming.     

Oxygen‐barrier properties of copolymers based on ethylene terephthalate

The oxygen‐barrier properties of amorphous polyethylene terephthalate‐based copolymers with various acid comonomers were examined. The incorporation of increasing amounts of isophthalate, phthalate, or naphthalate gradually reduced the permeability P toward the low values obtained for the corresponding homopolymers. The permeability of poly(ethylene 3,4′‐bibenzoate) homopolymer was only slightly lower than that of polyethylene terephthalate, and the copolymers correspondingly exhibited a very gradual decrease in P as the amount of 3,4′‐bibenzoate (3,4′BB) increased. In contrast, copolymerization with the linear isomer, 4,4′BB, produced a substantial increase in P. Generally, comonomer affected the solubility S less than the diffusivity D, and therefore changes in P reflected primarily changes in D for the polymers studied. The diffusivity and solubility depended on the copolymer composition in accordance with static and dynamic free‐volume concepts of gas permeability in glassy polymers. The solubility S correlated with the amount of free volume as determined by the glass‐transition temperature. Correlation of the diffusivity D with the magnitude of the subambient γ relaxation identified dynamic free volume with thermally activated conformational changes and segmental motions. Correspondence in the activation energy confirmed the relationship. © 2001 John Wiley & Sons, Inc. J Polym Sci Part B: Polym Phys 39: 1889–1899, 2001     

Nicotinic Acetylcholine Receptor Agonists: A Milestone for Modern Crop Protection

The destruction of crops by invertebrate pests is a major threat against a background of a continuously rising demand in food supply for a growing world population. Therefore, efficient crop protection measures in a vast range of agricultural settings are of utmost importance to guarantee sustainable yields. The discovery of synthetic agonists selectively addressing the nicotinic acetylcholine receptors (nAChRs), located in the central nervous system of insects, for use as insecticides was a major milestone in applied crop protection research. These compounds, as a result of their high target specificity and versatility in application methods, opened a new innovative era in the control of some of the world′s most devastating insect pests. These insecticides also contributed massively to extending our knowledge of the biochemistry of insect nicotinic acetylcholine receptors. The global economic success of synthetic nAChR agonists as insecticides renders the nicotinic acetylcholine receptor still one of the most attractive target sites for exploration in insecticide discovery.