Aqueous solution and solid state interactions of lanthanide ions with a methacrylic ester polymer bearing pendant 15‐crown‐5 moieties

The interaction between trivalent lanthanide ions and poly(1,4,7,10,13‐pentaoxacyclopentadecan‐2‐yl‐methyl methacrylate), PCR5, in aqueous solution and in the solid state have been studied. In aqueous solution, evidence of a weak interaction between the lanthanides and PCR5 comes from the small red shift of the Ce(III) emission spectra and the slight broadening of the Gd(III) EPR spectra. From the Tb(III) lifetimes in the presence of H₂O and D₂O the loss of one or two water coordinated molecules is confirmed when Tb(III) is bound to PCR5. An association constant of the order of 200 M^?1 was obtained for a 1:1 (lanthanide:15‐crown‐5) complex from the shift of the polymer NMR signals induced by Tb(III). A similar association constant is obtained from the differences of the molar conductivity of Ce(III) solution at various concentrations in presence and absence of PCR5. When Tb(III) is adsorbed on PCR5 membranes, lifetime experiments in H₂O and D₂O confirm the loss of 5 or 6 water coordinated molecules indicating that in solid state the lanthanide(III)‐PCR5 interaction is stronger than in solution. The adsorption of Ce(III) in PCR5 membranes shows a Langmuir type isotherm, from which an equilibrium constant of 39 M^?1 has been calculated. SEM shows that the membrane morphology is not much affected by lanthanide adsorption. Support for lanthanide ion–crown interactions comes from ab initio calculations on 15‐crown‐5/La(III) complex. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1788–1799, 2007     

屋顶绿化的自动灌溉系统设计

屋顶绿化对提高城市空气质量、减少“热岛效应”、改善居住环境有积极的意义，但其灌溉环节与普通园林绿化灌溉相比有更高的要求．为了增强屋顶灌溉的科学性，根据其特点提出了建立自动灌溉系统的设想，并对灌溉过程建立了混杂自动机模型，从离散事件动态系统与连续变量动态系统的角度共同描述了自动灌溉的过程，最后给出了自动灌溉系统的工程设计方案，对屋顶绿化自动化、精细化程度的提高具有一定的启示意义．     

Chemical reactivity of hypervalent silicon compounds: The local hard and soft acids and bases principle viewpoint

The silicon atom may increase its coordination number to values greater than four, to form pentacoordinated compounds. It has been observed experimentally that, in general, pentacoordinated compounds show greater reactivity than tetracoordinated compounds. In this work, density functional theory is used to calculate the global softness and the condensed softness of the silicon atom for SiH _n F_4−n and SiH _n F _5−n ¹⁻ . The values obtained show that the global and condensed softness are greater in the pentacoordinated compounds than in the tetracoordinated compounds, a result that explains the enhanced reactivity. If the results are analysed through a local version of the hard and soft acids and bases principle, it is possible to suggest that in nucleophilic substitution reactions, soft nucleophiles preferably react with SiH _n F _5−n ¹⁻ , and hard nucleophiles with SiH _n F_4−n .     

Neuro-fuzzy approach to processing inputs with missing values in pattern recognition problems

An approach to dealing with missing data, both during the design and normal operation of a neuro-fuzzy classifier is presented in this paper. Missing values are processed within a general fuzzy min–max neural network architecture utilising hyperbox fuzzy sets as input data cluster prototypes. An emphasis is put on ways of quantifying the uncertainty which missing data might have caused. This takes a form of classification procedure whose primary objective is the reduction of a number of viable alternatives rather than attempting to produce one winning class without supporting evidence. If required, the ways of selecting the most probable class among the viable alternatives found during the primary classification step, which are based on utilising the data frequency information, are also proposed. The reliability of the classification and the completeness of information is communicated by producing upper and lower classification membership values similar in essence to plausibility and belief measures to be found in the theory of evidence or possibility and necessity values to be found in the fuzzy sets theory. Similarities and differences between the proposed method and various fuzzy, neuro-fuzzy and probabilistic algorithms are also discussed. A number of simulation results for well-known data sets are provided in order to illustrate the properties and performance of the proposed approach.     

Expert systems as a tool for statistics: A review

The current state of using expert system (ES) techniques for statistics is expounded through the difficulties of defining the notion of statistical expert system (SES) and through several well-known examples. The main characteristics of statistical expertise, and particularly the important concept of strategy are emphasized. The current state of SESs is seen in the context of the global trend of the evolution of ES, i.e. within the growth of second generation expert system (SGESs). The knowledge base of these ESs represent an attempt to represent not only experts' knowledge but also the way experts acquire their expertise, thanks to the existence of an underlying model. We show through many examples how far SESs are and/or will be able to be SGESs.     

一类It型非线性时滞关联随机大系统的分散鲁棒控制

在非线性项满足全局Lipschitz条件下,本文研究了一类It型非线性时滞关联随机大系统的分散鲁棒控制问题.系统的时滞是关于状态和控制输入的.基于Lyapunov泛函及线性矩阵不等式(LMI)的分析方法,得到了无记忆状态反馈控制器使整个时滞关联随机大系统可镇定的充分条件.     

Dual Characterizations of Set Containments with Strict Convex Inequalities

Characterizations of the containment of a convex set either in an arbitrary convex set or in the complement of a finite union of convex sets (i.e., the set, described by reverse-convex inequalities) are given. These characterizations provide ways of verifying the containments either by comparing their corresponding dual cones or by checking the consistency of suitable associated systems. The convex sets considered in this paper are the solution sets of an arbitrary number of convex inequalities, which can be either weak or strict inequalities. Particular cases of dual characterizations of set containments have played key roles in solving large scale knowledge-based data classification problems where they are used to describe the containments as inequality constraints in optimization problems. The idea of evenly convex set (intersection of open half spaces), which was introduced by W. Fenchel in 1952, is used to derive the dual conditions, characterizing the set containments.     

Periodic solutions of second-order differential inclusions systems with p-Laplacian

Some existence results are obtained for periodic solutions of nonautonomous second-order differential inclusions systems with p-Laplacian.     

Electronic properties of model quantum-dot structures in zero and finite magnetic fields

We have computed electronic structures and total energies of circularly confined two-dimensional quantum dots and their lateral dimers in zero and finite uniform external magnetic fields using different theoretical schemes: the spin-density-functional theory (SDFT), the current-and-spin-density-functional theory (CSDFT), and the variational quantum Monte Carlo (VMC) method. The SDFT and CSDFT calculations employ a recently-developed, symmetry-unrestricted real-space algorithm allowing solutions which break the spin symmetry. Results obtained for a six-electron dot in the weak confinement limit and in zero magnetic field as well as in a moderate confinement and in finite magnetic fields enable us to draw conclusions about the reliability of the more approximative SDFT and CSDFT schemes in comparison with the VMC method. The same is true for results obtained for the two-electron quantum dot dimer as a function of inter-dot distance. The structure and role of the symmetry-breaking solutions appearing in the SDFT and CSDFT calculations for the above systems are discussed. Received 16 October 2001 and Received in final form 17 January 2002