全文获取类型
收费全文 | 19303篇 |
免费 | 3366篇 |
国内免费 | 2569篇 |
专业分类
化学 | 8021篇 |
晶体学 | 174篇 |
力学 | 1115篇 |
综合类 | 188篇 |
数学 | 5846篇 |
物理学 | 9894篇 |
出版年
2024年 | 39篇 |
2023年 | 190篇 |
2022年 | 422篇 |
2021年 | 430篇 |
2020年 | 564篇 |
2019年 | 515篇 |
2018年 | 534篇 |
2017年 | 532篇 |
2016年 | 582篇 |
2015年 | 667篇 |
2014年 | 905篇 |
2013年 | 1503篇 |
2012年 | 1074篇 |
2011年 | 1341篇 |
2010年 | 1165篇 |
2009年 | 1462篇 |
2008年 | 1514篇 |
2007年 | 1492篇 |
2006年 | 1307篇 |
2005年 | 1113篇 |
2004年 | 883篇 |
2003年 | 914篇 |
2002年 | 842篇 |
2001年 | 702篇 |
2000年 | 611篇 |
1999年 | 618篇 |
1998年 | 496篇 |
1997年 | 388篇 |
1996年 | 390篇 |
1995年 | 291篇 |
1994年 | 310篇 |
1993年 | 209篇 |
1992年 | 191篇 |
1991年 | 168篇 |
1990年 | 95篇 |
1989年 | 122篇 |
1988年 | 74篇 |
1987年 | 74篇 |
1986年 | 43篇 |
1985年 | 85篇 |
1984年 | 66篇 |
1983年 | 25篇 |
1982年 | 62篇 |
1981年 | 53篇 |
1980年 | 35篇 |
1979年 | 33篇 |
1978年 | 15篇 |
1977年 | 19篇 |
1976年 | 17篇 |
1973年 | 20篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
71.
采用固相反应合成了四羟基苯基卟啉与与Fe^2+,Co^2+金属离子的配合物,在室温下,将其与分子O2作用,提纯后得到两种固态氧合配合物.通过元素分析、红外光谱(IR)、核磁共振氢谱(^1HNMR)、电导、热分析(TG/DTA)、紫外光谱(UV)等测试手段确定了氧合配合物的组成为[Co·THPP·O2](NO3)2·2H2O、[Fe·THPP·O2]Cl2·2H2O],可知1mol配合物吸收了1molO2,采用失重法测定了氧合配合物中的配位氧,确定1mol金属配合物吸收1molO2形成超氧配合物. 相似文献
72.
For approximate wave functions, we prove the theorem that there is a one‐to‐one correspondence between the constraints of normalization and of the Fermi–Coulomb and Coulomb hole charge sum rules at each electron position. This correspondence is surprising in light of the fact that normalization depends on the probability of finding an electron at some position. In contrast, the Fermi–Coulomb hole sum rule depends on the probability of two electrons staying apart because of correlations due to the Pauli exclusion principle and Coulomb repulsion, while the Coulomb hole sum rule depends on Coulomb repulsion. We demonstrate the theorem for the ground state of the He atom by the use of two different approximate wave functions that are functionals rather than functions. The first of these wave function functionals is constructed to satisfy the constraint of normalization, and the second that of the Coulomb hole sum rule for each electron position. Each is then shown to satisfy the other corresponding sum rule. The significance of the theorem for the construction of approximate “exchange‐correlation” and “correlation” energy functionals of density functional theory is also discussed. © 2006 Wiley Periodicals, Inc. Int J Quantum Chem, 2007 相似文献
73.
Wilson A. Cañas-Marín Julián D. Ortiz-Arango Uriel E. Guerrero-Aconcha Claudia P. Soto-Tavera 《Fluid Phase Equilibria》2007
The ability of Soave–Redlich–Kwong cubic equation of state (SRK EoS) to predict densities and thermodynamic derivative properties such as thermal expansivity, isothermal compressibility, calorific capacity, and Joule–Thompson coefficients, for two gas condensates over a wide range of pressures (up to 110 MPa) was studied. The predictions of the EoS were compared to Monte Carlo simulation data obtained by Lagache et al. [M.H. Lagache, P. Ungerer, A. Boutin, Fluid Phase Equilibr. 220 (2004) 221]. Two completely different alpha functions for the SRK EoS attractive term were used and their respective effects on the predictions of such properties were analyzed. Also, two different forms of the crossed terms of the attractive parameter, aij, and three expressions of the crossed terms of the repulsive parameter, bij, were combined in different ways, and predictions were carried out. Little sensitivity of the properties on the chosen alpha function, except for the calorific capacities, was found in the systems studied. The most commonly used combination rules to model phase behavior of reservoir fluids, i.e. geometric and arithmetic forms of aij and bij, respectively, predicted very deficient results for these fluids at extreme conditions, specially for density calculations. 相似文献
74.
75.
相位差与q变形广义相干叠加态的压缩特性 总被引:1,自引:0,他引:1
对于q变形的非简谐振子广义相干态的叠加态β〉+eiφβeiδ〉,其量子涨落的可能高阶压缩阶数可以表示为k≠2πn/δ,这里n是整数.当δ=π时,压缩阶数不能是偶数即只能是奇数,这正是q变形非简谐振子广义奇偶相干态的结果.由此表明参数相位差δ对决定q变形的非简谐振子广义相干态叠加态的高阶压缩阶数起决定性作用. 相似文献
76.
提出一种利用 GHZ态实现多原子缠结态的量子隐形传态方案 .当作为量子通道的 GHZ态含有一个单模高 Q腔时 ,大大地简化了量子稳形传态中的联合测量过程 相似文献
77.
78.
Vijay Balasubramanian Donald Marolf Moshe Rozali 《General Relativity and Gravitation》2006,38(11):1529-1536
We argue that if black hole entropy arises from a finite number of underlying quantum states, then any particular such state
can be identified from infinity. The finite density of states implies a discrete energy spectrum, and, in general, such spectra
are non-degenerate except as determined by symmetries. Therefore, knowledge of the precise energy, and of other commuting
conserved charges, determines the quantum state. In a gravitating theory, all conserved charges including the energy are given
by boundary terms that can be measured at infinity. Thus, within any theory of quantum gravity, no information can be lost
in black holes with a finite number of states. However, identifying the state of a black hole from infinity requires measurements
with Planck scale precision. Hence observers with insufficient resolution will experience information loss.
First Award in the 2006 Essay Competition of the Gravity Research Foundation. 相似文献
79.
80.
Sung‐Fu Hsu Tzong‐Ming Wu Chien‐Shiun Liao 《Journal of Polymer Science.Polymer Physics》2006,44(23):3337-3347
Poly(3‐hydroxybutyrate) (PHB)/layered double hydroxides (LDHs) nanocomposites were prepared by mixing PHB and poly(ethylene glycol) phosphonates (PEOPAs)‐modified LDH (PMLDH) in chloroform solution. Both X‐ray diffraction data and TEM micrographs of PHB/PMLDH nanocomposites indicate that the PMLDHs are randomly dispersed and exfoliated into the PHB matrix. In this study, the effect of PMLDH on the isothermal crystallization behavior of PHB was investigated using a differential scanning calorimeter (DSC) and polarized optical microscopy. Isothermal crystallization results of PHB/PMLDH nanocomposites show that the addition of 2 wt % PMLDH into PHB induced more heterogeneous nucleation in the crystallization significantly increasing the crystallization rate and reducing their activation energy. By adding more PMLDH into the PHB probably causes more steric hindrance of the diffusion of PHB, reducing the transportation ability of polymer chains during crystallization, thus increasing the activation energy. The correlation among crystallization kinetics, melting behavior and crystalline structure of PHB/PMLDH nanocomposites can also be discussed. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3337–3347, 2006 相似文献