首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   74862篇
  免费   6145篇
  国内免费   7079篇
化学   27642篇
晶体学   313篇
力学   7181篇
综合类   1355篇
数学   26871篇
物理学   24724篇
  2023年   641篇
  2022年   1317篇
  2021年   1440篇
  2020年   1485篇
  2019年   1793篇
  2018年   1470篇
  2017年   1761篇
  2016年   2005篇
  2015年   1865篇
  2014年   2692篇
  2013年   4877篇
  2012年   2975篇
  2011年   3422篇
  2010年   2953篇
  2009年   4052篇
  2008年   4520篇
  2007年   4744篇
  2006年   4402篇
  2005年   3793篇
  2004年   3420篇
  2003年   3498篇
  2002年   3265篇
  2001年   2765篇
  2000年   2698篇
  1999年   2417篇
  1998年   2237篇
  1997年   1820篇
  1996年   1613篇
  1995年   1442篇
  1994年   1319篇
  1993年   1150篇
  1992年   1108篇
  1991年   857篇
  1990年   715篇
  1989年   610篇
  1988年   564篇
  1987年   434篇
  1986年   375篇
  1985年   445篇
  1984年   431篇
  1983年   215篇
  1982年   357篇
  1981年   409篇
  1980年   307篇
  1979年   295篇
  1978年   223篇
  1977年   206篇
  1976年   155篇
  1974年   111篇
  1973年   106篇
排序方式: 共有10000条查询结果,搜索用时 21 毫秒
61.
In the set of graphs of order n and chromatic number k the following partial order relation is defined. One says that a graph G is less than a graph H if ci(G) ≤ ci(H) holds for every i, kin and at least one inequality is strict, where ci(G) denotes the number of i‐color partitions of G. In this paper the first ? n/2 ? levels of the diagram of the partially ordered set of connected 3‐chromatic graphs of order n are described. © 2003 Wiley Periodicals, Inc. J Graph Theory 43: 210–222, 2003  相似文献   
62.
Finite element analysis of fluid flow with moving free surface has been performed in 2‐D and 3‐D. The new VOF‐based numerical algorithm that has been proposed by the present authors (Int. J. Numer. Meth. Fluids, submitted) was applied to several 2‐D and 3‐D free surface flow problems. The proposed free surface tracking scheme is based on two numerical tools; the orientation vector to represent the free surface orientation in each cell and the baby‐cell to determine the fluid volume flux at each cell boundary. The proposed numerical algorithm has been applied to 2‐D and 3‐D cavity filling and sloshing problems in order to demonstrate the versatility and effectiveness of the scheme. The proposed numerical algorithm resolved successfully the free surfaces interacting with each other. The simulated results demonstrated applicability of the proposed numerical algorithm to the practical problems of large free surface motion. It has been also demonstrated that the proposed free surface tracking scheme can be easily implemented in any irregular non‐uniform grid systems and can be extended to 3‐D free surface flow problems without additional efforts. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
63.
The reticulation process of an epoxy resin using an amine as a cure agent was studied at different temperatures and concentrations of the cure agent with dynamic mechanical thermal analysis. The study was performed under both isothermal and nonisothermal conditions, and a temperature–time–transformation diagram was obtained. The measurements from the two modes gave similar results, although the nonisothermal mode required fewer experiments. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1965–1977, 2003  相似文献   
64.
A statistical theory of light scattering from deformed isotropic and textured heterogeneous polymer materials is formulated. Two types of textured structures are analyzed: assemblies of optically isotropic and anisotropic rods and a spatially anisotropic distribution of isotropic spherical inclusion centers. The small-angle Hv light-scattering patterns are calculated. The appearance of scattering from isotropic rods and spheres in deformed materials has been demonstrated. The changes of the Hv scattering patterns as a function of elongation and strucuture parameters are discussed. © 1993 John Wiley & Sons, Inc.  相似文献   
65.
Fibers were spun from isotropic and anisotropic dimethylacetamide solutions of cellulose esters. Take-up speeds of the dry jet/wet spinning process varied. Water served as the coagulant. The mechanical properties of the fibers increased as spinning progressed from the isotropic to the anisotropic state of the solution. A trade-off in solubility and fiber properties was noted as the butyryl acetyl ratio decreased. Whereas high butyryl content enhances both overall solubility and the formation of liquid–crystalline solutions at lower concentration, it results in lower fiber modulus and strength. Morphology of the fibers depended on the coagulation rate which was influenced by the concentration of the sppinning solution. The level of orientation and crystallinity of the fibers increased somewhat when they were spun from liquid-crystalline solutions. © 1993 John Wiley & Sons, Inc.  相似文献   
66.
We investigated the structures induced by an irradiation of a near‐infrared (NIR) femtosecond laser pulse in dye‐doped polymeric materials {poly(methyl methacrylate) (PMMA), thermoplastic epoxy resin (Epoxy), and a block copolymer of methyl methacrylate and ethyl acrylate‐butyl acrylate [p(MMA/EA‐BA) block copolymer]}. Dyes used were classified into two types—type 1 with absorption at 400 nm and type 2 with no absorption at 400 nm. The 400‐nm wavelength corresponds to the two‐photon absorption region by the irradiated NIR laser pulse at 800 nm. Type 1 dye‐doped PMMA and p(MMA/EA‐BA) block copolymer showed a peculiar dye additive effect for the structures induced by the line irradiation of a NIR femtosecond laser pulse. On the contrary, dye‐doped Epoxy did not exhibit a dye additive effect. The different results among PMMA, p(MMA/EA‐BA) block copolymer, and Epoxy matrix polymers are supposed to be related to the difference of electron‐acceptor properties. The mechanism of this type 1 dye‐additive‐effect phenomenon for PMMA and p(MMA/EA‐BA) block copolymer is discussed on the basis of two‐photon absorption of type 1 dye at 400 nm by the irradiation of a femtosecond laser pulse with 800 nm wavelength and the dissipation of the absorbed energy to the polymer matrix among various transition processes. Dyes with a low‐fluorescence quantum yield favored the formation of thicker grating structures. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 2800–2806, 2002  相似文献   
67.
本文探讨了随机删失场合半参数回归模型的参数估计问题.考虑半参数回归模型Y =X}}3 + g(T)十。,其中(X,T)’为取值于Kp X [0,1〕上的随机向量,月为1'维未知参数向量,8为定义于【0.1]上的未知函数,。为随机误差,Ee = 0 . Eez = az }。未知,且(X ,T)与。独立,).被一个与之独立的随机变量V所截.此时仅能观察到:Z=min(Y,V),o=1(Y簇V),参数I3,az的估计量禽及公 z可综合非参数的权函数估计法与参数的最小二乘估计方法得到.本文对核函数的情形得到了念及ar z的精确收敛速度即重对数律.  相似文献   
68.
Conductive composite films of poly(styrene‐con‐butylacrylate) copolymers filled with low‐density, Ni‐plated core‐shell polymeric particles were prepared and their behaviors of positive temperature coefficient of resistance (PTCR) were investigated. When the conductive fillers in the composite film were loaded beyond the critical volume, 10 up to 25 vol %, composite films exhibited a unique electrical resistant transition behavior, which the electrical resistance rapidly increased by several orders of magnitude at the critical temperature. The PTCR transition temperature, in general, occurred before the glass transition temperature of polymer matrix. Further increased the conductive filler loading to 30 vol %, the overpacked conduction paths were formed in the entire composite and the PTCR effects became blurred. While the composite film treated with thermal cycle several times from room temperature up to 120 °C, the electrical resistivity increased accompanied with the shift of the PTCR transition to lower temperature. The reason might have been caused by the formed interfacial cracks within the composite film. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 322–329, 2007  相似文献   
69.
利用精炼的C语言进行程序设计,定量模拟狭义相结论的运动时钟变慢,并对处于两种不同时空观的时钟运行进行对比,使得时间膨胀效应变得直观。  相似文献   
70.
    
The solvent extraction of cobalt(II), nickel(II) and copper(II) using 2,4-pent-dione (Hacac) and 4-phenyl-2, 4-but-dione (Hbzac) is carried out by varying the reagent concentration and pH of the aqueous phase. Each of these metals is quantitatively separated (≈ 98%) from their binary mixtures with monovalent (Ag), divalent (Mn, Zn, Cd, Hg, Mg, Sn, Pb) and trivalent (Cr, Fe) metals. The extraction constants are calculated from the metal distribution data using linear regression analysis. The extracted species is MA2 in each case. A most significant result is separation of copper(II) from iron(III) which otherwise interferes when extracted from the acidic medium.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号