SiH3+O(3P)反应机理的理论研究

利用abinitio方法对SiH3+O(3P)反应进行了理论研究,在MP2/6-311+G(d,p)水平上优化得到了反应途径上的反应物、中间体、过渡态和产物的几何构型,并在QCISD(T)/6-311+G(d,p)水平上进行单点能计算.计算结果表明,SiH3+O(3P)→IM1→TS3→IM2→TS8→HOSi+H2为主反应通道,其他可能存在的次要产物有HSiOH+H、H2SiO+H和HSiO+H2.HOSi、HSiO和HSiOH(cis)还可能进一步解离生成SiO.另外,计算结果对SiH4+O(3P)反应机理中存在的争议给出了可能的解释,认为Withnall等人在实验中观察到的产物HSiOH、H2SiO和SiO并不是SiH4+O(3P)反应的直接产物,而是来自副反应SiH3+O(3P).     

N巴黎势和可能的p共振态(英文)

通过求解N巴黎光学势的复薛定谔方程,研究了N系统的近阈束缚和共振行为,得到了一个p系统的13P0共振态.发现其能量和宽度与最近BES用Breit Wigner(B W)公式分析J/ψ→γp衰变的实验数据给出的结果相容.讨论了这一结果的含义及进一步研究的建议.     

Evolution analysis of the states of the EZ model

Based on suitable choice of states, this paper studies the stability of the equilibrium state of the EZ model by regarding the evolution of the EZ model as a Markov chain and by showing that the Markov chain is ergodic. The Markov analysis is applied to the EZ model with small number of agents, the exact equilibrium state for N = 5 and numerical results for N=18 are obtained.     

Quasiprobability distributions of a new kind of even and odd nonlinear coherent states

Using a numerical computational method, quasiprobability distributions of new kinds of even and odd nonlinear coherent states (EONLCS) are investigated. The results show that the distributions of the new even nonlinear coherent states (NLCS) are distinct from those of the new odd NLCS and imply that the new EONLCS always exhibit some different nonclassical effects. Finally, with the aid of newly introduced intermediate coordinate-momentum representation in quantum optics, the tomograms of the new EONLCS are calculated. This is a new way of obtaining the tomogram function.     

Correspondence between quantum-optical transform and classical-optical transform explored by developing Dirac’s symbolic method

By virtue of the new technique of performing integration over Dirac’s ket–bra operators, we explore quantum optical version of classical optical transformations such as optical Fresnel transform, Hankel transform, fractional Fourier transform, Wigner transform, wavelet transform and Fresnel–Hadmard combinatorial transform etc. In this way one may gain benefit for developing classical optics theory from the research in quantum optics, or vice-versa. We cannot only find some new quantum mechanical unitary operators which correspond to the known optical transformations, deriving a new theorem for calculating quantum tomogram of density operators, but also can reveal some new classical optical transformations. For examples, we find the generalized Fresnel operator (GFO) to correspond to the generalized Fresnel transform (GFT) in classical optics. We derive GFO’s normal product form and its canonical coherent state representation and find that GFO is the loyal representation of symplectic group multiplication rule. We show that GFT is just the transformation matrix element of GFO in the coordinate representation such that two successive GFTs is still a GFT. The ABCD rule of the Gaussian beam propagation is directly demonstrated in the context of quantum optics. Especially, the introduction of quantum mechanical entangled state representations opens up a new area in finding new classical optical transformations. The complex wavelet transform and the condition of mother wavelet are studied in the context of quantum optics too. Throughout our discussions, the coherent state, the entangled state representation of the two-mode squeezing operators and the technique of integration within an ordered product (IWOP) of operators are fully used. All these have confirmed Dirac’s assertion: “...for a quantum dynamic system that has a classical analogue, unitary transformation in the quantum theory is the analogue of contact transformation in the classical theory”.     

Comparative study of heterogeneous magnetic state above TC in La0.82Sr0.18CoO3 cobaltite and La0.83Sr0.17MnO3 manganite

The magnetic, transport and structural properties are studied for La_0.83Sr_0.17MnO₃ and La_0.82Sr_0.18CoO₃ single crystals with nearly the same doping and the metallic ground state. Their comparisons have shown that ferromagnetic clusters originate in the paramagnetic matrix below Т^?>T_C in both samples and exhibit similar properties. This suggests the possible universality of such phenomena in doped mixed-valence oxides of transition metals with the perovskite-type structure. The cluster density increases on cooling and plays an important role on the physical properties of these systems. The differences in cluster evolutions and scenarios of their insulator–metal transitions are related to different magnetic behaviors of the matrixes in these crystals that is mainly due to distinct spin states of the Mn³⁺ and Co³⁺ ions.     

The master equation for a two-level atom in a laser field with squeezing-like terms

In this paper, we derive the time dependent solution of the effective master equation for the reduced density matrix operator of a two-level atom driven by a strong classical field and damped into a “modelled” reservoir with non-flat density of modes. The effects of different parameters on the atomic inversion, the von Neumann entropy and the entropy squeezing are discussed.     

含负折射率材料并具有零平均折射率的半无限一维光子晶体的表面态

用传输矩阵方法和Bloch定理,从理论上分析以色散介质为背景,由正负折射率材料组成的半无限一维光子晶体的表面态,发现以色散介质为背景,在满足平均折射率等于零的情况下,第一层厚度变化时,表面态将会在较大频率范围内显著变化。讨论了同一入射角度下不同频率的表面态的电场分布情况,结果表明：远离带边的表面态局域长度较小。     

Towards the decays of Nx（1625） the molecular picture

In this talk, we firstly overview the experimental status of Nx（1625）, which is an enhancement structure observed in K-3. invariant mass spectrum of J/ψ → pK-∧. process. Then we present the result of the decay of Nx（1625） under the two molecular assumptions, i.e. S-wave∧K- and S-wave ∑0K- molecular states. Several experimental suggestions for Nx （1625） are proposed.     

连续纠缠态表象的几种Schmidt分解、物理意义与应用

在两粒子连续纠缠态表象|η〉的基础上分别导出了此纠缠态在坐标、动量表象和粒子数表象中的Schmidt分解,阐述了其物理意义.并且,用|η〉的Schmidt分解直接给出单模压缩算符对纠缠态的作用结果、双模平移算符的纠缠态表象以及平移算符在Fock空间的矩阵元.文章的讨论可以推广到多粒子连续纠缠态情形.