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111.
采用油酸盐法分别制备出均匀的上转换发光裸核纳米粒子及其包覆具有不同Yb3+浓度掺杂的NaYF4:Yb3+,Er3+核壳纳米结构的上转换纳米粒子。在不同温度下(90~450 K),研究分析了在壳中掺杂不同浓度Yb3+的NaYF4:Yb3+,Er3+@NaYF4:x%Yb3+核壳纳米体系的上转换发光特性。结果表明:在NaYF4:Yb3+,Er3+上转换体系中,惰性壳中的525 nm(2H11/2 →4I15/2)发射峰呈现出与活性壳中不一样的趋势。壳层中掺杂的Yb3+通过声子对纳米粒子内部发光与表面及外界之间的相互作用起到了重要的"桥"连作用。 相似文献
112.
离心泵叶轮参数对进口回流的影响 总被引:3,自引:0,他引:3
本文对不同叶片进口角、叶片数、不同叶顶间隙的开式和闭式离心叶轮共12种叶轮的进口流场和回流发生情况进行了探针的动态测试和可视化观察.弄清了上述叶轮参数对进口回流初始流量和进口流场的影响. 相似文献
113.
注入控制铜蒸气激光方向性时间过程测量 总被引:1,自引:0,他引:1
实验研究了注入控制对铜蒸气激光非稳腔输出光束质量的影响,从输出光发散角时间分辨过程的测量结果说明注入加速被注入腔内激光发散角的减小过程。由于被注入腔内放大自发辐射的存在,为得到较好的注入控制效果,注入光的脉宽和进入被注入腔的延时必须恰当。 相似文献
114.
同步辐射光源的尺寸、散射角和中心亮度计算 总被引:1,自引:0,他引:1
同步辐射光源的尺寸、散角和中心亮度是装置的重要参数。着重讨论了同步光源的尺寸、散角和中心亮度的计算方法, 并给出了合肥同步辐射光源的结果。 相似文献
115.
I.V. Chikina N. Limodin A. Langlois M. Brazovskaia C. Even P. Pieranski 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,3(2):189-196
We investigate monolayers of 2-alcohols (2-C9 to 2-C16) obtained by placing a drop of pure alcohol at the water surface. These
alcohols are chiral molecules and we study the racemic mixtures. By ellipsometry and surface tension measurements we are able
to characterize the 2D crystallization-melting transition with temperature. We find a first order transition. Using X-ray
under grazing incidence we show that the racemic mixture crystallizes at 2D on a hexagonal cell. We find a parity effect on
the lateral pressure at the transition and on the stability of the Bragg peak. We compare all results with those observed
for 1-alcohols.
Received: 11 April 1997 / Revised: 18 August 1997 / Accepted: 9 October 1997 相似文献
116.
Christof Külske 《Journal of statistical physics》1998,91(1-2):155-176
We continue to investigate the size dependence of disordered mean-field models with finite local spin space in more detail, illustrating the concept of superstates as recently proposed by Bovier and Gayrard. We discuss various notions of convergence for the behavior of the paths (t[tN]())
t(0, 1] in the thermodynamic limit N. Here
n
() is the Gibbs measure in the finite volume {1,..., n} and is the disorder variable. In particular we prove refined convergence statements in our concrete examples, the Hopfield model with finitely many patterns (having continuous paths) and the Curie–Weiss random-field Ising model (having singular paths). 相似文献
117.
S. Villain-Guillot D. Andelman 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,4(1):95-101
We study interfacial behavior of a lamellar (stripe) phase coexisting with a disordered phase. Systematic analytical expansions
are obtained for the interfacial profile in the vicinity of a tricritical point. They are characterized by a wide interfacial
region involving a large number of lamellae. Our analytical results apply to systems with one dimensional symmetry in true
thermodynamical equilibrium and are of relevance to metastable interfaces between lamellar and disordered phases in two and
three dimensions. In addition, good agreement is found with numerical minimization schemes of the full free energy functional
having the same one dimensional symmetry. The interfacial energy for the lamellar to disordered transition is obtained in
accord with mean field scaling laws of tricritical points.
Received: 28 March 1997 / Revised: 6 February 1998 / Accepted: 16 February 1998 相似文献
118.
在柱状边界条件下将对柱侧面的曲面积分表示成一维积分,同时还给出了椭圆积分的计算方法,由对空间立体角积分的算例可知,其计算的速度有了显着的提高。 相似文献
119.
Yoshitaka Ishii Koichi Hirao Takehiko Terao Tsutomu Terauchi Makoto Oba Kozaburo Nishiyama Masatsune Kainosho 《Solid state nuclear magnetic resonance》1998,11(3-4):169-175
A solid state NMR method is presented for determination of a backbone dihedral angle φ in peptides, being based on the previously reported method, relayed anisotropy correlation (RACO) NMR [Y. Ishii et al., Chem. Phys. Lett. 256 (1996) 133]. In the present method, the
and the
dipolar tensors in the
system are two-dimensionally (2D) correlated via polarization transfer from
to
under magic angle spinning (MAS). This method was applied to N-acetyl
,
-valine, and the H–C–N–H dihedral angle was determined to be 154.0±1.4° or 206.0±1.4°, the former agreeing with the X-ray value of 154±5°. 相似文献
120.
The neutron response of electrochemically etched (ECE) CR-39 detectors is determined by the energy and angular dependence of the response to neutron-induced charged particles. This response has been measured for the example of protons with various initial energies and angles of incidence. Besides, some studies were made for modeling the mechanism of ECE of the proton trajectories with the aim of deriving the critical angle of incidence. 相似文献