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排序方式: 共有589条查询结果,搜索用时 62 毫秒
31.
Dr. Pablo Trigo‐Mouriño Dr. M. Carmen de la Fuente Dr. Roberto R. Gil Dr. Víctor M. Sánchez‐Pedregal Dr. Armando Navarro‐Vázquez 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(44):14989-14997
The conformational state of 8‐chloro‐1‐methyl‐2,3,4,5‐tetrahydro‐1H‐3‐benzazepine hydrochloride (lorcaserin) in water has been determined on the basis of one‐bond and long‐range C? H residual dipolar coupling (RDC) data along with DFT computations and 3JHH coupling‐constant analysis. According to this analysis, lorcaserin exists as a conformational equilibrium of two crown‐chair forms, of which the preferred conformation has the methyl group in an equatorial orientation. 相似文献
32.
Xanthine derivatives, caffeine (L1), theobromine (L2), theophylline (L3), 7-(β-hydroxyethyltheophylline) (L4), (7-(2,3-dihydroxypropyl)theophylline) (L5), and theophylline 7-acetic acid (L6) and the acetylated derivatives of the later three (L7–L9) were employed as ligands for the in situ palladium catalyzed Suzuki–Miyaura cross couplings of a series of halogenated pyridines. Optimized conditions were found where the diacetylated ligand (L8) was determined to be the best for this process, producing good to excellent yields in the couplings of halogenated anilines with phenylboronic acid under mild reaction conditions in water using microwave irradiation. 相似文献
33.
《Arabian Journal of Chemistry》2022,15(7):103922
Recently, the visible-light photoredox decarboxylative couplings of N-(acyloxy)phthalimides (NHPI esters) and its derivatives have become an efficient chemical transformation. Under visible light, the NHPI esters undergo a single-electron transfer (SET) process to afford the corresponding carbon or nitrogen radicals that participate in many chemical transformations. The photoredox decarboxylative couplings have been applied to achieve construction of an array of carbon–carbon and carbon–heteroatom bonds as well as the synthesis of carbocycles and heterocycles. This review categorises photocatalysts, discusses the application and catalysis mechanisms of NHPI esters, and details recent progress in this field. 相似文献
34.
《Comptes Rendus Physique》2015,16(10):986-993
Deciphering the mechanisms at play in the formation and evolution of the large-scale structure of the universe is part of the scientific goals of many projects of observational cosmology. In particular, large-scale structure observations can be used to infer mode-coupling effects, whether they come from the physics of the early universe or from its late time evolution. Specificities of such couplings are presented, noting that in principle they can be directly detected through bispectra of the cosmic microwave background temperature anisotropies or density in the local universe. The existence of such couplings have however more far-reaching consequences for the growth of the structure. Those are sketched as well as their possible observational impacts. 相似文献
35.
Metal‐Catalyzed Reductive Coupling Reactions of Organic Halides with Carbonyl‐Type Compounds
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Dr. Toni Moragas Dr. Arkaitz Correa Prof. Dr. Ruben Martin 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(27):8242-8258
Metal‐catalyzed reductive coupling reactions of aryl halides and (pseudo)halides with carbonyl‐type compounds have undergone an impressive development within the last years. These methodologies have shown to be a powerful alternate strategy, practicality aside, to the use of stoichiometric, well‐defined, and, in some cases, air‐sensitive organometallic species. In this Minireview, the recent findings in this field are summarized, with particular emphasis on the mechanistic interpretation of the results and future aspects of this area of expertise. 相似文献
36.
第一过渡系中的顺磁性离子CrⅢ、MnⅡ/MnⅢ、FeⅡ/FeⅢ、CoⅡ、NiⅡ和CuⅡ及抗磁性离子CoⅢ和ZnⅡ均可与DyⅢ在多齿螯合配体配位下形成单分子磁体配合物。在本文中,我们阐述或汇总了几乎所有的第一过渡系金属-镝单分子磁体。对于由顺磁性第一过渡金属离子和DyⅢ离子形成的配合物,有2个有趣的现象需要引起人们的注意:一是一些Cr-Dy配合物具有较高的阻塞温度和较大的矫顽场,这可归功于配合物内CrⅢ离子和DyⅢ离子之间较强的磁耦合作用(|J|>10 cm-1)。二是报道的FeⅡ2-Dy配合物的能垒可达到319 cm-1(459 K),这在第一过渡系金属-镝单分子磁体中也是比较高的。这可能与FeⅡ2-Dy中DyⅢ具有较高的轴向对称性(D5h)有关,且从头计算表明该配合物中Dy的第一激发态也具有较高的轴向对称性。除了部分Cr-Dy和FeⅡ-Dy配合物外,其他顺磁性第一过渡金属-Dy的能垒较低,这可能由配合物内顺磁离子间弱的磁耦合造成的。为了消除磁耦合对磁弛豫行为影响,近年来人们关注于使用抗磁性第一过渡金属离子与DyⅢ构建单分子磁体配合物。相比其他核数的Zn-Dy配合物,三核Zn2Dy配合物被报道的数目最多且研究得最为深入,这可能与较易调控Zn2Dy中Dy配位几何对称性有关。最后,我们提出了几点关于进一步提升第一过渡系金属-镝单分子磁体的磁性能的建议,其中最为重要的是控制Dy配位几何的轴向对称性及Dy的基态mJ的电荷分布。对于第一过渡系金属-镝单分子磁体中的DyⅢ离子,DyⅢ基态mJ的电荷与配体的电荷之间的静电排斥应该降到最低。 相似文献
37.
Based on fractional isospectral problems and general bilinear forms, the gener-alized fractional trace identity is presented. Then, a new explicit Lie algebra is introduced for which the new fractional integrable couplings of a fractional soliton hierarchy are derived from a fractional zero-curvature equation. Finally, we obtain the fractional Hamiltonian structures of the fractional integrable couplings of the soliton hierarchy. 相似文献
38.
研究了具有非局部时滞的扩散Nicholson苍蝇方程,其中时滞由一个定义在所有过去时间和整个一维空间区域上的积分卷积表示.当时滞核是强生成核时,根据线性链式技巧和几何奇异扰动理论,获得了小时滞时波前解的存在性. 相似文献
39.
40.
A. H.M. Zaheri S. Srivastava K. Tankeshwar 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,61(4):465-473
Expressions for zeroth, second and fourth sum rules of longitudinal and bulk
stress auto correlation functions have been derived for binary fluid mixtures.
Longitudinal and bulk viscosities of an Ar–Kr mixture have been calculated using
Mori's memory function formalism coupled with the sum rules of longitudinal and
bulk stress auto correlation functions.
The results obtained are compared with the molecular dynamics
simulation. Mass dependence of the longitudinal and bulk viscosities has
been studied for different compositions
of an isotopic mixture at different densities and temperatures. For very large mass ratio, the
longitudinal and bulk viscosities of the isotopic mixture are more dependent on mole fraction than on mass. 相似文献