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91.
Mihai V. Putz 《International journal of quantum chemistry》2006,106(2):361-389
A unified Mulliken valence with Parr ground‐state electronegativity picture is presented. It provides a useful analytical tool on which the absolute hardness as well ionization potential and electron affinity functionals are based. For all these chemical reactivity indices, systematic approximate density functionals are formulated within density functional softness theory and are applied to atomic systems. For the absolute hardness, a special relationship with the new electronegativity ansatz and a particular atomic trend paralleling the absolute electron affinity are established that should complement and augment the earlier finite‐difference energetic approach. © 2005 Wiley Periodicals, Inc. Int J Quantum Chem, 2006 相似文献
92.
J.E. Lorenzo H. Requardt 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,28(2):185-186
Eur. Phys. J. B 24, 315 (2001) Here we comment on a recently published paper on the presence of a phason contribution in the low temperature heat capacity data of the charge-density-wave compounds K0.3MoO3 and (TaSe4)2I. We have shown that the anomaly in the C
P
/
T
3
data reported by Odin et al. is straightforwardly interpreted in terms of low energy phonon modes resulting from the peculiar topology of these compounds.
Received 21 February 2002 Published online 19 July 2002 相似文献
93.
提出一种波长检测技术实现温度测量的方法,利用FBG传感器对温度等物理量实施监测,具有测试精度高,应用场合不受限制等特点,当环境参数发生变化时,光纤光栅的有效折射率和光栅周期会受到影响,将引起光纤光栅峰值波长的偏移,依据反射光谱结构的变化,可知道其温度的变化趋势。实验测试结果表明,在温度变化0.1°,波长变化1pm,温度和波长具有良好的线性关系。 相似文献
95.
In this paper, the structure of cubic CaTiO3 (001) surfaces with CaO and TiO2 terminations has been studied from density functional calculations. It has been found that the Ca atom has the largest relaxation for both kinds of terminations, and the rumpling of the CaO-terminated surface is much larger than that of TiO2-terminated surface. Also we have found that the metal atom relaxes much more prominently than the O atom does in each layer. The CaO-terminated surface is slightly more energetically favourahle than the TiO2-terminated surface from the analysis of the calculated surface energy. 相似文献
96.
利用电磁理论对表面传导电子发射显示器件的单个子像素在笛卡尔坐标系内建立合理的电学物理模型,对内部电场强度和电势进行了深入研究,推导出了模型不同部分的面电荷密度、电场强度和电势的表达式.为了形象地表征其电学特性,利用MATLAB 6.5对电场强度和电势的分布情况进行了模拟,从理论上对模拟曲面给出了合理的解释,分析了子像素内部电子的发射机理和电学行为,并与电子多重散射模型和惯性离心模型进行了对比,解释了SED阳极电流形成的重要原因.在误差允许的范围内,本模型有关电场强度分布的结论与惯性离心模型一致.
关键词:
表面传导电子发射显示
遂穿效应
面电荷密度
电场强度 相似文献
97.
Flat-top interleavers with chromatic dispersion compensator based on phase dispersive free space Mach-Zehnder interferometer 总被引:2,自引:0,他引:2
In this paper, novel interleavers using circular cavities (CC) in a Mach-Zehnder interferometer (MZI) has been presented and demonstrated for the first time, in which CCs act as phase dispersive mirrors which exhibit a periodic dependence on the frequency of light. Three implementation schemes have been proposed and investigated. Theoretical analysis shows the spectral characteristics of each scheme in a 50-GHz channel spacing application. Furthermore, the chromatic dispersion (CD) of each output comb can be flattened within passband by appending an additional CC. The result shows that the proposed designs with novel interferometer technique can simultaneously provide flat top passbands, high isolation stopband and low CD value as well. 相似文献
98.
Rb(5PJ)+Rb(5PJ)→Rb(5JS)+Rb(nl=5D,7S)碰撞能量合并 总被引:1,自引:1,他引:0
研究了Rb(5PJ)+Rb(5PJ)→Rb(nlJ')+Rb(5S)碰撞能量合并过程,利用单模半导体激光器分别共振激发Rb原子的5P1/2或5P3/2态,利用另一与泵浦激光束反向平行的单模激光束作为吸收线探测激发态原子密度及其空间分布,吸收线分别调至5P1/2→5D3/2和5P3/2→7S1/2跃迁.由激发态原子密度和谱线荧光比得到碰撞能量合并过程的截面,对5P3/2激发,碰撞转移得到5D5/2,5D3/2和7S1/2的截面分别是(1.32士0.59)×10-14,(1.18士0.53)×10-14和(3.21士1.44)×10-15cm2;对5P1/2激发,碰撞转移到5D5/2和5D3/2的截面分别是(6.57士2.96)×10-15和(5.90士2.66)×10-15cm2.与其他的实验结果进行了比较. 相似文献
99.
100.
Despite its capability of high spatial resolution, simulation of turbulent flows with traditional Lagrangian (front tracking) scheme is often discouraged by numerical instability caused by clustering of marker nodes and topological changes of fronts. Contour advection surgery (CAS), being a robust front tracking scheme, can limit the growth of front complexity during simulation without jeopardizing accuracy or efficiency. This allows it to open up an advantage over traditional front-tracking schemes. It has already been demonstrated that CAS, with incorporation of the reaction sheet model, can accurately simulate the propagation and advection of a turbulent premixed V-shaped flame. In this study, it is further tested with 10 values of vortex circulation. A range of upstream turbulence levels of 1.8–19.8% was obtained. Results indicate that upstream turbulence increase the average flame length, flame zone area and the overall burning rate. Flame surface density Σ was also estimated. Maximum values of Σ obtained lie in the range 0.1–1.4 mm−1. Skewness towards the burnt region was observed in all profiles of Σ. Similar to results from laboratory experiments, it was found that Σ values decreases with upstream turbulence. From this study, the ability of CAS to cope with intense turbulence is demonstrated and a better quantitative understanding on the scheme has also been acquired. 相似文献