全文获取类型
收费全文 | 38430篇 |
免费 | 5122篇 |
国内免费 | 4501篇 |
专业分类
化学 | 18392篇 |
晶体学 | 213篇 |
力学 | 2772篇 |
综合类 | 300篇 |
数学 | 11117篇 |
物理学 | 15259篇 |
出版年
2024年 | 107篇 |
2023年 | 422篇 |
2022年 | 927篇 |
2021年 | 1050篇 |
2020年 | 1256篇 |
2019年 | 1189篇 |
2018年 | 1056篇 |
2017年 | 1166篇 |
2016年 | 1664篇 |
2015年 | 1553篇 |
2014年 | 2026篇 |
2013年 | 3238篇 |
2012年 | 2169篇 |
2011年 | 2488篇 |
2010年 | 2016篇 |
2009年 | 2491篇 |
2008年 | 2521篇 |
2007年 | 2698篇 |
2006年 | 2290篇 |
2005年 | 1948篇 |
2004年 | 1618篇 |
2003年 | 1565篇 |
2002年 | 1302篇 |
2001年 | 1059篇 |
2000年 | 1099篇 |
1999年 | 923篇 |
1998年 | 817篇 |
1997年 | 656篇 |
1996年 | 443篇 |
1995年 | 434篇 |
1994年 | 372篇 |
1993年 | 336篇 |
1992年 | 308篇 |
1991年 | 248篇 |
1990年 | 257篇 |
1989年 | 240篇 |
1988年 | 226篇 |
1987年 | 206篇 |
1986年 | 177篇 |
1985年 | 194篇 |
1984年 | 175篇 |
1983年 | 93篇 |
1982年 | 147篇 |
1981年 | 137篇 |
1980年 | 117篇 |
1979年 | 114篇 |
1978年 | 99篇 |
1977年 | 93篇 |
1976年 | 79篇 |
1973年 | 69篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
91.
A review of the optimal stopping problem with more than a single decision maker (DM) is presented in this paper. We classify
the existing literature according to the arrival of the offers, the utility of the DMs, the length of the sequence of offers,
the nature of the game and the number of offers to be selected. We enumerate various definitions for this problem and describe
some dynamic approaches.
Fouad Ben Abdelaziz is on leave from the Institut Superieur de Gestion, University of Tunis, Tunisia e-mail: foued.benabdelaz@isg.run.tn. 相似文献
92.
Shawn Shih 《中国化学会会志》2003,50(4):815-822
A large class of stereochemcial and related interactions in organic chemistry are repulsive and others are attractive, but the relative orientation of two methyl groups and the amount of energy required to twist one relative to the other (the hindered rotation energy barriers), or the alignment of such a group with respect to a conjugated ring to which it is attached (widely attributed to a mechanism called “hyperconjugation”) are estimated to be small in compared with the total energy of the molecule. We used theories of both isotropic and anisotropic proton hyperfine interactions in the π‐electron systems developed in the early sixties. They are approximated by the magnetic dipole nteractions between each proton and an electron spin magnetization that is distributed in 2s and 2p Slater atomic orbitals center on carbon atoms. We have extended these theories to the non‐planar olefinic cation radicals, which are very important in biochemistry as well as in petroleum catalysis. A three dimensional electron spin density equation has been developed in this paper to handle some Jahn‐Teller vibronic molecules. The new electron spin density equation related the observed proton hyperfine splittings to the non‐planar structures of the open‐chain alkene cation radicals generated by radiolysis and various chemical oxidation methods. The spin densities and the conformational calculations based on valence bond theory and symmetry principles are compared with some more elaborated molecular orbital calculations in the literature. The localized valence bond approaches are better in accord with our experimental results. The anomalous line‐width effect of the four methyl groups observed in the 2,3‐dimethyl‐2‐butene cation radicals also confirmed the positive sign of the electron‐proton hyperfine constant of hyper‐conjugation mechanism. A methyl substituent attached to a conjugated molecule often behaves as if it formed part of the region of conjugation; the charge appears to flow from the methyl group into the π electron system and it may also give rise to an appreciable dipole moment. Methylation also gives rise to an appreciable dipole moment, and the resultant red shift of electronic absorption bands is of some importance in the design of dye molecules. 相似文献
93.
The theoretical investigation of the image states in front of an ultrathin iron film grown on copper has been performed by means of the embedding method and a recently developed procedure for the inclusion of the image potential tail in a first principle calculation. From the electronic response to an applied electric field, the image plane position has been evaluated. This also allows one to obtain useful information about the spin dependent screening properties of the system. Exchange splitting, effective mass, and lifetime of such surface states result in good agreement with recently performed two-photon photoemission experiments [see A.B. Schmidt, M. Pickel, M. Wiemhöfer, M. Donath, M. Weinelt, Phys. Rev. Lett. 95 (2005) 107402]. 相似文献
94.
Jiqin Deng 《Journal of Mathematical Analysis and Applications》2007,332(1):475-486
In this paper, by using the fixed point theory, under quite general conditions on the nonlinear term, we obtain an existence result of bounded positive solutions of Schrödinger equations in two-dimensional exterior domains. 相似文献
95.
V. P. Maslov 《Theoretical and Mathematical Physics》2007,150(1):102-122
From the standpoint of thermodynamic averaging of fission microprocesses, we investigate the origin of radioactive release
in an NPP after an accident or after resource depletion. The genesis of the NPP release is interpreted as a new thermodynamic
phenomenon, a zeroth-order phase transition. This problem setting results in a problem in probabilistic number theory. We
prove the corresponding theorem leading to quantization of the Zipf law for the frequency of a zeroth-order phase transition
with different values of the jump of the Gibbs thermodynamic potential. We introduce the notion of hole dimension.
__________
Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 150, No. 1, pp. 118–142, January, 2007. 相似文献
96.
We study the generalization of the Willmore functional for surfaces in the three-dimensional Heisenberg group. Its construction is based on the spectral theory of the Dirac operator entering into theWeierstrass representation of surfaces in this group. Using the surfaces of revolution we demonstrate that the generalization resembles the Willmore functional for the surfaces in the Euclidean space in many geometrical aspects. We also observe the relation of these functionals to the isoperimetric problem. 相似文献
97.
A. Vukics H. Ritsch 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,44(3):585-599
We present a framework for efficiently performing Monte Carlo
wave-function simulations in cavity QED with moving particles. It
relies heavily on the object-oriented programming paradigm as realised
in C++, and is extensible and applicable for simulating open
interacting qua
ntum dynamics in general. The user is provided with a
number of “elements”, e.g. pumped moving particles, pumped lossy
cavity modes, and various interactions to compose complex interacting
systems, which contain several particles moving in electromagnetic
fields of various configurations, and perform wave-function
simulations on such systems. A number of tools are provided to
facilitate the implementation of new elements. 相似文献
98.
1846年,刘维尔在自己主办的杂志“纯粹与应用数学杂志”首次出版了伽罗瓦的数学研究,这对于伽罗瓦理论的传播与发展是具有决定意义的事件.伽罗瓦去世14年后,刘维尔发表伽罗瓦数学研究的原因是什么?采用数学历史文献分析法,得出四个重要原因:①伽罗瓦的朋友和弟弟的请求;②力图弥补科学院曾经造成的不公正;③刘维尔积极扶持年轻人的高贵品质使然;④刘维尔与利布里学术论战的促进. 相似文献
99.
M. Iuga G. Steinle-Neumann J. Meinhardt 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,58(2):127-133
Athermal elasticity for some ceramic materials (α-Al2O3,
SiC (α and β phases), TiO2 (rutile and anatase),
hexagonal AlN and TiB2, cubic BN and CaF2, and monoclinic
ZrO2) have been investigated via density functional theory.
Energy-volume equation-of-state computations to obtain the zero pressure
equilibrium volume and bulk modulus as well as computations of the full
elastic constant tensor of these ceramics at the experimental zero pressure
volume have been performed. The present results for the single crystal
elasticity are in good agreement with experiments both for the aggregate
properties (bulk and shear modulus) and the elastic anisotropy. In contrast,
a considerable discrepancy for the zero pressure bulk modulus of some
ceramics evaluated from the energy-volume fit to the computational zero
pressure volume has been observed. 相似文献
100.
Within the framework of free interaction theory numerical methods are used to investigate the occurrence of supersonic zones with shocks in the outer inviscid region for flow past roughness in the lower viscous sublayer, with and without the formation of local separation zones. 相似文献