In present work, the ionic liquid, 1‐butyl‐3‐methylimidazolium bis (trifluoromethylsulfonyl) imide was incorporated in the carbon paste electrode as the binder (IL‐CPE). O‐anisidine (OA) monomer is electropolymerized in the presence of an aqueous acidic solution onto IL‐CPE (POA/IL‐CPE). The as‐prepared substrate is used as a porous matrix for dispersion of Ni(II) ions by immersing the modified electrode in a nickel(II) nitrite solution. The modified electrodes are characterized by scanning electron microscopy (SEM) and electrochemical methods. The POA/IL‐CPE was applied successfully to highly efficient (current density of 18.2 mA cm?2) electrocatalytic oxidation of formaldehyde in alkaline medium. Finally, the rate constant for chemical reaction between formaldehyde and redox sites of the electrode was calculated. 相似文献
The catalytic oxidative cyclocondensation of the o‐aminophenols 1a–f was investigated. The oxidants used were air/laccase, H2O2/horseradish peroxidase, H2O2/ebselen (3), and TBHP/diphenyl diselenide 4. The products obtained were 2‐amino‐3H‐phenoxazin‐3‐one—questiomycin A, its derivative 2b, and cinnabarinic acid and actinocin (2c,d). Substrates with methyl groups at 4 and 5 positions of benzene ring were converted to different dihydrophenoxazinones 2g,h. Compounds having chlorine atoms at the same positions underwent oxidation to planar phenoxa-zinones 2e,f with elimination of one hydrochloride molecule. 相似文献
We consider uniform stability to a nontrivial equilibrium of a nonlinear fluid–structure interaction (FSI) defined on a two or three dimensional bounded domain. Stabilization is achieved via boundary and/or interior feedback controls implemented on both the fluid and the structure. The interior damping on the fluid combining with the viscosity effect stabilizes the dynamics of fluid. However, this dissipation propagated from the fluid alone is not sufficient to drive uniformly to equilibrium the entire coupled system. Therefore, additional interior damping on the wave component or boundary porous like damping on the interface is considered. A geometric condition on the interface is needed if only boundary damping on the wave is active. The main technical difficulty is the mismatch of regularity of hyperbolic and parabolic component of the coupled system. This is overcome by considering special multipliers constructed from Stokes solvers. The uniform stabilization result obtained in this article is global for the fully coupled FSI model. 相似文献
This study mainly concentrates on the synthesis of three novel demulsifiers and the investigation of their demulsification efficiency. The demulsifiers were derived from 1,3,5-triethanolhexahydro-1,3,5-triazine, which was prepared by the reaction of monoethanol amine with formaldehyde. The 1,3,5-triethanolhexahydro-1,3,5-triazine was ethoxylated by introducing 20 units of ethylene oxide and then esterified at different molar ratios with oleic acid (1, 2, and 3) to give three demulsifiers, namely, E20TO, E20TO2, and E20TO3. The chemical structures of the prepared demulsifiers were confirmed by 1H NMR and FTIR spectrum. The demulsification efficiency of these demulsifiers was tested on the natural water-in-oil (w/o) emulsions (50% water content). From the obtained results, it has been found that the investigated demulsifiers have a great potential to break the w/o emulsions. The trioleat ester (E20TO3) exhibited the maximum demulsification efficiency (96%) after 120 minutes at 55°C. 相似文献
A novel scheme to multiply the repetition rate of a monolithic self‐mode‐locked laser for generating sub‐terahertz pulse sources is successfully demonstrated. A coated Yb:KGW crystal is designed to achieve a self‐mode‐locked operation at a repetition rate of 24 GHz with an average output power exceeding 1.0 W at a pump power of 4.8 W. A partially reflective mirror is utilized to combine with the output surface of the gain medium to constitute an external Fabry‐Perot cavity. It is theoretically and experimentally verified that adjusting the external cavity length to satisfy the commensurate condition can lead to the frequency spacing to be various order harmonics of the mode spacing of the monolithic cavity. The maximum pulse repetition rate of the laser output can be up to 216 GHz and the pulse duration is as short as 330 fs. More importantly, the overall characteristics of the first‐order temporal autocorrelation traces obtained by sequentially scanning the external cavity.length display an intriguing phenomenon of temporally fractional revivals, similar to the feature of spatial Talbot revivals.
Most of the commonly used microgels (MGs) are hydrophilic and tend to form oil-in-water emulsions. In this review, we discuss the function of MGs at the droplet interface in order to stabilize water-in-oil (w/o) emulsions. This topic addresses both interesting questions in fundamental research and a significant impact for applications, where the w/o emulsion type is of essential importance. Promising approaches to stabilize w/o emulsions with MGs are highlighted from different perspectives, ranging from novel MG modifications to assisted co-stabilization by adding soft or hard particles. We summarize the accumulated knowledge, evaluate the challenges and solutions, and highlight future research trends. 相似文献
Hydrophobic curcumin in temulawak extract and hydrophilic betacyanin in red dragon fruit extract are high-value bioactive compounds with extensive applications in functional food. In this study, these extracts were encapsulated in water-in-oil-in-water (w/o/w) nanoemulsions as a delivery system using a two-step high-energy emulsification method. PGPR and Span 20 were used as lipophilic emulsifiers for the primary w/o emulsion. The most stable w/o/w formulation with the least oil phase separation of 5% v/v consisted of w/o emulsion (15% w/w) and Tween 80 (1.5% w/w) as hydrophilic emulsifier. The formulation was characterized by a 189-nm mean droplet diameter, 0.16 polydispersity index, and –32 mV zeta potential. The freeze–thaw stability may be attributed to the combination of low w/o emulsion content and high Tween 80 concentration in the outer water phase of the w/o/w nanoemulsions used in this study. The IC50 values of the nanoemulsion and the red dragon fruit extract were similar. It means that the higher concentration of curcumin in the nanoemulsions and the lower IC50 value of temulawak extract ensured sufficient antioxidant activities of the w/o/w nanoemulsions. 相似文献