1,2-二芳基乙烯分子无损读取研究

1,2-二芳基乙烯类光致变色分子具有优良的热稳定性和耐疲劳性.它们作为新一代的光存储材料以及分子器件中光电微观性质控制的分子开关,引起了人们的重视.本文介绍了1,2-二芳基乙烯类光致变色分子的合成方法和光致变色性质,重点综述了这类分子在无损读取光存储材料方面的研究进展.     

Multichannel Data Acquisition System comparison for Quality Assurance in external beam radiation therapy

Megavoltage photon radiation therapies are widely used in modern cancer treatment. The improvement of the treatment has lead to the need of Quality Assurance (QA) devices to detect malfunctioning or human mistakes during the planning phase and treatment verification. Active electronic devices for 2D or 3D QA in external beam radiotherapy are typically based on analogue/digital mixed signal Data Acquisition Systems (DAS) which are required to have high spatial resolution, large dynamic range, high sensitivity, large numbers of channels and fast real-time capabilities. The Centre of Medical Radiation Physics (CMRP) has developed several multichannel DAS architectures based on different analogue front-ends to suit a wide range of radiotherapy applications. For the purpose of this study, two DAS, with different front-ends, have been equipped with 128 channels and tested in a clinical environment. Data show a good agreement within 1% between the two systems and the ionising chamber currently used for daily QA.     

新型波导多层光存储信息读出光学系统设计

信息读出光学系统是波导多层存储方法的重要组成部分,从几何光学角度,提出了两种信息读出光学系统的理论设计,并对两种系统的特点进行了实验研究,结果表明两种光学系统都是可行的,而且对波导多层光存储的进一步研究及实用化都有一定的参考价值。     

Improvement of fabrication and characterization methods for micromechanical disk resonators

In this paper we present a novel method to fabricate reliable micro-electro-mechanical system(MEMS) disk resonators with high yield and good performance.The key breakthrough in the fabrication process is a novel approach to effectively restraining electro-chemical corrosion of polycrystalline silicon(polysilicon) electrically coupled with noble metals of MEMS devices by hydrofluoric acid(HF)-based solutions.In addition,a measurement architecture based on a differential readout topology is demonstrated.The differential circuit proposed here can effectively suppress noise and feed-through current by common-mode rejection of the differential amplifier.This differential amplifier circuit configuration is also used to build up a notch filter.The preliminary result about the temperature dependence of the resonance frequency is discussed,and the device failure is analysed.     

基于GEM探测器的时间投影室TPC的讨论

自20世纪90年代以来, GEM探测器以其高电子倍增、高空间分辨和高计数率等优势在粒子物理和辐射成像等领域得到了广泛和深入的研究, 具有广阔的应用前景. 如果将GEM作为读出探测器应用在时间投影室TPC系统上, 和传统的读出方式比较起来, 既有许多优点也有许多挑战. 目前世界上有许多机构正在研究将此方案用于将来的大型正负电子对撞机ILC. 本文论述了这些研究课题的概况, 讨论了TPC的各项关键性能指标与GEM探测器的关系及存在的问题.     

光机械式红外探测器中镜面弯曲对探测灵敏度的影响

光学读出式红外成像技术是近年来研究的热点，本文讨论了镜面弯曲对光学检测灵敏度的影响。由双材料微悬臂梁组成的非致冷焦平面阵列通过体刻蚀工艺加工而成，由于残余应力的影响，制成的焦平面阵列将会发生弯曲，应力导致的镜面弯曲将会降低光学探测灵敏度。本文通过傅立叶光学模拟了镜面弯曲对光学探测灵敏度的影响，并通过实验验证了该模型。实验和模拟结果表明，在镜面曲率为0．1mm-1时，光学探测灵敏度将会降低到理想情况的40％。最后我们用这个模型评价了通过表面修饰来提高光学性能的效果。     

The Orange Side of Disperse Red 1: Humidity‐Driven Color Switching in Supramolecular Azo‐Polymer Materials Based on Reversible Dye Aggregation

Humidity detection, and the quest for low‐cost facile humidity‐sensitive indicator materials is of great interest for many fields, including semi‐conductor processing, food transport and storage, and pharmaceuticals. Ideal humidity‐detection materials for a these applications might be based on simple clear optical readout with no power supply, i.e.: a clear color change observed by the naked eye of any untrained observer, since it doesn't require any extra instrumentation or interpretation. Here, the introduction of a synthesis‐free one‐step procedure, based on physical mixing of easily available commercial materials, for producing a humidity memory material which can be easily painted onto a wide variety of surfaces and undergoes a remarkable color change (approximately 100 nm blue‐shift of λ_MAX) upon exposure to various thresholds of levels of ambient humidity is reported. This strong color change, easily visible to as a red‐to‐orange color switch, is locked in until inspection, but can then be restored reversibly if desired, after moderate heating. By taking advantage of spontaneously‐forming reversible ‘soft’ supramolecular bonds between a red‐colored azo dye and a host polymer matrix, a reversible dye ‘migration’ aggregation appearing orange, and dis‐aggregation back to red can be achieved, to function as the sensor.

     

吡啶基二噻吩乙烯轴向配位锰(Ⅱ)-卟啉化合物的合成及性质

针对有机光致变色材料实际应用中存在的光量子产率低,抗疲劳性差,记录信息在读取后遭到破坏等瓶颈问题,本文以2-甲基噻吩为原料,经过卤代、傅克酰基化、Mc Murry环合和Suzuki偶联反应得到的1-(5-氯-2-甲基噻吩-3-基)-2-(5-吡啶基-2-甲基噻吩-3-基)-环戊烯与锰(Ⅱ)-四苯基卟啉反应合成了吡啶基二噻吩乙烯轴向配位锰(Ⅱ)-卟啉化合物,通过紫外可见(UV-Vis)吸收光谱研究了其光致变色性能和抗疲劳性,并结合荧光光谱对无损读取功能进行了探究。实验结果表明,该化合物具有良好的光致变色性能及优良的抗疲劳性,通过波长为254、490和550 nm的光调控可无损地实现信息的写-读-擦过程,该物质有望应用于二进制存储设备中。     

Photonic Reservoir Computer with Output Expansion for Unsupervized Parameter Drift Compensation

We present a method to improve the performance of a reservoir computer by keeping the reservoir fixed and increasing the number of output neurons. The additional neurons are nonlinear functions, typically chosen randomly, of the reservoir neurons. We demonstrate the interest of this expanded output layer on an experimental opto-electronic system subject to slow parameter drift which results in loss of performance. We can partially recover the lost performance by using the output layer expansion. The proposed scheme allows for a trade-off between performance gains and system complexity.