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881.
Currently, there is no domain dictionary in the field of electric vehicles disassembly and other domain dictionary construction algorithms do not accurately extract terminology from disassembly text, because the terminology is complex and variable. Herein, the construction of a domain dictionary for the disassembly of electric vehicles is a research work that has important research significance. Extracting high-quality keywords from text and categorizing them widely uses information mining, which is the basis of named entity recognition, relation extraction, knowledge questions and answers and other disassembly domain information recognition and extraction. In this paper, we propose a supervised learning dictionary construction algorithm based on multi-dimensional features that combines different features of extraction candidate keywords from the text of each scientific study. Keywords recognition is regarded as a binary classification problem using the LightGBM model to filter each keyword, and then expand the domain dictionary based on the pointwise mutual information value between keywords and its category. Here, we make use of Chinese disassembly manuals, patents and papers in order to establish a general corpus about the disassembly information and then use our model to mine the disassembly parts, disassembly tools, disassembly methods, disassembly process, and other categories of disassembly keywords. The experiment evidenced that our algorithms can significantly improve extraction and category performance better than traditional algorithms in the disassembly domain. We also investigated the performance algorithms and attempts to describe them. Our work sets a benchmark for domain dictionary construction in the field of disassembly of electric vehicles that is based on the newly developed dataset using a multi-class terminology classification. 相似文献
882.
The Young's modulus of graphene with various rectangular and circular vacancy defects is investigated by molecular dynamics simulation. By comparing with the results calculated from an effective spring model, it is demonstrated that the Young's modulus of graphene is largely correlated to the size of vacancy defects perpendicular to the stretching direction. And a linear reduction of Young's modulus with the increasing concentration of mono‐atomic‐vacancy defects (i.e., the slope of ?0.03) is also observed. The fracture behavior of graphene, including the fracture strength, crack initiation and propagation are then studied by the molecular dynamics simulation, the effective spring model, and the quantized fracture mechanics. The blunting effect of vacancy edges is demonstrated, and the characterized crack tip radius of 4.44 Å is observed. 相似文献
883.
《Biomedical chromatography : BMC》2017,31(2)
A rapid dispersive micro‐solid phase extraction (D‐μ‐SPE) combined with LC/MS/MS method was developed and validated for the determination of ketoconazole and voriconazole in human urine and plasma samples. Synthesized mesoporous silica MCM‐41 was used as sorbent in d ‐μ‐SPE of the azole compounds from biological fluids. Important D‐μ‐SPE parameters, namely type desorption solvent, extraction time, sample pH, salt addition, desorption time, amount of sorbent and sample volume were optimized. Liquid chromatographic separations were carried out on a Zorbax SB‐C18 column (2.1 × 100 mm, 3.5 μm), using a mobile phase of acetonitrile–0.05% formic acid in 5 mm ammonium acetate buffer (70:30, v /v). A triple quadrupole mass spectrometer with positive ionization mode was used for the determination of target analytes. Under the optimized conditions, the calibration curves showed good linearity in the range of 0.1–10,000 μg/L with satisfactory limit of detection (≤0.06 μg/L) and limit of quantitation (≤0.3 μg/L). The proposed method also showed acceptable intra‐ and inter‐day precisions for ketoconazole and voriconazole from urine and human plasma with RSD ≤16.5% and good relative recoveries in the range 84.3–114.8%. The MCM‐41‐D‐μ‐SPE method proved to be rapid and simple and requires a small volume of organic solvent (200 μL); thus it is advantageous for routine drug analysis. 相似文献
884.
Dayanne Cristiane Mozaner Bordin Marcela Nogueira Rabelo Alves Eduardo Geraldo de Campos Bruno Spinosa De Martinis 《Journal of separation science》2016,39(6):1168-1172
Disposable pipette tips extraction consists of a solid‐phase extraction in which the sorbent is poorly dispersed in a pipette tip, which allows a quick and dynamic contact between the aspirated analyte from the sample and the solid phase. It is a technique used particularly in food and forensic analysis, since it requires a small amount of sample and solvent. This article highlights the principles, advantages and disadvantages of the disposable pipette tips extraction method and reviews recent applications. 相似文献
885.
Gas sensing is one of the most promising applications for graphene. Using molecular dynamics simulation method, adsorption isotherm of xenon (Xe) gas on defected and perfect graphene is studied in order to investigate sensing properties of graphene for Xe gas. In this method, first generation of Brenner many-body potential is used to simulate the interaction of carbon–carbon (C) atoms in graphene, and Lennard–Jones two-body potential is used to simulate interaction of Xe–Xe and Xe–C atoms. In the simulated systems, adsorption coverage, radial distribution function, heat of adsorption, binding energy and specific heat capacity at constant volume are calculated for several temperatures between 90 K and 130 K, and various pressures. It was found that both of the defected and perfect graphene could be introduced as very good candidates for adsorption of Xe gas. 相似文献
886.
Most of the techniques developed for infrared (IR) image enhancement (IE) depend heavily on the scene, environmental conditions, and the properties of the imaging system. So, with a set of predefined scenario properties, a content-based IR-IE technique can be developed for better situational awareness. This study proposes an adaptive IR-IE technique based on clustering of wavelet coefficients of an image for sea surveillance systems. Discrete wavelet transform (DWT) of an image is computed and feature vectors are constructed from subband images. Clustering operation is applied to group similar feature vectors that belong to different scene components such as target or background. Depending on the feature vectors, a weight is assigned to each cluster and these weights are used to compute gain matrices which are used to multiply wavelet coefficients for the enhancement of the original image. Enhancement results are presented and a comparison of the performance of the proposed algorithm is given through subjective tests with other well known frequency and histogram based enhancement techniques. The proposed algorithm outperforms previous ones in the truthfulness, detail visibility of the target, artificiality, and total quality criteria, while providing an acceptable computational load. 相似文献
887.
运用密度泛函理论方法研究了烷基碳链长度对氯化三烷基铵络合氯化汞的影响,计算结果表明,氯化三烷基铵与氯化汞的络合作用随着氯化三烷基铵中烷基碳链的增长而增强.通过对络合物的键长、Mayer键级和Mulliken电荷分析可知,电子富集在氯化三烷基铵的Cl原子上,并和Hg原子之间形成静电吸引作用.当烷基长度小于3时,烷基的电子效应影响较为明显,增强了原子之间的电子转移,使得络合物更稳定;当氯化三烷基铵烷基碳链长度大于3后,烷基链长对络合物中的电子转移不再有影响,络合物的稳定性受到烷基的几何效应影响更为明显. 相似文献
888.
Sulfur K-edge X-ray absorption near-edge structure spectroscopy and chemical sequential extraction was respectively used to study the speciation of sulfur in two sulfur-rich soils samples. Sulfur K-edge X-ray absorption near-edge structure spectroscopy analysis obtained a variety of spectra. Spectral fitting of the X-ray absorption near-edge structure spectra utilizing a large set of model compounds showed great differences between these two sulfur-rich soil samples. It was found that both of the soil samples had high sulfur content (8.40 and 11.57?g?kg?1, respectively). Chemical extraction results suggested that sulfur mainly existed as organic in the ancient paddy soil (7.37?g?kg?1) and more reduced sulfur was identified in it. X-ray absorption near-edge structure spectroscopy also got similar results. These organic forms of sulfur existed in organic matter across a range of oxidation states. There was high proportion of oxidized sulfur in the sulfuric acid plant that mainly existed as sulfate. 相似文献
889.
Based on molecular dynamics simulations, the plastic deformation of silver nanowires under uniaxial tension has been studied systematically. In this paper, the mechanical properties of [111]-oriented twin nanowires with different hole sizes have been studied. The existence of holes has no effect on the elastic deformation stage. The hole on the twin boundary has two main roles in the plastic deformation stage. During the initial stages of plastic deformation, the main function of the hole is to produce new dislocations as dislocation sources at small hole sizes.Upon increasing the hole size, the main effect changes to stop dislocation slip. During the late stages of plastic deformation, the two functions of the hole complement each other, upon increasing the hole size, the function of the hole as dislocation sources becomes obvious, leading to weakening of the plasticity of the nanowires. 相似文献
890.
The liquid–liquid equilibrium (LLE) of the ternary system comprising heptane, thiophene and the ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ([C2mim][NTf2]) was determined at 25 °C and atmospheric pressure, for preliminary evaluation of the potential of this ionic liquid as solvent for the desulfurisation of transportation fuels. Classical parameters such as solute distribution ratio and selectivity were calculated from the LLE data and subsequently analysed. The LLE data were also correlated by means of the ‘Non-Random Two-Liquid’ (NRTL) equation. Besides the LLE, another critical property for the design of extraction processes, namely the interfacial tension, was determined in parallel, throughout the immiscibility domain of the ternary system. For the first time, the LLE and the interfacial tension of a ternary system involving an ionic liquid are jointly reported. 相似文献