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971.
Kuang X.-Y. Jin S.-Q. Cao Y.-H. Zhang Y.-M. Dong S.-G. Zhu L.-H. Lin L.-W. Lin C.-J. 《电化学》2021,(6):624-636
The ordinary organic coatings on aluminum alloy usually encounter a problem of low adhesion to the substrate, which results in destruction and failure of the long-term protective performance of the anticorrosion systems. The surface modification of aluminum alloy is able to enhance the adhesion of organic coating on aluminum alloys, and to improve their protective performance. In this work, a combined surface modification of anodic oxidation and mussel adhesion protein/CeO2/3-aminopropyltriethoxysilane composite film (MCA) was developed on the aluminum alloy. The adhesion of modified polyurethane coated on the treated aluminum alloy and its corrosion protective performance were evaluated comprehensively by using contact angle, adhesion strength, electrochemical impedance spectroscopy (EIS), and scanning reference electrode technique (SRET). The measurements of EIS and SRET demonstrated that the MCA composite film on anodic oxidized Al possessed self-healing function and provided effective protection against early corrosion of aluminum alloy. The pull-off test showed that both anodic oxidation treatment and MCA composite film modification were able to increase the adhesion of modified polyurethane coating on aluminum alloy, and their combined action were supposed to remarkably enhance the adhesion strength up to 17.1 MPa. The reason for the improvement of adhesion was that the anodic oxidation treatment and MCA composite film modification could improve the surface roughness of aluminum alloy, and enhance the surface wettability and surface polarity, which is beneficent to enhance the bonding of the modified polyurethane coating to aluminum alloy surface. The EIS results showed that no any corrosion occurred for the modified polyurethane coating on the treated aluminum alloy during 65 d immersion in 3.5wt.% NaCl solution. The impedance value in low frequency range of the modified polyurethane coating always maintained at a high order of magnitude on the aluminum alloy treated by anodic oxidation and MCA composite film modification, showing an excellent protective performance of the coating system. The evaluation of Neutral Salt Spray (NSS) indicated that the modified polyurethane coating on the treated aluminum alloy owned superior corrosion protection performance, and the adhesion strength remained 13.1 MPa and no any corrosion was found at the scratch locations even after 1200 h of salt spray testing. It was concluded that combination of anodic oxidation and MCA composite film were capable of significantly improving the adhesion of modified polyurethane coating on aluminum alloy and providing long-term effective corrosion protection for aluminum alloy. © 2021 Authors. All rights reserved. 相似文献
972.
微量吸附量热法研究氧化物催化剂的酸碱性质 总被引:6,自引:0,他引:6
利用微量吸附量热技术定量地表征了Eu2O3、CeO2、MgO、ZnO、Al2O3和NiO等氧化物表面酸碱中心的强度和数量,结果表明,样品的NH3和CO2起始吸附热与其Sanderson电负性相关. 相似文献
973.
NO在Er2O3/Bi2O3催化剂上的程序升温分解 总被引:3,自引:0,他引:3
NOx是造成大气污染的化学物质之一,因此,消除NOx是环境保护的一项重要任务,目前比较成熟的消除NOx工艺是用氨为还原剂和V2O5/TiO2为催化剂的选择催化还原(SCR)法[1],但其成本过高. 相似文献
974.
975.
In this study, new biodegradable and biocompatible amphiphilic polymers were obtained by modifying the peripheral hydroxyl groups of branched polyethers and polyesters with organosilicon substituents. The structures of the synthesized polymers were confirmed by NMR and GPC. Organosilicon moieties of the polymers were formed by silatranes and trimethylsilyl blocks and displayed hydrophilic and hydrophobic properties, respectively. The effect of the ratio of hydrophilic to hydrophobic organosilicon structures on the surface activity and biological activity of macromolecules was studied, together with the effect on these activities of the macromolecules’ molecular weight and chemical structure. In particular, the critical micelle concentrations were determined, the effect of the structure of the polymers on their wetting with aqueous solutions on glass and parafilm was described, and the aggregation stability of emulsions was studied. Finally, the effect of the polymer structures on their antifungal activity and seed germination stimulation was examined. 相似文献
976.
977.
978.
测定了一系列有机铵盐与一种全氟烷磺酸盐1:1混合体系水 溶液的表面张力,由此研究有机铵盐对碳氟表面活性剂表面活性及溶度的影响,导出应用于此种混合体系的Gibbs吸附公式,并讨论了混合体系中两表面活性组分的表面分子相互作用和表面层的结构。 相似文献
979.
In this study, optimum conditions for adsorption of heavy metals such as Cu2+, Cd2+ and Pb2+ onto a low-cost, magnetically modified-alkali conditioned anaerobically digested sludge (MADS) adsorbent were obtained. Response Surface Methodology (RSM) incorporating Central Composite Design (CCD) of experiments was applied to optimize four independent process variables. Statistical analysis was executed by ANOVA and the quadratic model developed had regression coefficients of 0.959, 0.957 and 0.95 for Cu2+, Cd2+ and Pb2+, respectively. The independent variables such as pH, time and initial concentration positively influenced adsorption capacity, qe, whereas the value of qe decreased with an increase in MADS dosage. Model validation experiments for optimization of adsorption process showed comparable results with predicted values. The adsorption capacity of MADS adsorbent at optimum conditions found through RSM analysis was 29.721 mg L?1, 28.551 mg L?1 and 28.601 mg L?1 for Cu2+, Cd2+ and Pb2+ respectively. 相似文献
980.