Noncovalent Intermolecular Interaction in Cofacially Stacked 24π Antiaromatic Hexaphyrin Dimer

π–π Stacking is omnipresent not only in nature but in a wide variety of practical fields applied to our lives. Because of its importance in a performance of natural and artificial systems, such as light harvesting system and working layer in device, many researchers have put intensive effort into identifying its underlying nature. However, for the case of π–π stacked systems composed of antiaromatic units, the understanding of the fundamental mechanisms is still unclear. Herein, we synthesized a new type of planar β,β’-phenylene-bridged hexaphyrin (1.0.1.0.1.0), referred as naphthorosarin which possesses the 24π-electron conjugated pathway. Especially, the corresponding antiaromatic porphyrinoid shows the unique property to form dimeric species adopting the face-to-face geometry which is unprecedented in cases of known annulated naphthorosarins. In order to elucidate the intriguing properties derived from the stacked dimer, the current study focuses on the experimental support to rationalize the observed π–π interactions between the two subunits.     

Electrical characteristics of AlInN/GaN HEMTs under cryogenic operation

Electrical properties of an AlInN/GaN high-electron mobility transistor (HEMT) on a sapphire substrate are investi-gated in a cryogenic temperature range from 295 K down to 50 K. It is shown that drain saturation current and conductance increase as transistor operation temperature decreases. A self-heating effect is observed over the entire range of temperature under high power consumption. The dependence of channel electron mobility on electron density is investigated in detail. It is found that aside from Coulomb scattering, electrons that have been pushed away from the AlInN/GaN interface into the bulk GaN substrate at a large reverse gate voltage are also responsible for the electron mobility drop with the decrease of electron density.     

纯引力轨道验证质量辐射计效应分析

纯引力轨道飞行器在精密导航、重力场测量以及基础科学研究等方面具有重要意义,辐射计效应是纯引力轨道验证质量的重要干扰力之一．针对内编队重力场测量系统,利用解析和数值计算相结合的方法,分析了内卫星辐射计效应与内编队系统参数的关系,并给出了适宜于工程计算的内卫星辐射计效应近似函数及其修正因子．分析可知,内卫星辐射计效应与腔体平均压力成正比,与腔体平均温度成反比;随腔体温差的增加而增加,随外卫星腔体半径的增加存在极小值,并且取极小值时外卫星腔体半径和内卫星半径比为常数1.189 4,这一常数是由内外卫星的球形腔体构型决定的,与腔体内温度和压力无关．当内外卫星半径比大于10时,可认为外卫星腔体充分大,此时内卫星辐射计效应与内卫星半径的平方近似成正比,随外卫星腔体半径的变化可忽略．     

Image Displaying Method of Ground-Based Millimeter Wave Radiometric Imaging System

The image displaying methods used in a millimeter wave radiometric imaging system have great influence on its imaging quality. In order to obtain high quality millimeter wave radiometric images, intensive studies on the image displaying methods are needed. This paper describes the image displaying method of Ground-based 8mm Millimeter Wave Radiometric Imaging (GMWRI) system and compares two different image displaying methods. The experimental results prove the unequal size element arc displaying method fits GMWRI system better.     

Expected thermal deformation and wavefront preservation of a cryogenic Si monochromator for Cornell ERL beamlines

Cornell energy‐recovery linac (ERL) beamlines will have higher power density and higher fractional coherence than those available at third‐generation sources; therefore the capability of a monochromator for ERL beamlines has to be studied. A cryogenic Si monochromator is considered in this paper because the perfect atomic structure of Si crystal is needed to deliver highly coherent radiation. Since neither the total heat load nor the power density alone can determine the severity of crystal deformation, a metric called modified linear power density is used to gauge the thermal deformation. For all ERL undulator beamlines, crystal thermal deformation profiles are simulated using the finite‐element analysis tool ANSYS, and wavefront propagations are simulated using Synchrotron Radiation Workshop. It is concluded that cryogenic Si monochromators will be suitable for ERL beamlines in general.     

双通道数字红外辐射计的研究

 针对目前所使用的红外辐射强度测试系统的不足,提出双通道数字红外辐射计的方案,即在同一红外辐射计中设计两套相互独立的红外辐射强度测试通道,在红外辐射产品点火试验测试中,双通道测试同时工作,同时进行数据采集。用研制的双通道数字红外辐射计分别在室温（25℃）和低温（-15℃）条件下进行6次对比试验,结果表明：两系统测试的误差小于5%,双通道数字红外线辐射计两通道之间误差小于5％,原1905A测试系统出现2次漏测,双通道数字红外辐射计无漏测。     

Performance of a silicon monochromator under high heat load

The performance of a cryogenically cooled double‐crystal silicon monochromator was studied under high‐heat‐load conditions with total absorbed powers and power densities ranging from 8 to 780 W and from 8 to 240 W mm^?2, respectively. When the temperature of the first crystal is maintained close to the temperature of zero thermal expansion of silicon, the monochromator shows nearly ideal performance with a thermal slope error of 0.6 µrad. By tuning the size of the first slit, the regime of the ideal performance can be maintained over a wide range of heat loads, i.e. from power densities of 110 W mm^?2 (at total absorbed power of 510 W) to 240 W mm^?2 (at total absorbed power of 240 W).     

Solubility of Solid 2-Methyl-1,3-butadiene (Isoprene) in Liquid Argon and Nitrogen at the Standard Boiling Points of the Solvents

The solubility of solid 2-methyl-1,3-butadiene (isoprene) in liquid argon at a temperature of 87.3 K and in liquid nitrogen at 77.4 K has been measured by the filtration method. The hydrocarbon contents in solutions were determined using gas chromatography. GC–MS was used to identify impurities in the solute. The experimental value of the mole fraction solubility of solid isoprene in liquid argon at 87.3 K is (1.41 ± 0.27) × 10^–6 and (1.56 ± 0.36) × 10^–7 in liquid nitrogen at 77.4 K. The Preston–Prausnitz method was used for calculation of the solubilities of solid hydrocarbon in liquid argon in the temperature range 84.0–110.0 K and in liquid nitrogen from 64.0 to 90.0 K. The solvent–solute interaction parameters l ₁₂ were also calculated. At 90.0 K liquid argon is a better solvent for isoprene than is liquid nitrogen. The experimental values of the solubilities of isoprene in liquid argon and nitrogen were compared with results obtained for selected unsaturated and aromatic hydrocarbons.     

Imaging of Self‐Assembled Structures: Interpretation of TEM and Cryo‐TEM Images

The investigation of solution‐borne nanostructures by transmission electron microscopy (TEM) is a frequently used analytical method in materials chemistry. In many cases, the preparation of the TEM sample involves drying and staining steps, and the collection of images leads to the interaction of the specimen with the electron beam. Both aspects call for cautious interpretation of the resulting electron micrographs. Alternatively, a near‐native solvated state can be preserved by cryogenic vitrification and subsequent imaging by low‐dose cryogenic TEM. In this Minireview, we provide a critical analysis of sample preparation, and more importantly, of the acquisition and interpretation of electron micrographs. This overview should provide a framework for the application of (cryo)‐TEM as a powerful and reliable tool for the analysis of colloidal and self‐assembled structures with nanoscopic dimensions.