全文获取类型
收费全文 | 16501篇 |
免费 | 1589篇 |
国内免费 | 1083篇 |
专业分类
化学 | 12577篇 |
晶体学 | 58篇 |
力学 | 1111篇 |
综合类 | 97篇 |
数学 | 1604篇 |
物理学 | 3726篇 |
出版年
2024年 | 32篇 |
2023年 | 241篇 |
2022年 | 439篇 |
2021年 | 420篇 |
2020年 | 615篇 |
2019年 | 601篇 |
2018年 | 563篇 |
2017年 | 680篇 |
2016年 | 782篇 |
2015年 | 728篇 |
2014年 | 757篇 |
2013年 | 1151篇 |
2012年 | 1058篇 |
2011年 | 1023篇 |
2010年 | 809篇 |
2009年 | 973篇 |
2008年 | 876篇 |
2007年 | 919篇 |
2006年 | 858篇 |
2005年 | 771篇 |
2004年 | 731篇 |
2003年 | 632篇 |
2002年 | 517篇 |
2001年 | 386篇 |
2000年 | 345篇 |
1999年 | 305篇 |
1998年 | 249篇 |
1997年 | 200篇 |
1996年 | 190篇 |
1995年 | 192篇 |
1994年 | 163篇 |
1993年 | 132篇 |
1992年 | 110篇 |
1991年 | 99篇 |
1990年 | 90篇 |
1989年 | 78篇 |
1988年 | 77篇 |
1987年 | 66篇 |
1986年 | 53篇 |
1985年 | 45篇 |
1984年 | 37篇 |
1983年 | 26篇 |
1982年 | 39篇 |
1981年 | 27篇 |
1980年 | 13篇 |
1979年 | 16篇 |
1978年 | 22篇 |
1977年 | 8篇 |
1976年 | 10篇 |
1973年 | 8篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
121.
Pyrolysis ammonia chemical ionization (PyCI) mass spectrometry was performed on hy-droxyethyl-, hydroxypropyl-,methyl-, hydroxypropylmethyl-, and ethylhydroxyethyl cel-luloses. The mass peaks in the PyCI mass spectra of these cellulose ethers could be assigned to the ions of pyrolytic dissociation products which form via the [2 + 2 + 2] cycloreversion and the Ei elimination pyrolysis pathway. Structural information about the residual amount of nonderivatized cellulose, the relative chain length distributions of the substituents in hydroxyalkyl celluloses, and the end-capping of hydroxyalkyl substituents by alkyl groups in the mixed cellulose ethers is obtained. Interference of secondary pyrolysis products in the PyCI mass spectra is found to be of minor importance, especially in the lower mass regions. © 1995 John Wiley & Sons, Inc. 相似文献
122.
A multiparameter boundary-value problem of fresh infiltration water seepage in a drained fringe above quiescent saline water is solved in the direct statement and studied in detail. 相似文献
123.
L. Stoch 《Journal of Thermal Analysis and Calorimetry》1997,49(3):1433-1440
Chemical component exchange and transport phenomena accompanying the multistage phase transformations of several silicate and aluminosilicate-phosphate glasses and borates as model systems are considered. It is demonstrated that the component transport limitations modify the role of chemical affinity influence and determine the sequence of new compound formation.The work was supported by grant P040703406 from the National Committee of Scientific Research of Poland. 相似文献
124.
Unconventional antiferromagnetic correlations of the doped Haldane gapsystem Y 2 BaNi 1 - x Zn x O 5
V. Villar R. Mélin C. Paulsen J. Souletie E. Janod C. Payen 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,25(1):39-51
We make a new proposal to describe the very low temperature susceptibility of the doped Haldane gap compound Y2BaNi1-xZnxO5. We propose a new mean field model relevant for this compound. The ground state of this mean field model is unconventional
because antiferromagnetism coexists with random dimers. We present new susceptibility experiments at very low temperature.
We obtain a Curie-Weiss susceptibility χ(
T
) ∼
C
/(Θ +
T
) as expected for antiferromagnetic correlations but we do not obtain a direct signature of antiferromagnetic long range order.
We explain how to obtain the “impurity” susceptibility
(
T
) by subtracting the Haldane gap contribution to the total susceptibility. In the temperature range [1 K, 300 K] the experimental
data are well fitted by T
(
T
) =
C
imp
1 +
T
imp
/
T
. In the temperature range [100 mK, 1 K] the experimental data are well fitted by T
(
T
) =
A
ln(
T
/
T
c
), where T
c
increases with x. This fit suggests the existence of a finite Néel temperature which is however too small to be probed directly in our experiments.
We also obtain a maximum in the temperature dependence of the ac-susceptibility
(
T
) which suggests the existence of antiferromagnetic correlations at very low temperature.
Received 17 July 2001 相似文献
125.
Stefanie M. Walz Thomas E. Malner Ulrich Mueller Rolf Muelhaupt 《Journal of Polymer Science.Polymer Physics》2003,41(4):360-367
We explored phase separation and self‐assembly of perfluoroalkyl segments at the surface of polymer films obtained from latices of semifluorinated acrylate copolymers and the corresponding latex blends of nonfluorinated and semifluorinated polyacrylates. With laser‐induced secondary mass spectrometry the fluorine distribution was measured after annealing above the minimum film‐forming temperature of the polymers up to a depth of several micrometers. Depth profiles of a semifluorinated acrylate homopolymer and latex blends thereof with fluorine‐free alkylacrylates with 25, 50, and 75 mol % semifluorinated acrylate as well as a copolymer comprised of alkyl acrylate and semifluorinated acrylate (50/50 mol %) were investigated. In the case of latex blends containing both semifluorinated polyacrylates and fluorine‐free or low‐fluorine polymers, self‐assembly accounted for enrichment of the perfluoroalkyl segments at the surface. Coatings exhibiting low surface energy and having a substantially reduced total fluorine content were obtained. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 360–367, 2003 相似文献
126.
M. Drewsen 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,45(1):125-127
We briefly discuss some possibilities for cooling, identification and spectroscopy of super-heavy element (SHE) ions based
on recent results obtained from studies of atomic and molecular ions in linear rf traps. Since these investigations only relied
on the charge and the mass of the ion of interest, we believe it should be straight forward to adopt most of the techniques
for SHE ion research. 相似文献
127.
Sridevi Kaiti Eric Fossum 《Journal of polymer science. Part A, Polymer chemistry》2006,44(6):2099-2106
A thorough study of the polymerization behavior of 4‐fluoro‐4′‐hydroxytriphenyl‐phosphine oxide, 2 , under nucleophilic aromatic substitution reactions has been carried out. The synthesis of 2 was achieved in excellent yields by the reaction of bis(4‐fluorophenyl)phenylphosphine oxide, 1 , with one equivalent of potassium hydroxide in DMSO/water. The structure and purity of 2 were confirmed via 1H, 13C, and 31P NMR spectroscopy along with elemental analysis. Polymerization reactions of 2 in NMP or DMSO at 180 °C provided the corresponding linear poly(arylene ether phosphine oxide)s, PAEPOs, with number average molecular weights, Mn, ranging from 11,700 to 36,500 Da. All of the polymer samples were completely soluble in chloroform, tetrahydrofuran, DMSO, NMP, and DMAc. The polymerization reactions were accompanied by a competing intramolecular process that resulted in the formation of cyclic oligomeric species that were removed via a final precipitation from methanol. Analysis using 31P NMR spectroscopy and size exclusion chromatography (SEC) confirmed that the majority of the lower molecular weight cyclic species were removed via this process. The polymer samples formed tough films when chloroform solutions were slowly evaporated on a glass slide. The PAEPO samples prepared in this study exhibited excellent thermal stability with Td (5%) values between 503 and 542 in air while the glass transition temperatures ranged from 223 to 237 °C. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2099–2106, 2006 相似文献
128.
在这一报告中将报告我和BABU教授合作的在hep-ph/0507217一文中有关中微子混合研究结果. 目前中微子实验数据所决定的混合角可归结为几何混合状况:sin2θ12=1/3,sin2θ23=1/2, 和sin2θ13=0. 我们在这一工作中建立了能实现这一几何混合的可重整化模型. 模型以非阿贝尔非连续群A4为描述中微子不同代混合的对称性. 这类模型对中微子质量有很强的限制. 而且能很自然地由轻子数破坏产生重子不对称的实验观测值. 很有趣的是这类模型中出现在轻子不守恒和无中微子双beta衰变中的相位是一样的. 相似文献
129.
P. Kh. Atanasova T. L. Bojadjiev S. N. Dimova 《Computational Mathematics and Mathematical Physics》2006,46(4):666-679
Partial critical dependences of the form current-magnetic field in a two-layered symmetric Josephson junction are modeled. A numerical experiment shows that, for the zero interaction coefficient between the layers of the junction, jumps of the critical currents corresponding to different distributions of the magnetic fluxes in the layers may appear on the critical curves. This fact allows a mathematical interpretation of the results of some recent experimental results for two-layered junctions as a consequence of discontinuities of partial critical curves. 相似文献
130.
Summary A theory of theg-factor for electrons bound to donors in zincblende semiconductors is presented for all magnetic fields. Simple analytical
expressions are obtained for weak, intermediate and high magnetic-field intensities. A comparison between theory and the experimental
result in the case of InSb is made. 相似文献